QUANTUM CHEMICAL STUDY ON TWO BENZIMIDAZOLE DERIVATIVES

A quantum theoretical study was done on two of benzimidazole derivatives to calculate the energetic behavior of the compounds in the gas phase, where (the density functional theory (DFT), Becke’s three-parameter exchange function and the Lee-Yang-Parr correlation function (B3LYP)) was considered to...

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Bibliographic Details
Main Authors: Fatma Kandemirli, Zaid Al-sawaff, Hakan Sezgin Sayıner
Format: Article
Language:English
Published: Amasya University 2020-07-01
Series:Journal of Amasya University the Institute of Sciences and Technology
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Online Access:https://dergipark.org.tr/en/download/article-file/1110013
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Summary:A quantum theoretical study was done on two of benzimidazole derivatives to calculate the energetic behavior of the compounds in the gas phase, where (the density functional theory (DFT), Becke’s three-parameter exchange function and the Lee-Yang-Parr correlation function (B3LYP)) was considered to calculate the quantum chemical descriptors such as (the energy gap between HOMO and LUMO, the total energy, chemical hardness, softness, electrophilicity index, electro-negativity) calculations. Besides, a theoretical study was done for the compounds, which were in Gas-phase, in order to study and examine the effect of changing the temperature of the molecule which was from (200K to 1000K) on thermodynamics properties (Enthalpy, Entropy, Heat capacity, and correlation properties).
ISSN:2717-8900