Emissions of Perfluorinated Greenhouse Gases in Southeastern China Derived From High‐Frequency In Situ Observations

Abstract Sulfur hexafluoride (SF6), nitrogen trifluoride (NF3), and three perfluorocarbons (PFCs; CF4, C2F6, and c‐C4F8) are perfluorinated greenhouse gases (PF‐GHGs) with long atmospheric lifetimes and high global warming potentials. Using high‐frequency observations and a Bayesian inversion framew...

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Main Authors: Yuyang Chen, Bo Yao, Minde An, Ao Ding, Song Liu, Xicheng Li, Yali Li, Simon O’Doherty, Paul B. Krummel, Honglong Yang, Haibo Yu, Liqu Chen, Xin Yang, Tzung‐May Fu, Huizhong Shen, Jianhuai Ye, Chen Wang, Lei Zhu
Format: Article
Language:English
Published: Wiley 2025-03-01
Series:Geophysical Research Letters
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Online Access:https://doi.org/10.1029/2024GL111393
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Summary:Abstract Sulfur hexafluoride (SF6), nitrogen trifluoride (NF3), and three perfluorocarbons (PFCs; CF4, C2F6, and c‐C4F8) are perfluorinated greenhouse gases (PF‐GHGs) with long atmospheric lifetimes and high global warming potentials. Using high‐frequency observations and a Bayesian inversion framework, we assess 2021–2023 PF‐GHG emissions in southeastern China, a rapidly industrializing region. Total PF‐GHG emissions rise from 69.50 (55.16–84.97) in 2021 to 96.19 (69.53–127.14) Mt CO2‐eq yr−1 in 2023, accounting for 21.74% of global total PF‐GHG emissions in 2023. NF3 emissions nearly double, reaching 0.94 (0.69–1.25) Gg yr−1, with an annual growth rate of 40.38%, likely driven by semiconductor industry expansion. SF6 (51.75%) and NF3 (30.86%) dominate 3‐year PF‐GHG growth. c‐C4F8 shows strong seasonality, with a potential winter increase linked to HCFC‐22 feedstock use. Seasonal SF6 peaks align with winter electricity demand, while C2F6 variations suggest potential links with semiconductor industry.
ISSN:0094-8276
1944-8007