Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode

Biosensors are cost-effective, user-friendly devices with rapid response, sensitivity, selectivity, and stability. This study investigated the impact of K3[Fe(CN)6] concentration and glucose on glassy carbon electrode (GCE) performance. The cyclic voltammetry method determined the effects of varying...

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Main Authors: Adella Fajaretta Gunawan, Arie Hardian, Anceu Murniati
Format: Article
Language:English
Published: Universitas Sebelas Maret 2025-03-01
Series:Alchemy
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Online Access:https://jurnal.uns.ac.id/alchemy/article/view/87604
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author Adella Fajaretta Gunawan
Arie Hardian
Anceu Murniati
author_facet Adella Fajaretta Gunawan
Arie Hardian
Anceu Murniati
author_sort Adella Fajaretta Gunawan
collection DOAJ
description Biosensors are cost-effective, user-friendly devices with rapid response, sensitivity, selectivity, and stability. This study investigated the impact of K3[Fe(CN)6] concentration and glucose on glassy carbon electrode (GCE) performance. The cyclic voltammetry method determined the effects of varying K3[Fe(CN)6] and glucose concentrations on GCE. GCE characterization utilized K3[Fe(CN)6] solutions (1 – 5 mM) in 0.2 M KCl and achieved an optimum scan rate of 75 mV/s within -1.5 to 1 V vs. Ag/AgCl. Reversible Fe2+/Fe3+ redox occurred at 1mM (ipa/ipc= 0.99), with the highest reduction peak at 5mM. Glucose tests (1mM to 5mM) in 0.1 M NaOH exhibited an optimal scan rate of 200 mV/s within a potential range of -10 – 10 V at 1 mM (ipa/ipc= 1.01), with the highest oxidation peak at 5 mM. GCE effectively measured concentration effects, with ipa/ipc values close to 1, indicating reversible redox processes at low concentrations. Higher concentrations yielded stronger peak currents due to increased electroactive species.
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spelling doaj-art-811ec85d5e6b4808af3e58e7fd7d8fe82025-08-20T01:54:34ZengUniversitas Sebelas MaretAlchemy1412-40922443-41832025-03-01211435210.20961/alchemy.21.1.87604.43-5245281Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon ElectrodeAdella Fajaretta Gunawan0Arie Hardian1Anceu Murniati2Jenderal Achmad Yani University Jalan Terusan Jenderal Sudirman, Cimahi Selatan, Cimahi, Jawa Barat 40513, IndonesiaJenderal Achmad Yani University Jalan Terusan Jenderal Sudirman, Cimahi Selatan, Cimahi, Jawa Barat 40513, IndonesiaJenderal Achmad Yani University Jalan Terusan Jenderal Sudirman, Cimahi Selatan, Cimahi, Jawa Barat 40513, IndonesiaBiosensors are cost-effective, user-friendly devices with rapid response, sensitivity, selectivity, and stability. This study investigated the impact of K3[Fe(CN)6] concentration and glucose on glassy carbon electrode (GCE) performance. The cyclic voltammetry method determined the effects of varying K3[Fe(CN)6] and glucose concentrations on GCE. GCE characterization utilized K3[Fe(CN)6] solutions (1 – 5 mM) in 0.2 M KCl and achieved an optimum scan rate of 75 mV/s within -1.5 to 1 V vs. Ag/AgCl. Reversible Fe2+/Fe3+ redox occurred at 1mM (ipa/ipc= 0.99), with the highest reduction peak at 5mM. Glucose tests (1mM to 5mM) in 0.1 M NaOH exhibited an optimal scan rate of 200 mV/s within a potential range of -10 – 10 V at 1 mM (ipa/ipc= 1.01), with the highest oxidation peak at 5 mM. GCE effectively measured concentration effects, with ipa/ipc values close to 1, indicating reversible redox processes at low concentrations. Higher concentrations yielded stronger peak currents due to increased electroactive species.https://jurnal.uns.ac.id/alchemy/article/view/87604biosensorscyclic voltammetryglucoseglassy carbon electrodescan rate
spellingShingle Adella Fajaretta Gunawan
Arie Hardian
Anceu Murniati
Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode
Alchemy
biosensors
cyclic voltammetry
glucose
glassy carbon electrode
scan rate
title Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode
title_full Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode
title_fullStr Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode
title_full_unstemmed Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode
title_short Cyclic Voltammetry Study of the Influence of Concentration of K3[Fe(CN)6] and Glucose on Glassy Carbon Electrode
title_sort cyclic voltammetry study of the influence of concentration of k3 fe cn 6 and glucose on glassy carbon electrode
topic biosensors
cyclic voltammetry
glucose
glassy carbon electrode
scan rate
url https://jurnal.uns.ac.id/alchemy/article/view/87604
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