Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies

<p>Colloidal semiconductor nanocrystals from CdSe show photoluminescence quenching via titration with porphyrin derivatives. This quenching is an indication of the formation of nanoassemblies via surface attachment of pyridyl linker groups. As a consequence of the complex formation, dynamic an...

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Format: Article
Language:English
Published: Wiley 2006-01-01
Series:International Journal of Photoenergy
Online Access:http://www.hindawi.com/GetArticle.aspx?doi=10.1155/IJP/2006/90242
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description <p>Colloidal semiconductor nanocrystals from CdSe show photoluminescence quenching via titration with porphyrin derivatives. This quenching is an indication of the formation of nanoassemblies via surface attachment of pyridyl linker groups. As a consequence of the complex formation, dynamic and/or static interactions between QD and porphyrins are induced. Quenching efficiencies depend critically on sample stability, temperature, solvent, and electronic properties of the porphyrins. In order to optimize photoinduced dynamic processes these parameters have to be under control.</p>
format Article
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issn 1110-662X
language English
publishDate 2006-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-7adbaef2b72f43b597d03b347bed8efc2025-08-20T02:07:05ZengWileyInternational Journal of Photoenergy1110-662X2006-01-012006Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies<p>Colloidal semiconductor nanocrystals from CdSe show photoluminescence quenching via titration with porphyrin derivatives. This quenching is an indication of the formation of nanoassemblies via surface attachment of pyridyl linker groups. As a consequence of the complex formation, dynamic and/or static interactions between QD and porphyrins are induced. Quenching efficiencies depend critically on sample stability, temperature, solvent, and electronic properties of the porphyrins. In order to optimize photoinduced dynamic processes these parameters have to be under control.</p>http://www.hindawi.com/GetArticle.aspx?doi=10.1155/IJP/2006/90242
spellingShingle Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies
International Journal of Photoenergy
title Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies
title_full Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies
title_fullStr Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies
title_full_unstemmed Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies
title_short Photophysical properties of self-aggregated porphyrin: semiconductor nanoassemblies
title_sort photophysical properties of self aggregated porphyrin semiconductor nanoassemblies
url http://www.hindawi.com/GetArticle.aspx?doi=10.1155/IJP/2006/90242