Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology
Future alternatives for an electrode lithium borate-based glass–ceramic (GC) has been developed for rechargeable lithium-ion batteries. The composition of the GC is xNiO-(0.20-x)MnO2-0.80(Li2S:B2O3), where x varies from 0.10, 0.13, 0.15, and 0.16. The GC were fabricated using the melt-quenching tech...
Saved in:
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2025-01-01
|
| Series: | Materials Science for Energy Technologies |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2589299124000296 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850221339539931136 |
|---|---|
| author | Jintara Padchasri Sumeth Siriroj Amorntep Montreeuppathum Phakkhananan Pakawanit Nattapol Laorodphan Narong Chanlek Yingyot Poo-arporn Pinit Kidkhunthod |
| author_facet | Jintara Padchasri Sumeth Siriroj Amorntep Montreeuppathum Phakkhananan Pakawanit Nattapol Laorodphan Narong Chanlek Yingyot Poo-arporn Pinit Kidkhunthod |
| author_sort | Jintara Padchasri |
| collection | DOAJ |
| description | Future alternatives for an electrode lithium borate-based glass–ceramic (GC) has been developed for rechargeable lithium-ion batteries. The composition of the GC is xNiO-(0.20-x)MnO2-0.80(Li2S:B2O3), where x varies from 0.10, 0.13, 0.15, and 0.16. The GC were fabricated using the melt-quenching technique. The nature of the GC was determined using XRD examinations. The SEM-EDS analysis indicates the presence along with the distribution of components in the plate glasses. The battery charge/discharge tests showed that the 0.16NiO-0.04MnO2-0.8(Li2S:B2O3) (0.16Ni-0.04Mn) glass-ceramics exhibited a potential range of 0.8–1.1 V and a discharge capacity of 70 mAh.g−1 during the first cycle. Additionally, these GC demonstrated excellent cycling stability for over 100 cycles. As the same time, electrical impedance spectroscopy (EIS) measurements showed that the Li diffusion coefficient in 0.16Ni-0.04Mn GC was found to be 0.34 × 10−10 and 0.75 × 10−11 cm2.s−1 for before and after cycling, which is smaller than 0.10Ni-0.10Mn. Synchrotron-based XANES highlighted the oxidation state of Ni2+, as well as the mixing of Mn2+/3+ and S−1. The addition of Ni and Mn into the lithium-sulfur borate glass system has improved its electrochemical characteristics, making it a very interesting and economically viable option for energy storage technology electrodes. |
| format | Article |
| id | doaj-art-7a7e925838a34248abbfcca0cf368fcf |
| institution | OA Journals |
| issn | 2589-2991 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Materials Science for Energy Technologies |
| spelling | doaj-art-7a7e925838a34248abbfcca0cf368fcf2025-08-20T02:06:44ZengKeAi Communications Co., Ltd.Materials Science for Energy Technologies2589-29912025-01-01811112010.1016/j.mset.2024.11.002Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technologyJintara Padchasri0Sumeth Siriroj1Amorntep Montreeuppathum2Phakkhananan Pakawanit3Nattapol Laorodphan4Narong Chanlek5Yingyot Poo-arporn6Pinit Kidkhunthod7Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, ThailandProgram in Industrial Chemistry Innovation, Faculty of Science, Maejo University, Chiang Mai, 50290, Thailand; Corresponding authors.Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand; Corresponding authors.Future alternatives for an electrode lithium borate-based glass–ceramic (GC) has been developed for rechargeable lithium-ion batteries. The composition of the GC is xNiO-(0.20-x)MnO2-0.80(Li2S:B2O3), where x varies from 0.10, 0.13, 0.15, and 0.16. The GC were fabricated using the melt-quenching technique. The nature of the GC was determined using XRD examinations. The SEM-EDS analysis indicates the presence along with the distribution of components in the plate glasses. The battery charge/discharge tests showed that the 0.16NiO-0.04MnO2-0.8(Li2S:B2O3) (0.16Ni-0.04Mn) glass-ceramics exhibited a potential range of 0.8–1.1 V and a discharge capacity of 70 mAh.g−1 during the first cycle. Additionally, these GC demonstrated excellent cycling stability for over 100 cycles. As the same time, electrical impedance spectroscopy (EIS) measurements showed that the Li diffusion coefficient in 0.16Ni-0.04Mn GC was found to be 0.34 × 10−10 and 0.75 × 10−11 cm2.s−1 for before and after cycling, which is smaller than 0.10Ni-0.10Mn. Synchrotron-based XANES highlighted the oxidation state of Ni2+, as well as the mixing of Mn2+/3+ and S−1. The addition of Ni and Mn into the lithium-sulfur borate glass system has improved its electrochemical characteristics, making it a very interesting and economically viable option for energy storage technology electrodes.http://www.sciencedirect.com/science/article/pii/S2589299124000296Glass ceramicsGlass electrodeEnergy storage |
| spellingShingle | Jintara Padchasri Sumeth Siriroj Amorntep Montreeuppathum Phakkhananan Pakawanit Nattapol Laorodphan Narong Chanlek Yingyot Poo-arporn Pinit Kidkhunthod Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology Materials Science for Energy Technologies Glass ceramics Glass electrode Energy storage |
| title | Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology |
| title_full | Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology |
| title_fullStr | Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology |
| title_full_unstemmed | Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology |
| title_short | Li-S-B Glass-Ceramics: A Novel electrode materials for energy storage technology |
| title_sort | li s b glass ceramics a novel electrode materials for energy storage technology |
| topic | Glass ceramics Glass electrode Energy storage |
| url | http://www.sciencedirect.com/science/article/pii/S2589299124000296 |
| work_keys_str_mv | AT jintarapadchasri lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT sumethsiriroj lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT amorntepmontreeuppathum lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT phakkhanananpakawanit lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT nattapollaorodphan lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT narongchanlek lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT yingyotpooarporn lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology AT pinitkidkhunthod lisbglassceramicsanovelelectrodematerialsforenergystoragetechnology |