Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand
The use of polydentate macrocyclic Lewis bases is a way to contribute to determine the coordination number of metal complexes. In this sense, hexadentate <i>N</i><sub>6</sub> donors can help to achieve lanthanoid complexes with coordination number 8. But the geometry of these...
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MDPI AG
2023-11-01
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| author | Cristina González-Barreira Julio Corredoira-Vázquez Ana M. García-Deibe Matilde Fondo |
| author_facet | Cristina González-Barreira Julio Corredoira-Vázquez Ana M. García-Deibe Matilde Fondo |
| author_sort | Cristina González-Barreira |
| collection | DOAJ |
| description | The use of polydentate macrocyclic Lewis bases is a way to contribute to determine the coordination number of metal complexes. In this sense, hexadentate <i>N</i><sub>6</sub> donors can help to achieve lanthanoid complexes with coordination number 8. But the geometry of these complexes depends on the flexibility of the bases. Accordingly, in this communication we present the synthesis and crystallographic characterization of the dysprosium complex [DyL<sup>N6</sup>Cl<sub>2</sub>]Cl·2H<sub>2</sub>O, where L<sup>N6</sup> is a flexible hexaaza donor. |
| format | Article |
| id | doaj-art-7ed0f87eb40b4a72b8b9296cd790d860 |
| institution | DOAJ |
| issn | 2673-4583 |
| language | English |
| publishDate | 2023-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry Proceedings |
| spelling | doaj-art-7ed0f87eb40b4a72b8b9296cd790d8602025-08-20T02:56:06ZengMDPI AGChemistry Proceedings2673-45832023-11-011412310.3390/ecsoc-27-16143Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine LigandCristina González-Barreira0Julio Corredoira-Vázquez1Ana M. García-Deibe2Matilde Fondo3Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainThe use of polydentate macrocyclic Lewis bases is a way to contribute to determine the coordination number of metal complexes. In this sense, hexadentate <i>N</i><sub>6</sub> donors can help to achieve lanthanoid complexes with coordination number 8. But the geometry of these complexes depends on the flexibility of the bases. Accordingly, in this communication we present the synthesis and crystallographic characterization of the dysprosium complex [DyL<sup>N6</sup>Cl<sub>2</sub>]Cl·2H<sub>2</sub>O, where L<sup>N6</sup> is a flexible hexaaza donor.https://www.mdpi.com/2673-4583/14/1/23hexaaza donordysprosiumflexible macrocycle |
| spellingShingle | Cristina González-Barreira Julio Corredoira-Vázquez Ana M. García-Deibe Matilde Fondo Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand Chemistry Proceedings hexaaza donor dysprosium flexible macrocycle |
| title | Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand |
| title_full | Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand |
| title_fullStr | Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand |
| title_full_unstemmed | Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand |
| title_short | Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand |
| title_sort | synthesis of a dysprosium iii complex with a hexadentate amine ligand |
| topic | hexaaza donor dysprosium flexible macrocycle |
| url | https://www.mdpi.com/2673-4583/14/1/23 |
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