Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations
<p>Natural aerosol components such as particulate methanesulfonic acid (MSA<span class="inline-formula"><sub>p</sub></span>) play an important role in the Arctic climate. However, numerical models struggle to reproduce MSA<span class="inline-formula&qu...
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Copernicus Publications
2025-06-01
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| Series: | Atmospheric Chemistry and Physics |
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| author | J. B. Pernov J. B. Pernov W. H. Aeberhard M. Volpi E. Harris E. Harris B. Hohermuth S. Ishino R. B. Skeie S. Henne U. Im P. K. Quinn L. M. Upchurch L. M. Upchurch J. Schmale |
| author_facet | J. B. Pernov J. B. Pernov W. H. Aeberhard M. Volpi E. Harris E. Harris B. Hohermuth S. Ishino R. B. Skeie S. Henne U. Im P. K. Quinn L. M. Upchurch L. M. Upchurch J. Schmale |
| author_sort | J. B. Pernov |
| collection | DOAJ |
| description | <p>Natural aerosol components such as particulate methanesulfonic acid (MSA<span class="inline-formula"><sub>p</sub></span>) play an important role in the Arctic climate. However, numerical models struggle to reproduce MSA<span class="inline-formula"><sub>p</sub></span> concentrations and seasonality. Here we present an alternative data-driven methodology for modeling MSA<span class="inline-formula"><sub>p</sub></span> at four High Arctic stations (Alert, Gruvebadet, Pituffik (formerly Thule), and Utqiaġvik (formerly Barrow)). In our approach, we create input features that consider the ambient conditions experienced during atmospheric transport (e.g., dimethyl sulfide (DMS) emission, temperature, radiation, cloud cover, precipitation) for use in two data-driven models: a random forest (RF) regressor and an additive model (AM). The most important features were selected through automatic selection procedures, and their relationships with MSA<span class="inline-formula"><sub>p</sub></span> model output was investigated. Although the overall performance of our data-driven models on test data is modest (max. <span class="inline-formula"><i>R</i><sup>2</sup>=0.29</span>), the models can capture variability in the data well (max. Pearson correlation coefficient <span class="inline-formula">=</span> 0.77), outperform the current numerical models and reanalysis products, and produce physically interpretable results.</p>
<p>The data-driven models selected features which can be grouped into three categories, the sources, chemical processing, and removal of MSA<span class="inline-formula"><sub>p</sub></span>, with specific differences between stations. The seasonal cycles and selected features suggest gas-phase oxidation is relatively more important during peak concentration months at Alert, Gruvebadet, and Pituffik (Thule), while aqueous-phase oxidation is relatively more important at Utqiaġvik (Barrow). Alert and Pituffik (Thule) appear to be more influenced by processes aloft than in the boundary layer. Our models usually selected chemical-processing-related features as the main factors influencing MSA<span class="inline-formula"><sub>p</sub></span> predictions, highlighting the importance of properly simulating oxidation-related processes in numerical models.</p> |
| format | Article |
| id | doaj-art-77920792f7964b249e905b2de4e85227 |
| institution | Kabale University |
| issn | 1680-7316 1680-7324 |
| language | English |
| publishDate | 2025-06-01 |
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| series | Atmospheric Chemistry and Physics |
| spelling | doaj-art-77920792f7964b249e905b2de4e852272025-08-20T03:31:46ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242025-06-01256497653710.5194/acp-25-6497-2025Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrationsJ. B. Pernov0J. B. Pernov1W. H. Aeberhard2M. Volpi3E. Harris4E. Harris5B. Hohermuth6S. Ishino7R. B. Skeie8S. Henne9U. Im10P. K. Quinn11L. M. Upchurch12L. M. Upchurch13J. Schmale14Extreme Environments Research Laboratory, École Polytechnique Fédérale de Lausanne, Sion, Switzerlandnow at: School of Earth and Atmospheric Sciences, Queensland University of Technology, Brisbane, AustraliaSwiss Data Science Center, ETH Zurich and École Polytechnique Fédérale de Lausanne, SwitzerlandSwiss Data Science Center, ETH