Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)

<p>Elevated concentrations of ozone at the surface can lead to poor air quality and increased risks to human health. There have been large increases in surface ozone over the historical period associated with socio-economic development. Here, the change in peak-season ozone (OSDMA8) is estimat...

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Main Authors: S. T. Turnock, D. Akritidis, L. Horowitz, M. Mertens, A. Pozzer, C. L. Reddington, H. Wang, P. Zhou, F. O'Connor
Format: Article
Language:English
Published: Copernicus Publications 2025-07-01
Series:Atmospheric Chemistry and Physics
Online Access:https://acp.copernicus.org/articles/25/7111/2025/acp-25-7111-2025.pdf
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author S. T. Turnock
S. T. Turnock
D. Akritidis
D. Akritidis
L. Horowitz
M. Mertens
A. Pozzer
A. Pozzer
C. L. Reddington
H. Wang
P. Zhou
F. O'Connor
F. O'Connor
author_facet S. T. Turnock
S. T. Turnock
D. Akritidis
D. Akritidis
L. Horowitz
M. Mertens
A. Pozzer
A. Pozzer
C. L. Reddington
H. Wang
P. Zhou
F. O'Connor
F. O'Connor
author_sort S. T. Turnock
collection DOAJ
description <p>Elevated concentrations of ozone at the surface can lead to poor air quality and increased risks to human health. There have been large increases in surface ozone over the historical period associated with socio-economic development. Here, the change in peak-season ozone (OSDMA8) is estimated for the first time using hourly surface ozone output from three CMIP6 models over the 1850 to 2014 period. Additional results are obtained from one model to quantify the impact from different drivers of ozone formation, including anthropogenic emissions of ozone and aerosol precursors, stratospheric ozone, and climate change. The peak-season ozone concentrations are used to calculate the risk to human health, in terms of the attributable fraction metric (the percentage of deaths from COPD – chronic obstructive pulmonary disease – associated with long-term exposure to elevated ozone concentrations). OSDMA8 concentrations are simulated to increase by more than 50 % across northern mid-latitude regions over the historical period, mainly driven by increases in anthropogenic emissions of NO<span class="inline-formula"><sub><i>x</i></sub></span> and global <span class="inline-formula">CH<sub>4</sub></span> concentrations. Small contributions are made from changes in other anthropogenic precursor emissions (CO and non-<span class="inline-formula">CH<sub>4</sub></span> volatile organic compounds; VOCs), aerosols, stratospheric ozone and climate change. The proportion of the global population exposed to OSDMA8 concentrations above the theoretical minimum risk exposure level (32.4 ppb) increased from <span class="inline-formula">&lt;20</span> % in 1855 to <span class="inline-formula">&gt;90</span> % in 2010. This has also increased the risk to human health mortality due to COPD from long-term ozone exposure by up to 20 % across Northern Hemisphere regions in the present day. Like for OSDMA8 concentrations, the drivers of the increase in the ozone health risks are attributed mainly to changes in NO<span class="inline-formula"><sub><i>x</i></sub></span> and global <span class="inline-formula">CH<sub>4</sub></span>. Fixing anthropogenic NO<span class="inline-formula"><sub><i>x</i></sub></span> emissions at 1850 values can eliminate the risk to human health from long-term ozone exposure in the<span id="page7112"/> near-present-day period. Understanding the historical drivers of ozone concentrations and their risk to human health can help to inform the development of future pathways that reduce this risk.</p>
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spelling doaj-art-803ecc7b27cc4b4ea81c8791e50d90692025-08-20T03:47:17ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242025-07-01257111713610.5194/acp-25-7111-2025Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)S. T. Turnock0S. T. Turnock1D. Akritidis2D. Akritidis3L. Horowitz4M. Mertens5A. Pozzer6A. Pozzer7C. L. Reddington8H. Wang9P. Zhou10F. O'Connor11F. O'Connor12Met Office Hadley Centre, Exeter, UKUniversity of Leeds Met Office Strategic (LUMOS) Research Group, University of Leeds, Leeds, UKAtmospheric Chemistry Department, Max Planck Institute for Chemistry, Mainz, GermanyDepartment of Meteorology and Climatology, School of