Influence of Organic Esters on Portland Cement Hydration and Hardening
This paper investigated the effect of organic compounds with ester groups on the hydration and hardening of cement. The effects of five kinds of organic compounds with ester groups (ethyl acetate, dimethyl oxalate, glyceryl triacetate, trimethyl phosphate, and triethanolamine borate) on hydration he...
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Language: | English |
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Wiley
2018-01-01
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Series: | Advances in Materials Science and Engineering |
Online Access: | http://dx.doi.org/10.1155/2018/3203952 |
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author | Duan-le Li Da-peng Zheng Dong-min Wang Ji-hui Zhao Cheng Du Cai-fu Ren |
author_facet | Duan-le Li Da-peng Zheng Dong-min Wang Ji-hui Zhao Cheng Du Cai-fu Ren |
author_sort | Duan-le Li |
collection | DOAJ |
description | This paper investigated the effect of organic compounds with ester groups on the hydration and hardening of cement. The effects of five kinds of organic compounds with ester groups (ethyl acetate, dimethyl oxalate, glyceryl triacetate, trimethyl phosphate, and triethanolamine borate) on hydration heat, hydration degree, setting time, mechanical properties, microstructure, and pore structure of hardened cement slurry were studied. The test results showed that esters can make the end time of cement hydration induction longer and delay the occurrence of the second exothermic peak. Also, the effect of five kinds of esters on the hydration and hardening of cement was basically followed by TG> TB> DMO> EAC> TMP. In terms of molecular structure, for organic compounds containing only ester groups, the higher the number of ester groups, the greater the effect on the hydration of cement. The introduction of other functional groups (such as phosphate or borate) will influence the effect of the esters. |
format | Article |
id | doaj-art-78e73ea6b22f4f6dbb17afecf6fa4512 |
institution | Kabale University |
issn | 1687-8434 1687-8442 |
language | English |
publishDate | 2018-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Materials Science and Engineering |
spelling | doaj-art-78e73ea6b22f4f6dbb17afecf6fa45122025-02-03T01:30:37ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/32039523203952Influence of Organic Esters on Portland Cement Hydration and HardeningDuan-le Li0Da-peng Zheng1Dong-min Wang2Ji-hui Zhao3Cheng Du4Cai-fu Ren5School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaDepartment of Civil Engineering, Tsinghua University, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, ChinaThis paper investigated the effect of organic compounds with ester groups on the hydration and hardening of cement. The effects of five kinds of organic compounds with ester groups (ethyl acetate, dimethyl oxalate, glyceryl triacetate, trimethyl phosphate, and triethanolamine borate) on hydration heat, hydration degree, setting time, mechanical properties, microstructure, and pore structure of hardened cement slurry were studied. The test results showed that esters can make the end time of cement hydration induction longer and delay the occurrence of the second exothermic peak. Also, the effect of five kinds of esters on the hydration and hardening of cement was basically followed by TG> TB> DMO> EAC> TMP. In terms of molecular structure, for organic compounds containing only ester groups, the higher the number of ester groups, the greater the effect on the hydration of cement. The introduction of other functional groups (such as phosphate or borate) will influence the effect of the esters.http://dx.doi.org/10.1155/2018/3203952 |
spellingShingle | Duan-le Li Da-peng Zheng Dong-min Wang Ji-hui Zhao Cheng Du Cai-fu Ren Influence of Organic Esters on Portland Cement Hydration and Hardening Advances in Materials Science and Engineering |
title | Influence of Organic Esters on Portland Cement Hydration and Hardening |
title_full | Influence of Organic Esters on Portland Cement Hydration and Hardening |
title_fullStr | Influence of Organic Esters on Portland Cement Hydration and Hardening |
title_full_unstemmed | Influence of Organic Esters on Portland Cement Hydration and Hardening |
title_short | Influence of Organic Esters on Portland Cement Hydration and Hardening |
title_sort | influence of organic esters on portland cement hydration and hardening |
url | http://dx.doi.org/10.1155/2018/3203952 |
work_keys_str_mv | AT duanleli influenceoforganicestersonportlandcementhydrationandhardening AT dapengzheng influenceoforganicestersonportlandcementhydrationandhardening AT dongminwang influenceoforganicestersonportlandcementhydrationandhardening AT jihuizhao influenceoforganicestersonportlandcementhydrationandhardening AT chengdu influenceoforganicestersonportlandcementhydrationandhardening AT caifuren influenceoforganicestersonportlandcementhydrationandhardening |