Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process
This study aims to develop a single-cell prototype of a bulk all-solid-state electrolyte lithium-ion battery (ASSELIB) using the multi-layer co-fired ceramic (MLCC) method. The primary active materials selected for these experiments were as follows: i) solid-state electrolyte material: lithium alumi...
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University of Novi Sad
2025-03-01
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| Series: | Processing and Application of Ceramics |
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| Online Access: | https://doiserbia.nb.rs/img/doi/1820-6131/2025/1820-61312501094S.pdf |
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| author | Shieh Derrick Wang Sea-Fue Chi Po-Wei Hsu Yung-Fu Wu Kuen Maw |
| author_facet | Shieh Derrick Wang Sea-Fue Chi Po-Wei Hsu Yung-Fu Wu Kuen Maw |
| author_sort | Shieh Derrick |
| collection | DOAJ |
| description | This study aims to develop a single-cell prototype of a bulk all-solid-state electrolyte lithium-ion battery (ASSELIB) using the multi-layer co-fired ceramic (MLCC) method. The primary active materials selected for these experiments were as follows: i) solid-state electrolyte material: lithium aluminium titanium phosphate (Li1.3Al0.3Ti1.7(PO4)3, LATP) with a NaSICON structure, ii) cathode material: lithium nickel cobalt manganese oxide (LiNi0.8Co0.1Mn0.1O2, NCM) and iii) anode material: a mixture of lithium titanium oxide (Li4Ti5O12, LTO) with a spinel structure and titanium dioxide with a rutile structure (R-TiO2). The powders of these three components were sequentially layered into a specific mould, forming three distinct layers: cathode, electrolyte and anode. The electrolyte layer was placed between the cathode and anode layers to ensure effective separation and prevent direct contact. The layered sample was then subjected to high pressure, creating a solid laminated bulk structure. At high temperatures, the solid components were co-sintered to form a well-connected interface that allows lithium ions to migrate smoothly across the electrolyte, moving between the cathode and anode. In this study, influences of different composition of ASSELIB layers and different co-fired temperatures (600, 650, 700, 750 and 800°C) on the performances of the ASSELIB single cell were investigated. The battery’s physical properties, density changes and electrochemical characteristics were evaluated, including the formation quality of solid interfaces between each layer, ensuring no chemical interaction between components. Future work will be focused on optimizing the cell by adjusting experimental parameters for enhanced performance. |
| format | Article |
| id | doaj-art-7ced313599a64e63ab735edd05fa1110 |
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| issn | 1820-6131 2406-1034 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | University of Novi Sad |
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| series | Processing and Application of Ceramics |
| spelling | doaj-art-7ced313599a64e63ab735edd05fa11102025-08-20T02:32:10ZengUniversity of Novi SadProcessing and Application of Ceramics1820-61312406-10342025-03-011919410710.2298/PAC2501094SPreparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired processShieh Derrick0https://orcid.org/0009-0002-6672-9534Wang Sea-Fue1https://orcid.org/0000-0002-1211-7519Chi Po-Wei2https://orcid.org/0000-0002-5990-662XHsu Yung-Fu3https://orcid.org/0000-0001-8685-5437Wu Kuen Maw4https://orcid.org/0000-0001-6681-0098Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taipei, ROCDepartment of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taipei, ROCInstitute of Physics, Academia Sinica, Taipei, ROCDepartment of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taipei, ROCInstitute of Physics, Academia Sinica, Taipei, ROCThis study aims to develop a single-cell prototype of a bulk all-solid-state electrolyte lithium-ion battery (ASSELIB) using the multi-layer co-fired ceramic (MLCC) method. The primary active materials selected for these experiments were as follows: i) solid-state electrolyte material: lithium aluminium titanium phosphate (Li1.3Al0.3Ti1.7(PO4)3, LATP) with a NaSICON structure, ii) cathode material: lithium nickel cobalt manganese oxide (LiNi0.8Co0.1Mn0.1O2, NCM) and iii) anode material: a mixture of lithium titanium oxide (Li4Ti5O12, LTO) with a spinel structure and titanium dioxide with a rutile structure (R-TiO2). The powders of these three components were sequentially layered into a specific mould, forming three distinct layers: cathode, electrolyte and anode. The electrolyte layer was placed between the cathode and anode layers to ensure effective separation and prevent direct contact. The layered sample was then subjected to high pressure, creating a solid laminated bulk structure. At high temperatures, the solid components were co-sintered to form a well-connected interface that allows lithium ions to migrate smoothly across the electrolyte, moving between the cathode and anode. In this study, influences of different composition of ASSELIB layers and different co-fired temperatures (600, 650, 700, 750 and 800°C) on the performances of the ASSELIB single cell were investigated. The battery’s physical properties, density changes and electrochemical characteristics were evaluated, including the formation quality of solid interfaces between each layer, ensuring no chemical interaction between components. Future work will be focused on optimizing the cell by adjusting experimental parameters for enhanced performance.https://doiserbia.nb.rs/img/doi/1820-6131/2025/1820-61312501094S.pdflithium ion batterycathode/electrolyte/anodemulti-layer co-fired ceramicsperformances |
| spellingShingle | Shieh Derrick Wang Sea-Fue Chi Po-Wei Hsu Yung-Fu Wu Kuen Maw Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process Processing and Application of Ceramics lithium ion battery cathode/electrolyte/anode multi-layer co-fired ceramics performances |
| title | Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process |
| title_full | Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process |
| title_fullStr | Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process |
| title_full_unstemmed | Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process |
| title_short | Preparation of all solid-state electrolyte lithium ion batteries by multi-layer co-fired process |
| title_sort | preparation of all solid state electrolyte lithium ion batteries by multi layer co fired process |
| topic | lithium ion battery cathode/electrolyte/anode multi-layer co-fired ceramics performances |
| url | https://doiserbia.nb.rs/img/doi/1820-6131/2025/1820-61312501094S.pdf |
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