Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer
In recent years, amidyl radicals have emerged as highly efficient and versatile reagents for hydrogen atom transfer (HAT) in photocatalytic reactions. These radicals display exceptional selectivity and efficiency in abstracting hydrogen atoms from C–H, Si–H, B–H, and Ge–H, positioning them as invalu...
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2025-06-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.21.100 |
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| author | Hao-Sen Wang Lin Li Xin Chen Jian-Li Wu Kai Sun Xiao-Lan Chen Ling-Bo Qu Bing Yu |
| author_facet | Hao-Sen Wang Lin Li Xin Chen Jian-Li Wu Kai Sun Xiao-Lan Chen Ling-Bo Qu Bing Yu |
| author_sort | Hao-Sen Wang |
| collection | DOAJ |
| description | In recent years, amidyl radicals have emerged as highly efficient and versatile reagents for hydrogen atom transfer (HAT) in photocatalytic reactions. These radicals display exceptional selectivity and efficiency in abstracting hydrogen atoms from C–H, Si–H, B–H, and Ge–H, positioning them as invaluable tools in synthetic chemistry. This review summarizes the latest advancements in the photocatalyzed generation of amidyl radicals as HAT reagents, with a particular emphasis on their role in the intermolecular HAT process. We highlight key developments, mechanistic insights, and emerging strategies that harness the unique reactivity of amidyl radicals in the selective functionalization of a variety of substrates. |
| format | Article |
| id | doaj-art-79c8687bbcd3498fb4ceb822b7ccc298 |
| institution | Kabale University |
| issn | 1860-5397 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj-art-79c8687bbcd3498fb4ceb822b7ccc2982025-08-20T03:51:24ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972025-06-012111306132310.3762/bjoc.21.1001860-5397-21-100Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transferHao-Sen Wang0Lin Li1Xin Chen2Jian-Li Wu3Kai Sun4Xiao-Lan Chen5Ling-Bo Qu6Bing Yu7Medical School, Huanghe Science and Technology College, Zhengzhou, 450006, PR China College of Chemistry, Zhengzhou University, Zhengzhou 450001, PR China Institute of Chemistry, Henan Academy of Sciences, Zhengzhou 450002, PR China Medical School, Huanghe Science and Technology College, Zhengzhou, 450006, PR China College of Chemistry, Zhengzhou University, Zhengzhou 450001, PR China College of Chemistry, Zhengzhou University, Zhengzhou 450001, PR China Medical School, Huanghe Science and Technology College, Zhengzhou, 450006, PR China Medical School, Huanghe Science and Technology College, Zhengzhou, 450006, PR China In recent years, amidyl radicals have emerged as highly efficient and versatile reagents for hydrogen atom transfer (HAT) in photocatalytic reactions. These radicals display exceptional selectivity and efficiency in abstracting hydrogen atoms from C–H, Si–H, B–H, and Ge–H, positioning them as invaluable tools in synthetic chemistry. This review summarizes the latest advancements in the photocatalyzed generation of amidyl radicals as HAT reagents, with a particular emphasis on their role in the intermolecular HAT process. We highlight key developments, mechanistic insights, and emerging strategies that harness the unique reactivity of amidyl radicals in the selective functionalization of a variety of substrates.https://doi.org/10.3762/bjoc.21.100amidyl radicalsc–hhat reagentshydrogen-atom-transferlate-stage functionalization |
| spellingShingle | Hao-Sen Wang Lin Li Xin Chen Jian-Li Wu Kai Sun Xiao-Lan Chen Ling-Bo Qu Bing Yu Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer Beilstein Journal of Organic Chemistry amidyl radicals c–h hat reagents hydrogen-atom-transfer late-stage functionalization |
| title | Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer |
| title_full | Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer |
| title_fullStr | Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer |
| title_full_unstemmed | Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer |
| title_short | Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer |
| title_sort | recent advances in amidyl radical mediated photocatalytic direct intermolecular hydrogen atom transfer |
| topic | amidyl radicals c–h hat reagents hydrogen-atom-transfer late-stage functionalization |
| url | https://doi.org/10.3762/bjoc.21.100 |
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