Modeling the kinetics of pyrolysis of date seeds using artificial neural networks

<p>Ground date seeds were subjected to thermal analysis in a stream of Nitrogen at four different heating rates (5, 10, 15 and 20oC.min-1 ) and their TG – DTG patterns were obtained. Two peaks showed up for the degradation of lignocellulosic components. Three iso-conversional methods were used...

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Main Authors: R. A. Felobes, Magdy Abadir
Format: Article
Language:English
Published: Academy Publishing Center 2024-05-01
Series:Renewable Energy and Sustainable Development
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Online Access:http://apc.aast.edu/ojs/index.php/RESD/article/view/811
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author R. A. Felobes
Magdy Abadir
author_facet R. A. Felobes
Magdy Abadir
author_sort R. A. Felobes
collection DOAJ
description <p>Ground date seeds were subjected to thermal analysis in a stream of Nitrogen at four different heating rates (5, 10, 15 and 20oC.min-1 ) and their TG – DTG patterns were obtained. Two peaks showed up for the degradation of lignocellulosic components. Three iso-conversional methods were used to obtain the activation energy of these steps, namely the Flynn-Wall-Ozawa (FWO), the Kissinger-Asahira-Sunoze (KAS) and the Friedmann methods. The values of activation energy for the first step of degradation varied from 113.76 to 117.80 kJ.mol-1 , depending on the method of calculation. For the second step, the corresponding values were 130.99, 123.07 and 127.52 kJ.mol-1 . At the end of the second peak, biochar was formed that went on cracking off its more volatile constituents at higher temperatures. An artificial Neural Network simulation was carried out for the first degradation step. The values obtained from that simulation for conversion – temperature curves and for biochar content were in excellent agreement with the corresponding experimental figures. However, the simulated values obtained for activation energy at different conversion levels were higher.</p><p><strong><br /></strong></p><p><strong>Received: 17 February 2024 </strong></p><p><strong>Accepted: 11 April 2024 </strong></p><p><strong>Published: 20 May 2024</strong></p>
format Article
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institution Kabale University
issn 2356-8518
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language English
publishDate 2024-05-01
publisher Academy Publishing Center
record_format Article
series Renewable Energy and Sustainable Development
spelling doaj-art-7ade81620ebd43b08b4765aeb290f9c02025-08-20T03:28:47ZengAcademy Publishing CenterRenewable Energy and Sustainable Development2356-85182356-85692024-05-0110112313410.21622/resd.2024.10.1.811355Modeling the kinetics of pyrolysis of date seeds using artificial neural networksR. A. Felobes0Magdy Abadir1Chemical Engineering department Higher Technological InstituteThe Chemical Engineering Department, Faculty of Engineering, Cairo University, Giza, Cairo, Egypt<p>Ground date seeds were subjected to thermal analysis in a stream of Nitrogen at four different heating rates (5, 10, 15 and 20oC.min-1 ) and their TG – DTG patterns were obtained. Two peaks showed up for the degradation of lignocellulosic components. Three iso-conversional methods were used to obtain the activation energy of these steps, namely the Flynn-Wall-Ozawa (FWO), the Kissinger-Asahira-Sunoze (KAS) and the Friedmann methods. The values of activation energy for the first step of degradation varied from 113.76 to 117.80 kJ.mol-1 , depending on the method of calculation. For the second step, the corresponding values were 130.99, 123.07 and 127.52 kJ.mol-1 . At the end of the second peak, biochar was formed that went on cracking off its more volatile constituents at higher temperatures. An artificial Neural Network simulation was carried out for the first degradation step. The values obtained from that simulation for conversion – temperature curves and for biochar content were in excellent agreement with the corresponding experimental figures. However, the simulated values obtained for activation energy at different conversion levels were higher.</p><p><strong><br /></strong></p><p><strong>Received: 17 February 2024 </strong></p><p><strong>Accepted: 11 April 2024 </strong></p><p><strong>Published: 20 May 2024</strong></p>http://apc.aast.edu/ojs/index.php/RESD/article/view/811pyrolysis , date seeds , conversion, percent biochar , activation energy , ann simulation
spellingShingle R. A. Felobes
Magdy Abadir
Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
Renewable Energy and Sustainable Development
pyrolysis , date seeds , conversion, percent biochar , activation energy , ann simulation
title Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
title_full Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
title_fullStr Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
title_full_unstemmed Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
title_short Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
title_sort modeling the kinetics of pyrolysis of date seeds using artificial neural networks
topic pyrolysis , date seeds , conversion, percent biochar , activation energy , ann simulation
url http://apc.aast.edu/ojs/index.php/RESD/article/view/811
work_keys_str_mv AT rafelobes modelingthekineticsofpyrolysisofdateseedsusingartificialneuralnetworks
AT magdyabadir modelingthekineticsofpyrolysisofdateseedsusingartificialneuralnetworks