Influence of Organic Esters on Portland Cement Hydration and Hardening

This paper investigated the effect of organic compounds with ester groups on the hydration and hardening of cement. The effects of five kinds of organic compounds with ester groups (ethyl acetate, dimethyl oxalate, glyceryl triacetate, trimethyl phosphate, and triethanolamine borate) on hydration he...

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Main Authors: Duan-le Li, Da-peng Zheng, Dong-min Wang, Ji-hui Zhao, Cheng Du, Cai-fu Ren
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/3203952
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author Duan-le Li
Da-peng Zheng
Dong-min Wang
Ji-hui Zhao
Cheng Du
Cai-fu Ren
author_facet Duan-le Li
Da-peng Zheng
Dong-min Wang
Ji-hui Zhao
Cheng Du
Cai-fu Ren
author_sort Duan-le Li
collection DOAJ
description This paper investigated the effect of organic compounds with ester groups on the hydration and hardening of cement. The effects of five kinds of organic compounds with ester groups (ethyl acetate, dimethyl oxalate, glyceryl triacetate, trimethyl phosphate, and triethanolamine borate) on hydration heat, hydration degree, setting time, mechanical properties, microstructure, and pore structure of hardened cement slurry were studied. The test results showed that esters can make the end time of cement hydration induction longer and delay the occurrence of the second exothermic peak. Also, the effect of five kinds of esters on the hydration and hardening of cement was basically followed by TG> TB> DMO> EAC> TMP. In terms of molecular structure, for organic compounds containing only ester groups, the higher the number of ester groups, the greater the effect on the hydration of cement. The introduction of other functional groups (such as phosphate or borate) will influence the effect of the esters.
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institution Kabale University
issn 1687-8434
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language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-78e73ea6b22f4f6dbb17afecf6fa45122025-02-03T01:30:37ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/32039523203952Influence of Organic Esters on Portland Cement Hydration and HardeningDuan-le Li0Da-peng Zheng1Dong-min Wang2Ji-hui Zhao3Cheng Du4Cai-fu Ren5School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaDepartment of Civil Engineering, Tsinghua University, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaThis paper investigated the effect of organic compounds with ester groups on the hydration and hardening of cement. The effects of five kinds of organic compounds with ester groups (ethyl acetate, dimethyl oxalate, glyceryl triacetate, trimethyl phosphate, and triethanolamine borate) on hydration heat, hydration degree, setting time, mechanical properties, microstructure, and pore structure of hardened cement slurry were studied. The test results showed that esters can make the end time of cement hydration induction longer and delay the occurrence of the second exothermic peak. Also, the effect of five kinds of esters on the hydration and hardening of cement was basically followed by TG> TB> DMO> EAC> TMP. In terms of molecular structure, for organic compounds containing only ester groups, the higher the number of ester groups, the greater the effect on the hydration of cement. The introduction of other functional groups (such as phosphate or borate) will influence the effect of the esters.http://dx.doi.org/10.1155/2018/3203952
spellingShingle Duan-le Li
Da-peng Zheng
Dong-min Wang
Ji-hui Zhao
Cheng Du
Cai-fu Ren
Influence of Organic Esters on Portland Cement Hydration and Hardening
Advances in Materials Science and Engineering
title Influence of Organic Esters on Portland Cement Hydration and Hardening
title_full Influence of Organic Esters on Portland Cement Hydration and Hardening
title_fullStr Influence of Organic Esters on Portland Cement Hydration and Hardening
title_full_unstemmed Influence of Organic Esters on Portland Cement Hydration and Hardening
title_short Influence of Organic Esters on Portland Cement Hydration and Hardening
title_sort influence of organic esters on portland cement hydration and hardening
url http://dx.doi.org/10.1155/2018/3203952
work_keys_str_mv AT duanleli influenceoforganicestersonportlandcementhydrationandhardening
AT dapengzheng influenceoforganicestersonportlandcementhydrationandhardening
AT dongminwang influenceoforganicestersonportlandcementhydrationandhardening
AT jihuizhao influenceoforganicestersonportlandcementhydrationandhardening
AT chengdu influenceoforganicestersonportlandcementhydrationandhardening
AT caifuren influenceoforganicestersonportlandcementhydrationandhardening