Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD

(1) The evidence is mounting that polycyclic aromatic hydrocarbons (PAHs) are a class of hazardous organic compounds with established carcinogenic and toxic properties. Humans may be exposed to PAHs through several different routes, including diet, inhalation, and dermal contact. There is also a pos...

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Main Authors: Bernard Collins Anditi, Viktória Poór, Dénes Szerencsés, István Szabó, Mátyás Wahr, Anikó Kőnig-Péter, Timea Dergez
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/29/21/5060
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author Bernard Collins Anditi
Viktória Poór
Dénes Szerencsés
István Szabó
Mátyás Wahr
Anikó Kőnig-Péter
Timea Dergez
author_facet Bernard Collins Anditi
Viktória Poór
Dénes Szerencsés
István Szabó
Mátyás Wahr
Anikó Kőnig-Péter
Timea Dergez
author_sort Bernard Collins Anditi
collection DOAJ
description (1) The evidence is mounting that polycyclic aromatic hydrocarbons (PAHs) are a class of hazardous organic compounds with established carcinogenic and toxic properties. Humans may be exposed to PAHs through several different routes, including diet, inhalation, and dermal contact. There is also a possibility that they could transfer into breast milk following maternal exposure, which could potentially endanger breastfeeding infants. (2) The objective of this study was to ascertain the concentration of polycyclic aromatic hydrocarbons (PAHs) in breast milk samples from 50 Hungarian mothers, employing high-performance liquid chromatography with fluorescence detection (HPLC–FLD). An Incremental Life Risk Calculation (IRCL) model estimated the carcinogenic risk to infants. (3) Total PAH concentrations ranged from 0 to 78 ng/mL, with fluorene (5.3 ng/mL), phenanthrene (3.2 ng/mL), and pyrene (2.5 ng/mL) being the most abundant. PAHs were detected in 48 of the 50 samples, with phenanthrene present in 92% of samples. Dibenzo (a,h)anthracene was not detected. (4) According to the model measurements, most of the samples were within acceptable risk levels; however, 2 samples out of 50 posed a higher risk. Statistical analysis of questionnaires completed by the mothers indicated that factors such as diet, residence, and education may influence PAH levels in breast milk.
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spelling doaj-art-7ee18b64db524ebebc470484dfbb47552025-08-20T02:14:23ZengMDPI AGMolecules1420-30492024-10-012921506010.3390/molecules29215060Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLDBernard Collins Anditi0Viktória Poór1Dénes Szerencsés2István Szabó3Mátyás Wahr4Anikó Kőnig-Péter5Timea Dergez6Doctoral School of Chemistry, Faculty of Sciences, University of Pécs, 7624 Pécs, HungaryInstitute of Bioanalysis, Medical School, University of Pécs, 7624 Pécs, HungaryDoctoral School of Chemistry, Faculty of Sciences, University of Pécs, 7624 Pécs, HungaryDepartment of Environmental Toxicology, Hungarian University of Agricultural and Life Sciences, 2100 Gödöllő, HungaryInstitute of Bioanalysis, Medical School, University of Pécs, 7624 Pécs, HungaryInstitute of Bioanalysis, Medical School, University of Pécs, 7624 Pécs, HungaryInstitute of Bioanalysis, Medical School, University of Pécs, 7624 Pécs, Hungary(1) The evidence is mounting that polycyclic aromatic hydrocarbons (PAHs) are a class of hazardous organic compounds with established carcinogenic and toxic properties. Humans may be exposed to PAHs through several different routes, including diet, inhalation, and dermal contact. There is also a possibility that they could transfer into breast milk following maternal exposure, which could potentially endanger breastfeeding infants. (2) The objective of this study was to ascertain the concentration of polycyclic aromatic hydrocarbons (PAHs) in breast milk samples from 50 Hungarian mothers, employing high-performance liquid chromatography with fluorescence detection (HPLC–FLD). An Incremental Life Risk Calculation (IRCL) model estimated the carcinogenic risk to infants. (3) Total PAH concentrations ranged from 0 to 78 ng/mL, with fluorene (5.3 ng/mL), phenanthrene (3.2 ng/mL), and pyrene (2.5 ng/mL) being the most abundant. PAHs were detected in 48 of the 50 samples, with phenanthrene present in 92% of samples. Dibenzo (a,h)anthracene was not detected. (4) According to the model measurements, most of the samples were within acceptable risk levels; however, 2 samples out of 50 posed a higher risk. Statistical analysis of questionnaires completed by the mothers indicated that factors such as diet, residence, and education may influence PAH levels in breast milk.https://www.mdpi.com/1420-3049/29/21/5060polycyclic aromatic hydrocarbon (PAH)HPLC–FLDbreast milktotal PAHsincremental life risk calculation (IRCL)
spellingShingle Bernard Collins Anditi
Viktória Poór
Dénes Szerencsés
István Szabó
Mátyás Wahr
Anikó Kőnig-Péter
Timea Dergez
Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD
Molecules
polycyclic aromatic hydrocarbon (PAH)
HPLC–FLD
breast milk
total PAHs
incremental life risk calculation (IRCL)
title Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD
title_full Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD
title_fullStr Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD
title_full_unstemmed Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD
title_short Determination of PAH Contamination in Breast Milk Samples from Hungarian Volunteering Mothers, Using HPLC–FLD
title_sort determination of pah contamination in breast milk samples from hungarian volunteering mothers using hplc fld
topic polycyclic aromatic hydrocarbon (PAH)
HPLC–FLD
breast milk
total PAHs
incremental life risk calculation (IRCL)
url https://www.mdpi.com/1420-3049/29/21/5060
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