Progress and challenges in dicarboxylation with CO<sub>2</sub>
Dicarboxylic acids, which are appealing structural motifs in organic synthesis and exist widely in bioactive compounds, have been widely used as important monomers in the polymer industry to construct valuable materials. The dicarboxylation with CO<sub>2</sub> provides a convenient and p...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Science Press
2022-10-01
|
| Series: | National Science Open |
| Subjects: | |
| Online Access: | https://www.sciengine.com/doi/10.1360/nso/20220024 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849708977742413824 |
|---|---|
| author | Ran Chuan-Kun Xiao Han-Zhi Liao Li-Li Ju Tao Zhang Wei Yu Da-Gang |
| author_facet | Ran Chuan-Kun Xiao Han-Zhi Liao Li-Li Ju Tao Zhang Wei Yu Da-Gang |
| author_sort | Ran Chuan-Kun |
| collection | DOAJ |
| description | Dicarboxylic acids, which are appealing structural motifs in organic synthesis and exist widely in bioactive compounds, have been widely used as important monomers in the polymer industry to construct valuable materials. The dicarboxylation with CO<sub>2</sub> provides a convenient and potent way to furnish value-added dicarboxylic acids via the chemical fixation of two CO<sub>2</sub> molecules. Beyond any doubt, the development of dicarboxylation, especially the dicarboxylation of bulk chemicals, might represent a promising prospect in CO<sub>2</sub> capture and utilization (CCU). In this review, we critically summarized and comprehensively reviewed the advances made in the past decades in dicarboxylation with CO<sub>2</sub> under electro-, photo- and transition metal-mediated/catalytic systems. Moreover, the advantages and limitations of such dicarboxylation reactions are pointed out to unravel further development for future scientific and industrial advances in dicarboxylation with CO<sub>2</sub> to synthesize dicarboxylic acids in high selectivity and efficiency. |
| format | Article |
| id | doaj-art-78319c31ccb24846b3c6e586d941e2c1 |
| institution | DOAJ |
| issn | 2097-1168 |
| language | English |
| publishDate | 2022-10-01 |
| publisher | Science Press |
| record_format | Article |
| series | National Science Open |
| spelling | doaj-art-78319c31ccb24846b3c6e586d941e2c12025-08-20T03:15:27ZengScience PressNational Science Open2097-11682022-10-01210.1360/nso/20220024eb33e642Progress and challenges in dicarboxylation with CO<sub>2</sub>Ran Chuan-Kun0Xiao Han-Zhi1Liao Li-Li2Ju Tao3Zhang Wei4Yu Da-Gang5["Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"]["Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"]["School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China"]["College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China"]["Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"]["Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"]Dicarboxylic acids, which are appealing structural motifs in organic synthesis and exist widely in bioactive compounds, have been widely used as important monomers in the polymer industry to construct valuable materials. The dicarboxylation with CO<sub>2</sub> provides a convenient and potent way to furnish value-added dicarboxylic acids via the chemical fixation of two CO<sub>2</sub> molecules. Beyond any doubt, the development of dicarboxylation, especially the dicarboxylation of bulk chemicals, might represent a promising prospect in CO<sub>2</sub> capture and utilization (CCU). In this review, we critically summarized and comprehensively reviewed the advances made in the past decades in dicarboxylation with CO<sub>2</sub> under electro-, photo- and transition metal-mediated/catalytic systems. Moreover, the advantages and limitations of such dicarboxylation reactions are pointed out to unravel further development for future scientific and industrial advances in dicarboxylation with CO<sub>2</sub> to synthesize dicarboxylic acids in high selectivity and efficiency.https://www.sciengine.com/doi/10.1360/nso/20220024carbon dioxidedicarboxylationelectrochemistryphotoredox catalysistransition-metal catalysis |
| spellingShingle | Ran Chuan-Kun Xiao Han-Zhi Liao Li-Li Ju Tao Zhang Wei Yu Da-Gang Progress and challenges in dicarboxylation with CO<sub>2</sub> National Science Open carbon dioxide dicarboxylation electrochemistry photoredox catalysis transition-metal catalysis |
| title | Progress and challenges in dicarboxylation with CO<sub>2</sub> |
| title_full | Progress and challenges in dicarboxylation with CO<sub>2</sub> |
| title_fullStr | Progress and challenges in dicarboxylation with CO<sub>2</sub> |
| title_full_unstemmed | Progress and challenges in dicarboxylation with CO<sub>2</sub> |
| title_short | Progress and challenges in dicarboxylation with CO<sub>2</sub> |
| title_sort | progress and challenges in dicarboxylation with co sub 2 sub |
| topic | carbon dioxide dicarboxylation electrochemistry photoredox catalysis transition-metal catalysis |
| url | https://www.sciengine.com/doi/10.1360/nso/20220024 |
| work_keys_str_mv | AT ranchuankun progressandchallengesindicarboxylationwithcosub2sub AT xiaohanzhi progressandchallengesindicarboxylationwithcosub2sub AT liaolili progressandchallengesindicarboxylationwithcosub2sub AT jutao progressandchallengesindicarboxylationwithcosub2sub AT zhangwei progressandchallengesindicarboxylationwithcosub2sub AT yudagang progressandchallengesindicarboxylationwithcosub2sub |