Zurich and École Polytechnique Fédérale de Lausanne, SwitzerlandSwiss Data Science Center, ETH Zurich and École Polytechnique Fédérale de Lausanne, Switzerlandnow at: Climate and Environmental Physics, University of Bern, Sidlerstrasse 5, 3012 Bern, SwitzerlandSchroders Capital ILS, Zurich, SwitzerlandInstitute of Nature and Environmental Technology, Kanazawa University, Kanazawa, JapanCICERO, Center for International Climate Research, Oslo, NorwayEmpa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, SwitzerlandDepartment of Environmental Science/Interdisciplinary Centre for Climate Change, Aarhus University, Roskilde, DenmarkPacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, WA, USAPacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, WA, USACooperative Institute for Climate, Ocean, and Ecosystem Studies, University of Washington, Seattle, WA, USAExtreme Environments Research Laboratory, École Polytechnique Fédérale de Lausanne, Sion, Switzerland<p>Natural aerosol components such as particulate methanesulfonic acid (MSA<span class="inline-formula"><sub>p</sub></span>) play an important role in the Arctic climate. However, numerical models struggle to reproduce MSA<span class="inline-formula"><sub>p</sub></span> concentrations and seasonality. Here we present an alternative data-driven methodology for modeling MSA<span class="inline-formula"><sub>p</sub></span> at four High Arctic stations (Alert, Gruvebadet, Pituffik (formerly Thule), and Utqiaġvik (formerly Barrow)). In our approach, we create input features that consider the ambient conditions experienced during atmospheric transport (e.g., dimethyl sulfide (DMS) emission, temperature, radiation, cloud cover, precipitation) for use in two data-driven models: a random forest (RF) regressor and an additive model (AM). The most important features were selected through automatic selection procedures, and their relationships with MSA<span class="inline-formula"><sub>p</sub></span> model output was investigated. Although the overall performance of our data-driven models on test data is modest (max. <span class="inline-formula"><i>R</i><sup>2</sup>=0.29</span>), the models can capture variability in the data well (max. Pearson correlation coefficient <span class="inline-formula">=</span> 0.77), outperform the current numerical models and reanalysis products, and produce physically interpretable results.</p> <p>The data-driven models selected features which can be grouped into three categories, the sources, chemical processing, and removal of MSA<span class="inline-formula"><sub>p</sub></span>, with specific differences between stations. The seasonal cycles and selected features suggest gas-phase oxidation is relatively more important during peak concentration months at Alert, Gruvebadet, and Pituffik (Thule), while aqueous-phase oxidation is relatively more important at Utqiaġvik (Barrow). Alert and Pituffik (Thule) appear to be more influenced by processes aloft than in the boundary layer. Our models usually selected chemical-processing-related features as the main factors influencing MSA<span class="inline-formula"><sub>p</sub></span> predictions, highlighting the importance of properly simulating oxidation-related processes in numerical models.</p>https://acp.copernicus.org/articles/25/6497/2025/acp-25-6497-2025.pdf |
| spellingShingle | J. B. Pernov J. B. Pernov W. H. Aeberhard M. Volpi E. Harris E. Harris B. Hohermuth S. Ishino R. B. Skeie S. Henne U. Im P. K. Quinn L. M. Upchurch L. M. Upchurch J. Schmale Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations Atmospheric Chemistry and Physics |
| title | Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations |
| title_full | Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations |
| title_fullStr | Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations |
| title_full_unstemmed | Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations |
| title_short | Data-driven modeling of environmental factors influencing Arctic methanesulfonic acid aerosol concentrations |
| title_sort | data driven modeling of environmental factors influencing arctic methanesulfonic acid aerosol concentrations |
| url | https://acp.copernicus.org/articles/25/6497/2025/acp-25-6497-2025.pdf |
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