High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy

Infrared (IR) spectroscopy is a powerful, nondestructive analytical technique that requires cost‐effective and highly sensitive IR photodetectors (PDs). Herein, complementary metal‐oxide‐semiconductor (CMOS)‐compatible GeSn p–i–n PDs with record‐high detectivity (D*) are presented, offering a broad...

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Main Authors: Meng‐Hsien Chou, Radhika Bansal, Yue‐Tong Jheng, Greg Sun, Wei Du, Shui‐Qing Yu, Guo‐En Chang
Format: Article
Language:English
Published: Wiley-VCH 2025-06-01
Series:Advanced Photonics Research
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Online Access:https://doi.org/10.1002/adpr.202400155
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author Meng‐Hsien Chou
Radhika Bansal
Yue‐Tong Jheng
Greg Sun
Wei Du
Shui‐Qing Yu
Guo‐En Chang
author_facet Meng‐Hsien Chou
Radhika Bansal
Yue‐Tong Jheng
Greg Sun
Wei Du
Shui‐Qing Yu
Guo‐En Chang
author_sort Meng‐Hsien Chou
collection DOAJ
description Infrared (IR) spectroscopy is a powerful, nondestructive analytical technique that requires cost‐effective and highly sensitive IR photodetectors (PDs). Herein, complementary metal‐oxide‐semiconductor (CMOS)‐compatible GeSn p–i–n PDs with record‐high detectivity (D*) are presented, offering a broad photodetection range that spans the mid‐IR region. With 10% Sn incorporation, the photodetection range extends to 2680 nm. By introducing a composition‐graded GeSn buffer to enhance the material quality and increasing the thickness of the GeSn active layer to 1490 nm, optical responsivity and dark current are significantly improved, thereby achieving record‐high D* values of 3.15×109 cm·Hz1/2 W−1 and 1.19×1010 cm·Hz1/2 W−1 at T = 300 K and T = 77 K, respectively. Leveraging these record‐high D* levels, the capability of GeSn PDs in IR spectroscopy is demonstrated, which can resolve weak photoluminescence from Ge, confirming their effectiveness for sensitive IR detection.
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institution OA Journals
issn 2699-9293
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publisher Wiley-VCH
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series Advanced Photonics Research
spelling doaj-art-7ceee5954ea340289402cd6f1f865d9d2025-08-20T02:33:15ZengWiley-VCHAdvanced Photonics Research2699-92932025-06-0166n/an/a10.1002/adpr.202400155High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared SpectroscopyMeng‐Hsien Chou0Radhika Bansal1Yue‐Tong Jheng2Greg Sun3Wei Du4Shui‐Qing Yu5Guo‐En Chang6Department of Mechanical Engineering and Advanced Institute of Manufacturing with High‐Tech Innovations (AIM‐HI) National Chung Cheng University Chiayi County 62102 TaiwanDepartment of Mechanical Engineering and Advanced Institute of Manufacturing with High‐Tech Innovations (AIM‐HI) National Chung Cheng University Chiayi County 62102 TaiwanDepartment of Mechanical Engineering and Advanced Institute of Manufacturing with High‐Tech Innovations (AIM‐HI) National Chung Cheng University Chiayi County 62102 TaiwanDepartment of Engineering University of Massachusetts—Boston Boston MA 02125 USADepartment of Electrical Engineering and Computer Science University of Arkansas Fayetteville AR 72701 USADepartment of Electrical Engineering and Computer Science University of Arkansas Fayetteville AR 72701 USADepartment of Mechanical Engineering and Advanced Institute of Manufacturing with High‐Tech Innovations (AIM‐HI) National Chung Cheng University Chiayi County 62102 TaiwanInfrared (IR) spectroscopy is a powerful, nondestructive analytical technique that requires cost‐effective and highly sensitive IR photodetectors (PDs). Herein, complementary metal‐oxide‐semiconductor (CMOS)‐compatible GeSn p–i–n PDs with record‐high detectivity (D*) are presented, offering a broad photodetection range that spans the mid‐IR region. With 10% Sn incorporation, the photodetection range extends to 2680 nm. By introducing a composition‐graded GeSn buffer to enhance the material quality and increasing the thickness of the GeSn active layer to 1490 nm, optical responsivity and dark current are significantly improved, thereby achieving record‐high D* values of 3.15×109 cm·Hz1/2 W−1 and 1.19×1010 cm·Hz1/2 W−1 at T = 300 K and T = 77 K, respectively. Leveraging these record‐high D* levels, the capability of GeSn PDs in IR spectroscopy is demonstrated, which can resolve weak photoluminescence from Ge, confirming their effectiveness for sensitive IR detection.https://doi.org/10.1002/adpr.202400155detectivityGeSn alloysinfrared spectroscopymid‐infraredphotodetectors
spellingShingle Meng‐Hsien Chou
Radhika Bansal
Yue‐Tong Jheng
Greg Sun
Wei Du
Shui‐Qing Yu
Guo‐En Chang
High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy
Advanced Photonics Research
detectivity
GeSn alloys
infrared spectroscopy
mid‐infrared
photodetectors
title High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy
title_full High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy
title_fullStr High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy
title_full_unstemmed High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy
title_short High‐Detectivity GeSn Mid‐Infrared Photodetectors for Sensitive Infrared Spectroscopy
title_sort high detectivity gesn mid infrared photodetectors for sensitive infrared spectroscopy
topic detectivity
GeSn alloys
infrared spectroscopy
mid‐infrared
photodetectors
url https://doi.org/10.1002/adpr.202400155
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