Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi

This study explores the novel synthesis of high-density core-shell structured nanoprecipitates (NPs) within FeCrNi alloys via ion irradiation, aiming to enhance mechanical properties through NPs. We have successfully prepared NPs in FeCrNi with an average diameter of ∼15.2 nm and a number density of...

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Main Authors: Yizhou Qian, Xiaolei Ma, Kangkang Wen, Siyu Chen, Yiheng Chen, Yugang Wang, Tongde Shen, Gang Sha, Chenxu Wang
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425002753
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author Yizhou Qian
Xiaolei Ma
Kangkang Wen
Siyu Chen
Yiheng Chen
Yugang Wang
Tongde Shen
Gang Sha
Chenxu Wang
author_facet Yizhou Qian
Xiaolei Ma
Kangkang Wen
Siyu Chen
Yiheng Chen
Yugang Wang
Tongde Shen
Gang Sha
Chenxu Wang
author_sort Yizhou Qian
collection DOAJ
description This study explores the novel synthesis of high-density core-shell structured nanoprecipitates (NPs) within FeCrNi alloys via ion irradiation, aiming to enhance mechanical properties through NPs. We have successfully prepared NPs in FeCrNi with an average diameter of ∼15.2 nm and a number density of ∼2.03 × 1022 m−3 by employing ion irradiation. Transmission Electron Microscopy (TEM) and Atom Probe Tomography (APT) results show the unique core-shell structure of these NPs, consisting of Cr-rich M23C6 carbides cores and Ni-rich shells. The ion irradiation process facilitated the controlled formation of these nanostructures by inducing localized vacancies, which allowed the nucleation and growth of NPs uniformly distributed within the alloy matrix. This synthesis method overcomes traditional limitations posed by thermodynamic constraints and grain boundary (GB) agglomeration, providing a potential pathway for the precise tailoring of microstructures. The combination of APT and TEM analysis offers detailed insight into the structural evolution of the core-shell NPs. These findings represent ion irradiation as an effective technique for fabricating novel nanostructures and hold potential for further improvements in mechanical properties, particularly in the strength, of FeCrNi alloys. Future studies will focus on evaluating the impact of varying irradiation parameters and carbon content on the structural and mechanical characteristics of these alloys.
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institution Kabale University
issn 2238-7854
language English
publishDate 2025-03-01
publisher Elsevier
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series Journal of Materials Research and Technology
spelling doaj-art-7b08742f27484021bbd03b2d3e815ca52025-02-10T04:34:25ZengElsevierJournal of Materials Research and Technology2238-78542025-03-013532363244Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNiYizhou Qian0Xiaolei Ma1Kangkang Wen2Siyu Chen3Yiheng Chen4Yugang Wang5Tongde Shen6Gang Sha7Chenxu Wang8State Key Laboratory of Nuclear Physics and Technology, Center for Applied Physics and Technology, Peking University, Beijing, 100871, ChinaState Key Laboratory of Nuclear Physics and Technology, Center for Applied Physics and Technology, Peking University, Beijing, 100871, China; Corresponding author.Clean Nano Energy Center, State Key Laboratory of Metastable Materials Technology and Science, Yanshan University, Qinhuangdao, 066004, ChinaDepartment of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, ChinaState Key Laboratory of Nuclear Physics and Technology, Center for Applied Physics and Technology, Peking University, Beijing, 100871, ChinaState Key Laboratory of Nuclear Physics and Technology, Center for Applied Physics and Technology, Peking University, Beijing, 100871, ChinaClean Nano Energy Center, State Key Laboratory of Metastable Materials Technology and Science, Yanshan University, Qinhuangdao, 066004, ChinaDepartment of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, ChinaState Key Laboratory of Nuclear Physics and Technology, Center for Applied Physics and Technology, Peking University, Beijing, 100871, China; Corresponding author.This study explores the novel synthesis of high-density core-shell structured nanoprecipitates (NPs) within FeCrNi alloys via ion irradiation, aiming to enhance mechanical properties through NPs. We have successfully prepared NPs in FeCrNi with an average diameter of ∼15.2 nm and a number density of ∼2.03 × 1022 m−3 by employing ion irradiation. Transmission Electron Microscopy (TEM) and Atom Probe Tomography (APT) results show the unique core-shell structure of these NPs, consisting of Cr-rich M23C6 carbides cores and Ni-rich shells. The ion irradiation process facilitated the controlled formation of these nanostructures by inducing localized vacancies, which allowed the nucleation and growth of NPs uniformly distributed within the alloy matrix. This synthesis method overcomes traditional limitations posed by thermodynamic constraints and grain boundary (GB) agglomeration, providing a potential pathway for the precise tailoring of microstructures. The combination of APT and TEM analysis offers detailed insight into the structural evolution of the core-shell NPs. These findings represent ion irradiation as an effective technique for fabricating novel nanostructures and hold potential for further improvements in mechanical properties, particularly in the strength, of FeCrNi alloys. Future studies will focus on evaluating the impact of varying irradiation parameters and carbon content on the structural and mechanical characteristics of these alloys.http://www.sciencedirect.com/science/article/pii/S2238785425002753FeCrNi alloysIon irradiationMicrostructureNanoprecipitatesCore-shell structure
spellingShingle Yizhou Qian
Xiaolei Ma
Kangkang Wen
Siyu Chen
Yiheng Chen
Yugang Wang
Tongde Shen
Gang Sha
Chenxu Wang
Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi
Journal of Materials Research and Technology
FeCrNi alloys
Ion irradiation
Microstructure
Nanoprecipitates
Core-shell structure
title Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi
title_full Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi
title_fullStr Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi
title_full_unstemmed Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi
title_short Ion irradiation introduced high-density core-shell structured nanoprecipitates in FeCrNi
title_sort ion irradiation introduced high density core shell structured nanoprecipitates in fecrni
topic FeCrNi alloys
Ion irradiation
Microstructure
Nanoprecipitates
Core-shell structure
url http://www.sciencedirect.com/science/article/pii/S2238785425002753
work_keys_str_mv AT yizhouqian ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT xiaoleima ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT kangkangwen ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT siyuchen ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT yihengchen ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT yugangwang ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT tongdeshen ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT gangsha ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni
AT chenxuwang ionirradiationintroducedhighdensitycoreshellstructurednanoprecipitatesinfecrni