Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum

In view of the problems of environmental pollution and large consumption of reagents in traditional chalcopyrite depressant, it is of great significance to develop new depressant to achieve effective separation of copper and molybdenum. A new type of depressant GX3 was studied. The effects of PAX, d...

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Main Authors: Wentao XU, Yuemeng LIN, Baisui HAN, Haoyu XIE
Format: Article
Language:zho
Published: Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences 2025-08-01
Series:Kuangchan zonghe liyong
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Online Access:http://www.kczhly.com/en/article/doi/10.12476/kczhly.202403050087
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author Wentao XU
Yuemeng LIN
Baisui HAN
Haoyu XIE
author_facet Wentao XU
Yuemeng LIN
Baisui HAN
Haoyu XIE
author_sort Wentao XU
collection DOAJ
description In view of the problems of environmental pollution and large consumption of reagents in traditional chalcopyrite depressant, it is of great significance to develop new depressant to achieve effective separation of copper and molybdenum. A new type of depressant GX3 was studied. The effects of PAX, depressant concentration and pH value on the floatability of chalcopyrite and molybdenite and the separation performance of copper and molybdenum were investigated by single mineral and mixed mineral flotation tests. The mechanism of action between depressant and minerals was analyzed by contact angle, Zeta potential, infrared spectroscopy and X-ray photoelectron spectroscopy. The flotation results show that when the concentration of PAX is 10 mg/L, the recovery rate of chalcopyrite is reduced to 20% and the recovery rate of molybdenite is 87% when the concentration of GX3 is 500 mg/L at the condition of pH value 8 ~ 12 and kerosene concentration of 20 mg/L, thus achieving efficient separation of copper and molybdenum. The mechanism study shows that GX3 can oxidize the surface of chalcopyrite to form hydrophilic oxides and hydroxides, which inhibits chalcopyrite, but has little effect on the hydrophobicity and surface properties of molybdenite, thus achieving effective flotation separation of copper and molybdenum.
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publishDate 2025-08-01
publisher Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences
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spelling doaj-art-7aab9f9a117a46c8afc76e4b2a88c09e2025-08-25T08:13:18ZzhoInstitute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesKuangchan zonghe liyong1000-65322025-08-01464919910.12476/kczhly.2024030500872025-04xuwentaoEffect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and MolybdenumWentao XU0Yuemeng LIN1Baisui HAN2Haoyu XIE3School of Mining Engineering, University of Science and Technology Liaoning, Anshan, Liaoning 110451, ChinaSchool of Mining Engineering, University of Science and Technology Liaoning, Anshan, Liaoning 110451, ChinaSchool of Mining Engineering, University of Science and Technology Liaoning, Anshan, Liaoning 110451, ChinaSchool of Mining Engineering, University of Science and Technology Liaoning, Anshan, Liaoning 110451, ChinaIn view of the problems of environmental pollution and large consumption of reagents in traditional chalcopyrite depressant, it is of great significance to develop new depressant to achieve effective separation of copper and molybdenum. A new type of depressant GX3 was studied. The effects of PAX, depressant concentration and pH value on the floatability of chalcopyrite and molybdenite and the separation performance of copper and molybdenum were investigated by single mineral and mixed mineral flotation tests. The mechanism of action between depressant and minerals was analyzed by contact angle, Zeta potential, infrared spectroscopy and X-ray photoelectron spectroscopy. The flotation results show that when the concentration of PAX is 10 mg/L, the recovery rate of chalcopyrite is reduced to 20% and the recovery rate of molybdenite is 87% when the concentration of GX3 is 500 mg/L at the condition of pH value 8 ~ 12 and kerosene concentration of 20 mg/L, thus achieving efficient separation of copper and molybdenum. The mechanism study shows that GX3 can oxidize the surface of chalcopyrite to form hydrophilic oxides and hydroxides, which inhibits chalcopyrite, but has little effect on the hydrophobicity and surface properties of molybdenite, thus achieving effective flotation separation of copper and molybdenum.http://www.kczhly.com/en/article/doi/10.12476/kczhly.202403050087chalcopyritemolybdenitecu-mo separationdepressantmechanism
spellingShingle Wentao XU
Yuemeng LIN
Baisui HAN
Haoyu XIE
Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum
Kuangchan zonghe liyong
chalcopyrite
molybdenite
cu-mo separation
depressant
mechanism
title Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum
title_full Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum
title_fullStr Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum
title_full_unstemmed Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum
title_short Effect and Mechanism of New Chalcopyrite Depressant GX3 on Flotation Separation of Copper and Molybdenum
title_sort effect and mechanism of new chalcopyrite depressant gx3 on flotation separation of copper and molybdenum
topic chalcopyrite
molybdenite
cu-mo separation
depressant
mechanism
url http://www.kczhly.com/en/article/doi/10.12476/kczhly.202403050087
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