Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)

Rare earth element complexes with iminodiacetic acid (IMDA) of the Ln(IMDA) − 2 type exhibit an unusual sequence of affinities for anion exchangers. In this work, the applicability of strongly basic gel and macroporous polystyrene anion exchangers to the sorption and separation of rare earth element...

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Main Authors: Halina Hubicka, Dorota Kolodyńska
Format: Article
Language:English
Published: SAGE Publishing 2000-10-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263617001493765
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author Halina Hubicka
Dorota Kolodyńska
author_facet Halina Hubicka
Dorota Kolodyńska
author_sort Halina Hubicka
collection DOAJ
description Rare earth element complexes with iminodiacetic acid (IMDA) of the Ln(IMDA) − 2 type exhibit an unusual sequence of affinities for anion exchangers. In this work, the applicability of strongly basic gel and macroporous polystyrene anion exchangers to the sorption and separation of rare earth element complexes with iminodiacetic acid has been investigated. It was shown that the acetate forms of both the macroporous and gel anion exchangers were most effective and cheapest for this type of separation. As far as their applicability to the purification of lanthanum(III) IMDA from the corresponding neodymium(III) complexes is concerned, the anion exchangers investigated may be arranged in the following sequence: strongly basic gel anion exchangers ≈ strongly basic macroporous anion exchangers > weakly basic macroporous anion exchangers.
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series Adsorption Science & Technology
spelling doaj-art-805c079d9157401d89ab2af30cd0f9d22025-01-03T01:24:47ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382000-10-011810.1260/0263617001493765Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)Halina HubickaDorota KolodyńskaRare earth element complexes with iminodiacetic acid (IMDA) of the Ln(IMDA) − 2 type exhibit an unusual sequence of affinities for anion exchangers. In this work, the applicability of strongly basic gel and macroporous polystyrene anion exchangers to the sorption and separation of rare earth element complexes with iminodiacetic acid has been investigated. It was shown that the acetate forms of both the macroporous and gel anion exchangers were most effective and cheapest for this type of separation. As far as their applicability to the purification of lanthanum(III) IMDA from the corresponding neodymium(III) complexes is concerned, the anion exchangers investigated may be arranged in the following sequence: strongly basic gel anion exchangers ≈ strongly basic macroporous anion exchangers > weakly basic macroporous anion exchangers.https://doi.org/10.1260/0263617001493765
spellingShingle Halina Hubicka
Dorota Kolodyńska
Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)
Adsorption Science & Technology
title Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)
title_full Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)
title_fullStr Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)
title_full_unstemmed Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)
title_short Investigation into the Use of Macroporous Anion Exchangers for the Sorption and Separation of Iminodiacetate Complexes of Lanthanum(III) and Neodymium(III)
title_sort investigation into the use of macroporous anion exchangers for the sorption and separation of iminodiacetate complexes of lanthanum iii and neodymium iii
url https://doi.org/10.1260/0263617001493765
work_keys_str_mv AT halinahubicka investigationintotheuseofmacroporousanionexchangersforthesorptionandseparationofiminodiacetatecomplexesoflanthanumiiiandneodymiumiii
AT dorotakolodynska investigationintotheuseofmacroporousanionexchangersforthesorptionandseparationofiminodiacetatecomplexesoflanthanumiiiandneodymiumiii