Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate
Cellulose was dissolved in an aqueous solution of sodium hydroxide (NaOH) and urea followed by the addition of barium sulfate (BaSO4) to yield the BaSO4/cellulose composite particles. The morphology, particle size, and BaSO4 content of the composite particles were adjusted by controlling the feed ra...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2013/312615 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849408756233797632 |
|---|---|
| author | Wei Chen Zhaoqun Wang Xiaolin Xie Xingping Zhou Zheng-Wu Bai |
| author_facet | Wei Chen Zhaoqun Wang Xiaolin Xie Xingping Zhou Zheng-Wu Bai |
| author_sort | Wei Chen |
| collection | DOAJ |
| description | Cellulose was dissolved in an aqueous solution of sodium hydroxide (NaOH) and urea followed by the addition of barium sulfate (BaSO4) to yield the BaSO4/cellulose composite particles. The morphology, particle size, and BaSO4 content of the composite particles were adjusted by controlling the feed ratio of cellulose and BaSO4. The cellulose within the composite particles then reacted with 3,5-dimethylphenyl isocyanate. The resulting materials were utilized as the chiral stationary phases (CSPs) whose enantioseparation capabilities were evaluated by various chiral analytes. Due to the mechanical enhancement effect of BaSO4, the composite particles could be applied to the chromatographic packing materials. |
| format | Article |
| id | doaj-art-7a90c1deea024c6ba58966b1206be8e2 |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-7a90c1deea024c6ba58966b1206be8e22025-08-20T03:35:41ZengWileyInternational Journal of Polymer Science1687-94221687-94302013-01-01201310.1155/2013/312615312615Novel Composite Materials for Chiral Separation from Cellulose and Barium SulfateWei Chen0Zhaoqun Wang1Xiaolin Xie2Xingping Zhou3Zheng-Wu Bai4Key Lab for Large-Format Battery Materials and Systems, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaKey Laboratory of Green Chemical Process of the Ministry of Education, Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, ChinaKey Lab for Large-Format Battery Materials and Systems, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaKey Lab for Large-Format Battery Materials and Systems, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaKey Laboratory of Green Chemical Process of the Ministry of Education, Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, ChinaCellulose was dissolved in an aqueous solution of sodium hydroxide (NaOH) and urea followed by the addition of barium sulfate (BaSO4) to yield the BaSO4/cellulose composite particles. The morphology, particle size, and BaSO4 content of the composite particles were adjusted by controlling the feed ratio of cellulose and BaSO4. The cellulose within the composite particles then reacted with 3,5-dimethylphenyl isocyanate. The resulting materials were utilized as the chiral stationary phases (CSPs) whose enantioseparation capabilities were evaluated by various chiral analytes. Due to the mechanical enhancement effect of BaSO4, the composite particles could be applied to the chromatographic packing materials.http://dx.doi.org/10.1155/2013/312615 |
| spellingShingle | Wei Chen Zhaoqun Wang Xiaolin Xie Xingping Zhou Zheng-Wu Bai Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate International Journal of Polymer Science |
| title | Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate |
| title_full | Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate |
| title_fullStr | Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate |
| title_full_unstemmed | Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate |
| title_short | Novel Composite Materials for Chiral Separation from Cellulose and Barium Sulfate |
| title_sort | novel composite materials for chiral separation from cellulose and barium sulfate |
| url | http://dx.doi.org/10.1155/2013/312615 |
| work_keys_str_mv | AT weichen novelcompositematerialsforchiralseparationfromcelluloseandbariumsulfate AT zhaoqunwang novelcompositematerialsforchiralseparationfromcelluloseandbariumsulfate AT xiaolinxie novelcompositematerialsforchiralseparationfromcelluloseandbariumsulfate AT xingpingzhou novelcompositematerialsforchiralseparationfromcelluloseandbariumsulfate AT zhengwubai novelcompositematerialsforchiralseparationfromcelluloseandbariumsulfate |