Regulating mechanical properties of laser powder bed fusion manufactured CoCrFeMnNi high-entropy alloy using oversaturated boron doping

The laser powder bed fusion (LPBF) manufactured CoCrFeMnNi high-entropy alloy (HEA) presents potential application at cryogenic temperatures, except for a relatively low yield strength (σy). In this work, we proposed an oversaturated boron-doping strategy to overcome this insufficiency. Compared to...

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Bibliographic Details
Main Authors: Ruize Zhang, Haihua Yao, Xin Lin, Jiahui Gao, Zhuofei Guo, Jiaxin Gong, Yu Zhao, Zhen Tan, Dingyong He, Zheng Zhou
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Virtual and Physical Prototyping
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Online Access:https://www.tandfonline.com/doi/10.1080/17452759.2025.2470923
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Summary:The laser powder bed fusion (LPBF) manufactured CoCrFeMnNi high-entropy alloy (HEA) presents potential application at cryogenic temperatures, except for a relatively low yield strength (σy). In this work, we proposed an oversaturated boron-doping strategy to overcome this insufficiency. Compared to the boron-free and high boron-doping references, the moderate boron-doping LPBF HEA exhibits high strength at temperatures of 77 and 298 K, while maintains favourable ductility, corresponding to a σy of 806 MPa with a total elongation (ϵ) of ∼20% at 298 K, and a σy of 1072 MPa with a ϵ of ∼12% at 77 K, respectively. The improved mechanical properties are attributed to the microstructures composed of refined grains, reduced cell size, oversaturation of boron and the formation of nano-sized Cr2B precipitates at cell boundaries. The grain boundary strengthening, precipitation strengthening, solid solution strengthening and dislocation strengthening contribute to the high σy. The interactions between dislocation slip and deformation twins with boride precipitates account for the enhanced strain hardening and favourable plasticity at 77 K. The results demonstrate an effective strategy to establish balanced mechanical properties of LPBF HEA, and provide an inspiration for future works aiming to develop high-performance structural materials over a wide temperature range.
ISSN:1745-2759
1745-2767