Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures
Abstract A set of mixed metal oxide catalysts, MOx-Co3O4 (M: Fe, Mn, Cu, Ni, Cr, and Zn) enveloped in polymer nanofilms was fabricated using the solid-phase synthesis method. These catalysts were subsequently studied for their catalytic performance in the low-temperature oxidation of carbon monoxide...
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Nature Portfolio
2025-07-01
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| Online Access: | https://doi.org/10.1038/s41598-025-10737-0 |
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| author | Seyedeh Maryam Teymoori Seyed Mehdi Alavi Mehran Rezaei |
| author_facet | Seyedeh Maryam Teymoori Seyed Mehdi Alavi Mehran Rezaei |
| author_sort | Seyedeh Maryam Teymoori |
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| description | Abstract A set of mixed metal oxide catalysts, MOx-Co3O4 (M: Fe, Mn, Cu, Ni, Cr, and Zn) enveloped in polymer nanofilms was fabricated using the solid-phase synthesis method. These catalysts were subsequently studied for their catalytic performance in the low-temperature oxidation of carbon monoxide. Characterization of the catalysts was accomplished using various techniques, including X-ray diffraction (XRD), N2 adsorption-desorption, temperature-programmed reduction (H2-TPR), temperature-programmed desorption of oxygen (O2-TPD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric and differential thermal analyses (TGA and DTA) and scanning electron microscopy (FESEM). The outcomes of these investigations indicated that the composite oxides possess different characteristic features. The catalytic activity of these catalysts exhibited a decreasing trend as follows: Fe-Co > Mn-Co > Cu-Co > Ni-Co > Zn-Co > Cr-Co. Among the catalysts prepared, Fe-Co nanoparticles revealed the greatest specific surface area (138 m2.g− 1) and the largest pore volume (0.45 cm3.g− 1), resulting in the most superior catalytic activity, achieving total CO conversion at 72 °C. Additionally, the Fe-Co catalyst demonstrated exceptional long-term stability at low temperature (60 °C). Furthermore, the study investigated the impact of various parameters such as calcination temperature, CO content, gas hourly space velocity (GHSV), and pretreatment conditions. |
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| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | Nature Portfolio |
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| spelling | doaj-art-7cdece4e80564d6ba85b366d1fbbd5592025-08-20T04:03:03ZengNature PortfolioScientific Reports2045-23222025-07-0115111910.1038/s41598-025-10737-0Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperaturesSeyedeh Maryam Teymoori0Seyed Mehdi Alavi1Mehran Rezaei2College of Chemical, Petroleum and Gas Engineering, Iran University of Science and TechnologyCollege of Chemical, Petroleum and Gas Engineering, Iran University of Science and TechnologyCollege of Chemical, Petroleum and Gas Engineering, Iran University of Science and TechnologyAbstract A set of mixed metal oxide catalysts, MOx-Co3O4 (M: Fe, Mn, Cu, Ni, Cr, and Zn) enveloped in polymer nanofilms was fabricated using the solid-phase synthesis method. These catalysts were subsequently studied for their catalytic performance in the low-temperature oxidation of carbon monoxide. Characterization of the catalysts was accomplished using various techniques, including X-ray diffraction (XRD), N2 adsorption-desorption, temperature-programmed reduction (H2-TPR), temperature-programmed desorption of oxygen (O2-TPD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric and differential thermal analyses (TGA and DTA) and scanning electron microscopy (FESEM). The outcomes of these investigations indicated that the composite oxides possess different characteristic features. The catalytic activity of these catalysts exhibited a decreasing trend as follows: Fe-Co > Mn-Co > Cu-Co > Ni-Co > Zn-Co > Cr-Co. Among the catalysts prepared, Fe-Co nanoparticles revealed the greatest specific surface area (138 m2.g− 1) and the largest pore volume (0.45 cm3.g− 1), resulting in the most superior catalytic activity, achieving total CO conversion at 72 °C. Additionally, the Fe-Co catalyst demonstrated exceptional long-term stability at low temperature (60 °C). Furthermore, the study investigated the impact of various parameters such as calcination temperature, CO content, gas hourly space velocity (GHSV), and pretreatment conditions.https://doi.org/10.1038/s41598-025-10737-0Mixed oxide catalystsSolid-phase methodIronCobaltCO oxidation |
| spellingShingle | Seyedeh Maryam Teymoori Seyed Mehdi Alavi Mehran Rezaei Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures Scientific Reports Mixed oxide catalysts Solid-phase method Iron Cobalt CO oxidation |
| title | Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures |
| title_full | Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures |
| title_fullStr | Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures |
| title_full_unstemmed | Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures |
| title_short | Catalytic oxidation of CO over the MOx – Co3O4 (M: fe, mn, cu, ni, cr, and Zn) mixed oxide nanocatalysts at low temperatures |
| title_sort | catalytic oxidation of co over the mox co3o4 m fe mn cu ni cr and zn mixed oxide nanocatalysts at low temperatures |
| topic | Mixed oxide catalysts Solid-phase method Iron Cobalt CO oxidation |
| url | https://doi.org/10.1038/s41598-025-10737-0 |
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