Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution

Corrosion is recognized as a notable problem in oil sector where API5LX60 steel transmission pipelines are in frequent use. In this report, three oxazolone derivatives as potential corrosion inhibitors were investigated on API5LX60 graded carbon steel in 1N H2SO4 solution in stagnant conditions at c...

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Main Authors: Parijat Burhagohain, Gitalee Sharma, Prankush Malla Bujarbaruah
Format: Article
Language:English
Published: Egyptian Petroleum Research Institute 2022-09-01
Series:Egyptian Journal of Petroleum
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Online Access:http://www.sciencedirect.com/science/article/pii/S1110062122000459
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author Parijat Burhagohain
Gitalee Sharma
Prankush Malla Bujarbaruah
author_facet Parijat Burhagohain
Gitalee Sharma
Prankush Malla Bujarbaruah
author_sort Parijat Burhagohain
collection DOAJ
description Corrosion is recognized as a notable problem in oil sector where API5LX60 steel transmission pipelines are in frequent use. In this report, three oxazolone derivatives as potential corrosion inhibitors were investigated on API5LX60 graded carbon steel in 1N H2SO4 solution in stagnant conditions at concentrations 50–200 ppm. Gravimetric weight loss coupons and electrical resistance corrosion monitoring techniques performed on test samples showed inhibitory properties with best at 200 ppm inhibitor concentration. The results further revealed that the degree of inhibition was concentration dependent. Inhibitor I exhibited the highest inhibition efficiency of 90.70% at 200 ppm concentration. Statistical analysis using multiple linear regression model procreated high R2 value of 0.998 and p-value < 0.0001 asserting a smooth linear dependence of inhibitor efficiency on oxazolone concentration and weight loss of the steel. Again, surface analysis affirmed the formation of protective coating of inhibitor on steel surface. Furthermore, the oxazolone inhibitor adsorbed physically on the steel surface and obeyed the Langmuir isotherm which is evident from the linear correlation coefficient value of 0.9992.
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issn 1110-0621
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publishDate 2022-09-01
publisher Egyptian Petroleum Research Institute
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series Egyptian Journal of Petroleum
spelling doaj-art-78769abf7dd7489e8761c751cb874cf52025-08-20T03:19:17ZengEgyptian Petroleum Research InstituteEgyptian Journal of Petroleum1110-06212022-09-01313374510.1016/j.ejpe.2022.06.006Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solutionParijat Burhagohain0Gitalee Sharma1Prankush Malla Bujarbaruah2Department of Chemistry, Dibrugarh University, Dibrugarh 786004, Assam, IndiaDepartment of Chemistry, Dibrugarh University Institute of Engineering and Technology (DUIET), Dibrugarh University, Dibrugarh 786004, Assam, India; Corresponding author.DGM, OGPL &amp; P, Oil India Limited, Duliajan, Duliajan 786602, Assam, IndiaCorrosion is recognized as a notable problem in oil sector where API5LX60 steel transmission pipelines are in frequent use. In this report, three oxazolone derivatives as potential corrosion inhibitors were investigated on API5LX60 graded carbon steel in 1N H2SO4 solution in stagnant conditions at concentrations 50–200 ppm. Gravimetric weight loss coupons and electrical resistance corrosion monitoring techniques performed on test samples showed inhibitory properties with best at 200 ppm inhibitor concentration. The results further revealed that the degree of inhibition was concentration dependent. Inhibitor I exhibited the highest inhibition efficiency of 90.70% at 200 ppm concentration. Statistical analysis using multiple linear regression model procreated high R2 value of 0.998 and p-value < 0.0001 asserting a smooth linear dependence of inhibitor efficiency on oxazolone concentration and weight loss of the steel. Again, surface analysis affirmed the formation of protective coating of inhibitor on steel surface. Furthermore, the oxazolone inhibitor adsorbed physically on the steel surface and obeyed the Langmuir isotherm which is evident from the linear correlation coefficient value of 0.9992.http://www.sciencedirect.com/science/article/pii/S1110062122000459API5LX60 steelCorrosion inhibitorOxazoloneH2SO4
spellingShingle Parijat Burhagohain
Gitalee Sharma
Prankush Malla Bujarbaruah
Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution
Egyptian Journal of Petroleum
API5LX60 steel
Corrosion inhibitor
Oxazolone
H2SO4
title Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution
title_full Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution
title_fullStr Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution
title_full_unstemmed Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution
title_short Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution
title_sort investigation of a few oxazolone molecules as corrosion inhibitor for api5lx60 steel in 1n h2so4 solution
topic API5LX60 steel
Corrosion inhibitor
Oxazolone
H2SO4
url http://www.sciencedirect.com/science/article/pii/S1110062122000459
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AT gitaleesharma investigationofafewoxazolonemoleculesascorrosioninhibitorforapi5lx60steelin1nh2so4solution
AT prankushmallabujarbaruah investigationofafewoxazolonemoleculesascorrosioninhibitorforapi5lx60steelin1nh2so4solution