Geology, Aristotle University of Thessaloniki, Thessaloniki, GreeceNOAA Geophysical Fluid Dynamics Laboratory, Princeton, NJ, USADeutsches Zentrum für Luft- und Raumfahrt (DLR), Institut für Physik der Atmosphäre, Oberpfaffenhofen, GermanyAtmospheric Chemistry Department, Max Planck Institute for Chemistry, Mainz, GermanyClimate and Atmosphere Research Center, The Cyprus Institute, 1645 Nicosia, CyprusInstitute for Climate and Atmospheric Science (ICAS), School of Earth and Environment, University of Leeds, Leeds, UKDepartment of Environmental Sciences and Engineering, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, USAInstitute for Atmospheric and Earth System Research (INAR), University of Helsinki, Helsinki, FinlandMet Office Hadley Centre, Exeter, UKDepartment of Mathematics and Statistics, Global Systems Institute, University of Exeter, Exeter, UK<p>Elevated concentrations of ozone at the surface can lead to poor air quality and increased risks to human health. There have been large increases in surface ozone over the historical period associated with socio-economic development. Here, the change in peak-season ozone (OSDMA8) is estimated for the first time using hourly surface ozone output from three CMIP6 models over the 1850 to 2014 period. Additional results are obtained from one model to quantify the impact from different drivers of ozone formation, including anthropogenic emissions of ozone and aerosol precursors, stratospheric ozone, and climate change. The peak-season ozone concentrations are used to calculate the risk to human health, in terms of the attributable fraction metric (the percentage of deaths from COPD – chronic obstructive pulmonary disease – associated with long-term exposure to elevated ozone concentrations). OSDMA8 concentrations are simulated to increase by more than 50 % across northern mid-latitude regions over the historical period, mainly driven by increases in anthropogenic emissions of NO<span class="inline-formula"><sub><i>x</i></sub></span> and global <span class="inline-formula">CH<sub>4</sub></span> concentrations. Small contributions are made from changes in other anthropogenic precursor emissions (CO and non-<span class="inline-formula">CH<sub>4</sub></span> volatile organic compounds; VOCs), aerosols, stratospheric ozone and climate change. The proportion of the global population exposed to OSDMA8 concentrations above the theoretical minimum risk exposure level (32.4 ppb) increased from <span class="inline-formula">&lt;20</span> % in 1855 to <span class="inline-formula">&gt;90</span> % in 2010. This has also increased the risk to human health mortality due to COPD from long-term ozone exposure by up to 20 % across Northern Hemisphere regions in the present day. Like for OSDMA8 concentrations, the drivers of the increase in the ozone health risks are attributed mainly to changes in NO<span class="inline-formula"><sub><i>x</i></sub></span> and global <span class="inline-formula">CH<sub>4</sub></span>. Fixing anthropogenic NO<span class="inline-formula"><sub><i>x</i></sub></span> emissions at 1850 values can eliminate the risk to human health from long-term ozone exposure in the<span id="page7112"/> near-present-day period. Understanding the historical drivers of ozone concentrations and their risk to human health can help to inform the development of future pathways that reduce this risk.</p>https://acp.copernicus.org/articles/25/7111/2025/acp-25-7111-2025.pdf
spellingShingle S. T. Turnock
S. T. Turnock
D. Akritidis
D. Akritidis
L. Horowitz
M. Mertens
A. Pozzer
A. Pozzer
C. L. Reddington
H. Wang
P. Zhou
F. O'Connor
F. O'Connor
Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)
Atmospheric Chemistry and Physics
title Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)
title_full Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)
title_fullStr Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)
title_full_unstemmed Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)
title_short Drivers of change in peak-season surface ozone concentrations and impacts on human health over the historical period (1850–2014)
title_sort drivers of change in peak season surface ozone concentrations and impacts on human health over the historical period 1850 2014
url https://acp.copernicus.org/articles/25/7111/2025/acp-25-7111-2025.pdf
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