Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars

Surfactants and polymers are widely used as shape-directing agents in the synthesis of colloidal plasmonic nanostars, consequently acting as non-negligible players in all those high-performance applications in which processes occur at their interfaces, such as surface enhanced Raman spectroscopy (SE...

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Main Authors: Debora Ferrari, Chiara Deriu, Laura Fabris
Format: Article
Language:English
Published: Frontiers Media S.A. 2024-12-01
Series:Frontiers in Nanotechnology
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fnano.2024.1505304/full
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author Debora Ferrari
Chiara Deriu
Laura Fabris
author_facet Debora Ferrari
Chiara Deriu
Laura Fabris
author_sort Debora Ferrari
collection DOAJ
description Surfactants and polymers are widely used as shape-directing agents in the synthesis of colloidal plasmonic nanostars, consequently acting as non-negligible players in all those high-performance applications in which processes occur at their interfaces, such as surface enhanced Raman spectroscopy (SERS) and plasmon-induced catalysis. Therefore, elucidating surfactant- and polymer-metal interactions is critical to rationally improving the performance of nanostars in the same range of applications. In this mini-review, we present traditional and state-of-the-art characterization methods that can be used to investigate the ligand-surface interactions that occur on mature nanostars. Due to historically based limitations in the availability of nanostar-specific literature, we utilize nanorod literature as a starting point to critically infer which analytical approaches can be seamlessly translated to nanostar systems, and which instead need to be adapted to intercept the peculiar needs imposed by the branched nanoparticle morphology.
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publishDate 2024-12-01
publisher Frontiers Media S.A.
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series Frontiers in Nanotechnology
spelling doaj-art-81f1b61ca1f54da89e7a6e80240052642025-08-20T01:59:57ZengFrontiers Media S.A.Frontiers in Nanotechnology2673-30132024-12-01610.3389/fnano.2024.15053041505304Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostarsDebora FerrariChiara DeriuLaura FabrisSurfactants and polymers are widely used as shape-directing agents in the synthesis of colloidal plasmonic nanostars, consequently acting as non-negligible players in all those high-performance applications in which processes occur at their interfaces, such as surface enhanced Raman spectroscopy (SERS) and plasmon-induced catalysis. Therefore, elucidating surfactant- and polymer-metal interactions is critical to rationally improving the performance of nanostars in the same range of applications. In this mini-review, we present traditional and state-of-the-art characterization methods that can be used to investigate the ligand-surface interactions that occur on mature nanostars. Due to historically based limitations in the availability of nanostar-specific literature, we utilize nanorod literature as a starting point to critically infer which analytical approaches can be seamlessly translated to nanostar systems, and which instead need to be adapted to intercept the peculiar needs imposed by the branched nanoparticle morphology.https://www.frontiersin.org/articles/10.3389/fnano.2024.1505304/fullsurfactantspolymersnanostarssurface adsorptionplasmonic nanoparticlesgold
spellingShingle Debora Ferrari
Chiara Deriu
Laura Fabris
Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars
Frontiers in Nanotechnology
surfactants
polymers
nanostars
surface adsorption
plasmonic nanoparticles
gold
title Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars
title_full Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars
title_fullStr Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars
title_full_unstemmed Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars
title_short Surfactants and polymers on nanoscale surfaces: the interface landscape of plasmonic nanostars
title_sort surfactants and polymers on nanoscale surfaces the interface landscape of plasmonic nanostars
topic surfactants
polymers
nanostars
surface adsorption
plasmonic nanoparticles
gold
url https://www.frontiersin.org/articles/10.3389/fnano.2024.1505304/full
work_keys_str_mv AT deboraferrari surfactantsandpolymersonnanoscalesurfacestheinterfacelandscapeofplasmonicnanostars
AT chiaraderiu surfactantsandpolymersonnanoscalesurfacestheinterfacelandscapeofplasmonicnanostars
AT laurafabris surfactantsandpolymersonnanoscalesurfacestheinterfacelandscapeofplasmonicnanostars