Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization

The protein from black soldier fly larvae was used as a functional ingredient of a novel green nanofiber. Larvae protein powder (LP) was blended with biodegradable poly(ε-caprolactone) (PCL) and processed in an electrospinning machine using a coaxial feeding/mixing method to produce nanofibers appro...

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Main Authors: Chin-San Wu, Shan-Shue Wang, Dung-Yi Wu, Wanwen Gu
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2024-08-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0012984&mi=cd
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author Chin-San Wu
Shan-Shue Wang
Dung-Yi Wu
Wanwen Gu
author_facet Chin-San Wu
Shan-Shue Wang
Dung-Yi Wu
Wanwen Gu
author_sort Chin-San Wu
collection DOAJ
description The protein from black soldier fly larvae was used as a functional ingredient of a novel green nanofiber. Larvae protein powder (LP) was blended with biodegradable poly(ε-caprolactone) (PCL) and processed in an electrospinning machine using a coaxial feeding/mixing method to produce nanofibers approximately 100–350 nm in diameter. To improve the dispersion and interface bonding of various PCL/LP nanofiber components, a homemade compatibilizer, maleic anhydridegrafted poly(ε-caprolactone) (MPCL), was added to form MPCL/LP nanofibers. The structure, morphology, mechanical properties, water absorption, cytocompatibility, wound healing, and biodegradability of PCL/LP and MPCL/LP nanofiber mats were investigated. The results showed enhanced adhesion in the MPCL/LP nanofiber mats compared to PCL/LP nanofiber mats; additionally, the MPCL/LP nanofibers exhibited increases of approximately 0.7–2.2 MPa in breaking strength and 9.0–22.8 MPa in Young’s modulus. Decomposition tests using a simulated body fluid revealed that the addition of LP enhanced the decomposition rate of both PCL/LP and MPCL/LP nanofiber mats and in vitro protein release. Cell proliferation and migration analysis indicated that PCL, MPCL, and their composites were biocompatible for fibroblast (FB) growth. Biodegradability was tested in a 30 day soil test. When the LP content was 20 wt%, the degradation rate exceeded 50%.
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institution Kabale University
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series eXPRESS Polymer Letters
spelling doaj-art-81ece18a9a374e58baf0cb4f0f084a0f2025-08-20T03:37:01ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2024-08-0118883585010.3144/expresspolymlett.2024.62Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterizationChin-San WuShan-Shue WangDung-Yi WuWanwen GuThe protein from black soldier fly larvae was used as a functional ingredient of a novel green nanofiber. Larvae protein powder (LP) was blended with biodegradable poly(ε-caprolactone) (PCL) and processed in an electrospinning machine using a coaxial feeding/mixing method to produce nanofibers approximately 100–350 nm in diameter. To improve the dispersion and interface bonding of various PCL/LP nanofiber components, a homemade compatibilizer, maleic anhydridegrafted poly(ε-caprolactone) (MPCL), was added to form MPCL/LP nanofibers. The structure, morphology, mechanical properties, water absorption, cytocompatibility, wound healing, and biodegradability of PCL/LP and MPCL/LP nanofiber mats were investigated. The results showed enhanced adhesion in the MPCL/LP nanofiber mats compared to PCL/LP nanofiber mats; additionally, the MPCL/LP nanofibers exhibited increases of approximately 0.7–2.2 MPa in breaking strength and 9.0–22.8 MPa in Young’s modulus. Decomposition tests using a simulated body fluid revealed that the addition of LP enhanced the decomposition rate of both PCL/LP and MPCL/LP nanofiber mats and in vitro protein release. Cell proliferation and migration analysis indicated that PCL, MPCL, and their composites were biocompatible for fibroblast (FB) growth. Biodegradability was tested in a 30 day soil test. When the LP content was 20 wt%, the degradation rate exceeded 50%.http://www.expresspolymlett.com/letolt.php?file=EPL-0012984&mi=cd additive biocompatible polymer biocomposite poly(caprolactone)biodegradation nanocomposites
spellingShingle Chin-San Wu
Shan-Shue Wang
Dung-Yi Wu
Wanwen Gu
Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization
eXPRESS Polymer Letters
additive
biocompatible polymer
biocomposite
poly(caprolactone)
biodegradation
nanocomposites
title Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization
title_full Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization
title_fullStr Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization
title_full_unstemmed Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization
title_short Modified poly(ε-caprolactone) with larvae protein environmentally friendly nanofiber: Assessment of interface properties and characterization
title_sort modified poly ε caprolactone with larvae protein environmentally friendly nanofiber assessment of interface properties and characterization
topic additive
biocompatible polymer
biocomposite
poly(caprolactone)
biodegradation
nanocomposites
url http://www.expresspolymlett.com/letolt.php?file=EPL-0012984&mi=cd
work_keys_str_mv AT chinsanwu modifiedpolyecaprolactonewithlarvaeproteinenvironmentallyfriendlynanofiberassessmentofinterfacepropertiesandcharacterization
AT shanshuewang modifiedpolyecaprolactonewithlarvaeproteinenvironmentallyfriendlynanofiberassessmentofinterfacepropertiesandcharacterization
AT dungyiwu modifiedpolyecaprolactonewithlarvaeproteinenvironmentallyfriendlynanofiberassessmentofinterfacepropertiesandcharacterization
AT wanwengu modifiedpolyecaprolactonewithlarvaeproteinenvironmentallyfriendlynanofiberassessmentofinterfacepropertiesandcharacterization