Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts
Activated carbon (AC) was modified by H2SO4 and used as a support for catalyst. The Fe2S3/AC-T catalyst was prepared by deposition-precipitation method and used to catalyze hydrocracking of coal-related model compound, di(1-naphthyl)methane (DNM). The properties of catalyst were studied by N2 adsorp...
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| Format: | Article |
| Language: | English |
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Wiley
2017-01-01
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| Series: | Journal of Spectroscopy |
| Online Access: | http://dx.doi.org/10.1155/2017/9860619 |
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| author | Ruiyu Wang Fei Wang Ling Liu |
| author_facet | Ruiyu Wang Fei Wang Ling Liu |
| author_sort | Ruiyu Wang |
| collection | DOAJ |
| description | Activated carbon (AC) was modified by H2SO4 and used as a support for catalyst. The Fe2S3/AC-T catalyst was prepared by deposition-precipitation method and used to catalyze hydrocracking of coal-related model compound, di(1-naphthyl)methane (DNM). The properties of catalyst were studied by N2 adsorption-desorption, X-ray diffraction, and scanning electron microscopy. The result showed that ferric sulfate and acidic centers had synergetic effect on hydrocracking of DNM when using Fe2S3/AC-T as catalyst, the optimal loading of Fe is 9 wt.%. Hydroconversion of the extraction residue from Guizhou bituminous coal was also studied using Fe2S3/AC-T as the catalyst. The reaction was conducted in cyclohexane under 0.8 Mpa of initial hydrogen pressure at 310°C. The reaction mixture was extracted with petroleum ether and analyzed by GC/MS. Amounts of organic compounds which fall into the categories of homologues of benzene and naphthalene were detected. It suggested that the catalyst could effectively catalyze the cleavage of C-C-bridged bonds. |
| format | Article |
| id | doaj-art-7af28caad24340e8bd6937d908d6a384 |
| institution | Kabale University |
| issn | 2314-4920 2314-4939 |
| language | English |
| publishDate | 2017-01-01 |
| publisher | Wiley |
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| series | Journal of Spectroscopy |
| spelling | doaj-art-7af28caad24340e8bd6937d908d6a3842025-02-03T05:43:59ZengWileyJournal of Spectroscopy2314-49202314-49392017-01-01201710.1155/2017/98606199860619Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC CatalystsRuiyu Wang0Fei Wang1Ling Liu2Key Laboratory of Coal-Based CO2 Capture and Geological Storage of Jiangsu Province, China University of Mining & Technology, Xuzhou, Jiangsu 221008, ChinaSchool of Chemical Engineering and Technology, China University of Mining & Technology, Xuzhou, Jiangsu 221116, ChinaKey Laboratory of Coal-Based CO2 Capture and Geological Storage of Jiangsu Province, China University of Mining & Technology, Xuzhou, Jiangsu 221008, ChinaActivated carbon (AC) was modified by H2SO4 and used as a support for catalyst. The Fe2S3/AC-T catalyst was prepared by deposition-precipitation method and used to catalyze hydrocracking of coal-related model compound, di(1-naphthyl)methane (DNM). The properties of catalyst were studied by N2 adsorption-desorption, X-ray diffraction, and scanning electron microscopy. The result showed that ferric sulfate and acidic centers had synergetic effect on hydrocracking of DNM when using Fe2S3/AC-T as catalyst, the optimal loading of Fe is 9 wt.%. Hydroconversion of the extraction residue from Guizhou bituminous coal was also studied using Fe2S3/AC-T as the catalyst. The reaction was conducted in cyclohexane under 0.8 Mpa of initial hydrogen pressure at 310°C. The reaction mixture was extracted with petroleum ether and analyzed by GC/MS. Amounts of organic compounds which fall into the categories of homologues of benzene and naphthalene were detected. It suggested that the catalyst could effectively catalyze the cleavage of C-C-bridged bonds.http://dx.doi.org/10.1155/2017/9860619 |
| spellingShingle | Ruiyu Wang Fei Wang Ling Liu Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts Journal of Spectroscopy |
| title | Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts |
| title_full | Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts |
| title_fullStr | Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts |
| title_full_unstemmed | Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts |
| title_short | Effect of Pretreatment with Sulfuric Acid on Catalytic Hydrocracking of Fe/AC Catalysts |
| title_sort | effect of pretreatment with sulfuric acid on catalytic hydrocracking of fe ac catalysts |
| url | http://dx.doi.org/10.1155/2017/9860619 |
| work_keys_str_mv | AT ruiyuwang effectofpretreatmentwithsulfuricacidoncatalytichydrocrackingoffeaccatalysts AT feiwang effectofpretreatmentwithsulfuricacidoncatalytichydrocrackingoffeaccatalysts AT lingliu effectofpretreatmentwithsulfuricacidoncatalytichydrocrackingoffeaccatalysts |