New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents

A new three-parameter isotherm equation to describe multilayer adsorption of vapours on non-porous adsorbants is derived. The model parameters are the monolayer adsorption capacity ( m ) and two temperature dependent constants, C 1 and C ∞ , which describe the adsorbate-surface interactions in, resp...

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Main Author: S. Sircar
Format: Article
Language:English
Published: SAGE Publishing 1985-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361748500200103
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author S. Sircar
author_facet S. Sircar
author_sort S. Sircar
collection DOAJ
description A new three-parameter isotherm equation to describe multilayer adsorption of vapours on non-porous adsorbants is derived. The model parameters are the monolayer adsorption capacity ( m ) and two temperature dependent constants, C 1 and C ∞ , which describe the adsorbate-surface interactions in, respectively, the first and the subsequent layers. The model can successfully describe the data for multilayer adsorption of ethanol, benzene and cyclohexane on cabosil in the entire relative saturation pressure range of zero to unity.
format Article
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institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 1985-03-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-7f8a271f696d45a6ba389d71954c18902025-02-03T10:07:35ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381985-03-01210.1177/026361748500200103New Isotherm for Multilayer Adsorption of Vapours on Non-Porous AdsorbentsS. SircarA new three-parameter isotherm equation to describe multilayer adsorption of vapours on non-porous adsorbants is derived. The model parameters are the monolayer adsorption capacity ( m ) and two temperature dependent constants, C 1 and C ∞ , which describe the adsorbate-surface interactions in, respectively, the first and the subsequent layers. The model can successfully describe the data for multilayer adsorption of ethanol, benzene and cyclohexane on cabosil in the entire relative saturation pressure range of zero to unity.https://doi.org/10.1177/026361748500200103
spellingShingle S. Sircar
New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
Adsorption Science & Technology
title New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
title_full New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
title_fullStr New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
title_full_unstemmed New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
title_short New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
title_sort new isotherm for multilayer adsorption of vapours on non porous adsorbents
url https://doi.org/10.1177/026361748500200103
work_keys_str_mv AT ssircar newisothermformultilayeradsorptionofvapoursonnonporousadsorbents