Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies

The removal of malachite green (MG) by cocoa (Theobroma cacao) shell activated carbon (CSAC) was investigated in present study. Adsorption studies were performed by batch experiments as a function of process parameters such as initial pH, contact time, initial concentration and adsorbent dose. A com...

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Main Authors: C. Theivarasu, S. Mylsamy
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/714808
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author C. Theivarasu
S. Mylsamy
author_facet C. Theivarasu
S. Mylsamy
author_sort C. Theivarasu
collection DOAJ
description The removal of malachite green (MG) by cocoa (Theobroma cacao) shell activated carbon (CSAC) was investigated in present study. Adsorption studies were performed by batch experiments as a function of process parameters such as initial pH, contact time, initial concentration and adsorbent dose. A comparison of kinetic models applied to the adsorption of MG on CSAC was evaluated for the pseudo-first order and pseudo-second order kinetic models. Results showed that the pseudo-second order kinetic model was found to correlate the experimental data well. The experimental equilibrium adsorption data was represented with Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich and Flory-Huggins isotherms. The experimental data obtained in the present study indicated that activated carbon developed from cocoa shell can be attractive options for dye removal from waste water.
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spelling doaj-art-7dc1cf1e67dd441885c5e1e97d6568d12025-02-03T05:47:51ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018S1S363S37110.1155/2011/714808Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium StudiesC. Theivarasu0S. Mylsamy1Department of Chemistry, PSG College of Technology, Coimbatore-641 004, IndiaDepartment of Chemistry, PSG College of Technology, Coimbatore-641 004, IndiaThe removal of malachite green (MG) by cocoa (Theobroma cacao) shell activated carbon (CSAC) was investigated in present study. Adsorption studies were performed by batch experiments as a function of process parameters such as initial pH, contact time, initial concentration and adsorbent dose. A comparison of kinetic models applied to the adsorption of MG on CSAC was evaluated for the pseudo-first order and pseudo-second order kinetic models. Results showed that the pseudo-second order kinetic model was found to correlate the experimental data well. The experimental equilibrium adsorption data was represented with Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich and Flory-Huggins isotherms. The experimental data obtained in the present study indicated that activated carbon developed from cocoa shell can be attractive options for dye removal from waste water.http://dx.doi.org/10.1155/2011/714808
spellingShingle C. Theivarasu
S. Mylsamy
Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies
E-Journal of Chemistry
title Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies
title_full Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies
title_fullStr Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies
title_full_unstemmed Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies
title_short Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies
title_sort removal of malachite green from aqueous solution by activated carbon developed from cocoa theobroma cacao shell a kinetic and equilibrium studies
url http://dx.doi.org/10.1155/2011/714808
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AT smylsamy removalofmalachitegreenfromaqueoussolutionbyactivatedcarbondevelopedfromcocoatheobromacacaoshellakineticandequilibriumstudies