New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States
The millimeter-wave rotational spectra of the ground and excited vibrational states v7 =1 and v8 =1 of the symmetric top molecule, CCl3CN, have been analyzed again. The B0 = 1666.80894(13) MHz, DJ = 0.135023 (23) kHz, DJK = 0.60596 (45) kHz, HJ = -0.0192 (10) mHz, HJK = 1.188 (34) mHz and HKJ = -1.6...
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| Format: | Article |
| Language: | English |
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Wiley
2008-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2008/149378 |
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| author | Masoud Motamedi Tahere Zohrevand |
| author_facet | Masoud Motamedi Tahere Zohrevand |
| author_sort | Masoud Motamedi |
| collection | DOAJ |
| description | The millimeter-wave rotational spectra of the ground and excited vibrational states v7 =1 and v8 =1 of the symmetric top molecule, CCl3CN, have been analyzed again. The B0 = 1666.80894(13) MHz, DJ = 0.135023 (23) kHz, DJK = 0.60596 (45) kHz, HJ = -0.0192 (10) mHz, HJK = 1.188 (34) mHz and HKJ = -1.60 (21) mHz have been determined for ground state. The 𝓁 = ±1 series have been assigned and the rotational parameters including B7 =1667.96659(25) MHz, (q+t)7=1.58855(94) MHz for v7 =1 and B8 =1667.08204 (31) MHz, (q+t)8 = 1.6141(36) MHz for v8 = 1 states were determined accurately. |
| format | Article |
| id | doaj-art-823a103056484922a999d4bc258220da |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2008-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-823a103056484922a999d4bc258220da2025-02-03T01:20:25ZengWileyE-Journal of Chemistry0973-49452090-98102008-01-015494696210.1155/2008/149378New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 StatesMasoud Motamedi0Tahere Zohrevand1Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, IranDepartment of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, IranThe millimeter-wave rotational spectra of the ground and excited vibrational states v7 =1 and v8 =1 of the symmetric top molecule, CCl3CN, have been analyzed again. The B0 = 1666.80894(13) MHz, DJ = 0.135023 (23) kHz, DJK = 0.60596 (45) kHz, HJ = -0.0192 (10) mHz, HJK = 1.188 (34) mHz and HKJ = -1.60 (21) mHz have been determined for ground state. The 𝓁 = ±1 series have been assigned and the rotational parameters including B7 =1667.96659(25) MHz, (q+t)7=1.58855(94) MHz for v7 =1 and B8 =1667.08204 (31) MHz, (q+t)8 = 1.6141(36) MHz for v8 = 1 states were determined accurately.http://dx.doi.org/10.1155/2008/149378 |
| spellingShingle | Masoud Motamedi Tahere Zohrevand New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States E-Journal of Chemistry |
| title | New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States |
| title_full | New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States |
| title_fullStr | New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States |
| title_full_unstemmed | New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States |
| title_short | New Investigation of Millimeter-Wave Rotational Spectrum of CCl3CN in Ground, v7 = 1 and v8 = 1 States |
| title_sort | new investigation of millimeter wave rotational spectrum of ccl3cn in ground v7 1 and v8 1 states |
| url | http://dx.doi.org/10.1155/2008/149378 |
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