Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media

The time-periods required for the % of Mn(III) to disappear from the solution and the half-life of Mn(III) was studied in 7 mol dm-3 H2SO4 and 7 mol dm-3 H3PO4 media at ambient conditions at three different Mn(III) concentrations viz. 4.98, 1.94 and 1.04 mmol dm-3 using spectrophotometric method. H...

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Main Authors: Balaprasad Ankamwar, Omprakash Yemul, Shashikant Deshmukh
Format: Article
Language:English
Published: Wiley 2009-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2009/736463
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author Balaprasad Ankamwar
Omprakash Yemul
Shashikant Deshmukh
author_facet Balaprasad Ankamwar
Omprakash Yemul
Shashikant Deshmukh
author_sort Balaprasad Ankamwar
collection DOAJ
description The time-periods required for the % of Mn(III) to disappear from the solution and the half-life of Mn(III) was studied in 7 mol dm-3 H2SO4 and 7 mol dm-3 H3PO4 media at ambient conditions at three different Mn(III) concentrations viz. 4.98, 1.94 and 1.04 mmol dm-3 using spectrophotometric method. Half-life periods in the presence of 7 mol dm-3 H2SO4 are more than those in presence of 7 mol dm-3 H3PO4. The time-periods required for the 1% of Mn(III) to disappear that for H2SO4 medium from 1.94 mmol dm-3, Mn(III) solutions prepared from solid form is about 20 days, 10 days for electro-generated Mn(III) and 6 days for chemical oxidation method.
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issn 0973-4945
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publisher Wiley
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spelling doaj-art-7acf2af410a343c19caf2a8a1829c2922025-08-20T02:07:05ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-016S1S225S23410.1155/2009/736463Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 MediaBalaprasad Ankamwar0Omprakash Yemul1Shashikant Deshmukh2Department of Chemistry, Shivaji University, Kolhapur-416 004, IndiaDepartment of Chemistry, Shivaji University, Kolhapur-416 004, IndiaDepartment of Chemistry, Shivaji University, Kolhapur-416 004, IndiaThe time-periods required for the % of Mn(III) to disappear from the solution and the half-life of Mn(III) was studied in 7 mol dm-3 H2SO4 and 7 mol dm-3 H3PO4 media at ambient conditions at three different Mn(III) concentrations viz. 4.98, 1.94 and 1.04 mmol dm-3 using spectrophotometric method. Half-life periods in the presence of 7 mol dm-3 H2SO4 are more than those in presence of 7 mol dm-3 H3PO4. The time-periods required for the 1% of Mn(III) to disappear that for H2SO4 medium from 1.94 mmol dm-3, Mn(III) solutions prepared from solid form is about 20 days, 10 days for electro-generated Mn(III) and 6 days for chemical oxidation method.http://dx.doi.org/10.1155/2009/736463
spellingShingle Balaprasad Ankamwar
Omprakash Yemul
Shashikant Deshmukh
Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media
E-Journal of Chemistry
title Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media
title_full Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media
title_fullStr Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media
title_full_unstemmed Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media
title_short Comparative Study on the Stability of Mn(III) Ion Prepared by Different Methods in H2SO4 and H3PO4 Media
title_sort comparative study on the stability of mn iii ion prepared by different methods in h2so4 and h3po4 media
url http://dx.doi.org/10.1155/2009/736463
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AT omprakashyemul comparativestudyonthestabilityofmniiiionpreparedbydifferentmethodsinh2so4andh3po4media
AT shashikantdeshmukh comparativestudyonthestabilityofmniiiionpreparedbydifferentmethodsinh2so4andh3po4media