A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization
Considering the importance of organic functionalization of MOFs, we here report a simple, tunable and efficient one-step post-modification procedure for introducing amino and carboxylic groups into the mesoporous metal–organic framework Al- and Cr-MIL-101-NH<sub>2</sub> based on its reac...
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MDPI AG
2025-03-01
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| Series: | Chemistry |
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| Online Access: | https://www.mdpi.com/2624-8549/7/2/48 |
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| author | Alain Vigroux Christian Lherbet Isabelle Fabing Marie-Claire Barthélémy Christophe Laurent Pascal Hoffmann |
| author_facet | Alain Vigroux Christian Lherbet Isabelle Fabing Marie-Claire Barthélémy Christophe Laurent Pascal Hoffmann |
| author_sort | Alain Vigroux |
| collection | DOAJ |
| description | Considering the importance of organic functionalization of MOFs, we here report a simple, tunable and efficient one-step post-modification procedure for introducing amino and carboxylic groups into the mesoporous metal–organic framework Al- and Cr-MIL-101-NH<sub>2</sub> based on its reaction with alkyl bromides. This procedure allows also access to polyfunctionalized MIL-101 decorated with both carboxylic and primary amino groups. Other chemical functions, such as alcohols and alkynes, were also successfully introduced by this method. |
| format | Article |
| id | doaj-art-78b2c44bfde449ac84ec9e3ef5159049 |
| institution | DOAJ |
| issn | 2624-8549 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry |
| spelling | doaj-art-78b2c44bfde449ac84ec9e3ef51590492025-08-20T03:14:17ZengMDPI AGChemistry2624-85492025-03-01724810.3390/chemistry7020048A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> FunctionalizationAlain Vigroux0Christian Lherbet1Isabelle Fabing2Marie-Claire Barthélémy3Christophe Laurent4Pascal Hoffmann5Laboratoire de Synthèse et Physico-Chimie de Molécules d’Interêt Biologique LSPCMIB, Université de Toulouse, UMR CNRS UT 5068, 118 Route de Narbonne, 31062 Toulouse, FranceLaboratoire de Synthèse et Physico-Chimie de Molécules d’Interêt Biologique LSPCMIB, Université de Toulouse, UMR CNRS UT 5068, 118 Route de Narbonne, 31062 Toulouse, FranceLaboratoire de Synthèse et Physico-Chimie de Molécules d’Interêt Biologique LSPCMIB, Université de Toulouse, UMR CNRS UT 5068, 118 Route de Narbonne, 31062 Toulouse, FranceCentre Interuniversitaire de Recherche et d’Ingénierie des Matériaux CIRIMAT, Université de Toulouse, UMR CNRS INP UT 5085, 118 Route de Narbonne, 31062 Toulouse, FranceCentre Interuniversitaire de Recherche et d’Ingénierie des Matériaux CIRIMAT, Université de Toulouse, UMR CNRS INP UT 5085, 118 Route de Narbonne, 31062 Toulouse, FranceLaboratoire de Synthèse et Physico-Chimie de Molécules d’Interêt Biologique LSPCMIB, Université de Toulouse, UMR CNRS UT 5068, 118 Route de Narbonne, 31062 Toulouse, FranceConsidering the importance of organic functionalization of MOFs, we here report a simple, tunable and efficient one-step post-modification procedure for introducing amino and carboxylic groups into the mesoporous metal–organic framework Al- and Cr-MIL-101-NH<sub>2</sub> based on its reaction with alkyl bromides. This procedure allows also access to polyfunctionalized MIL-101 decorated with both carboxylic and primary amino groups. Other chemical functions, such as alcohols and alkynes, were also successfully introduced by this method.https://www.mdpi.com/2624-8549/7/2/48metal–organic frameworkspost-synthetic modificationPSM(Al)MIL101-NH<sub>2</sub>(Cr)MIL101-NH<sub>2</sub>alkylation |
| spellingShingle | Alain Vigroux Christian Lherbet Isabelle Fabing Marie-Claire Barthélémy Christophe Laurent Pascal Hoffmann A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization Chemistry metal–organic frameworks post-synthetic modification PSM (Al)MIL101-NH<sub>2</sub> (Cr)MIL101-NH<sub>2</sub> alkylation |
| title | A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization |
| title_full | A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization |
| title_fullStr | A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization |
| title_full_unstemmed | A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization |
| title_short | A Post-Synthetic Modification Approach to Expand MIL-101-NH<sub>2</sub> Functionalization |
| title_sort | post synthetic modification approach to expand mil 101 nh sub 2 sub functionalization |
| topic | metal–organic frameworks post-synthetic modification PSM (Al)MIL101-NH<sub>2</sub> (Cr)MIL101-NH<sub>2</sub> alkylation |
| url | https://www.mdpi.com/2624-8549/7/2/48 |
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