Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations

Silica nanoparticles were modified with aromatic amino groups and modified-silica/polyimide composite films were prepared using them. 3,3',4,4'-Benzophenone tetracarboxylic dianhydride (BTDA) and 4,4'-oxydianiline (ODA) were used as precursors for polyimide matrix. The structures of t...

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Main Authors: R. V. Ghorpade, C. R. Rajan, N. N. Chavan, S. Ponrathnam
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2015-05-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0005851&mi=cd
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author R. V. Ghorpade
C. R. Rajan
N. N. Chavan
S. Ponrathnam
author_facet R. V. Ghorpade
C. R. Rajan
N. N. Chavan
S. Ponrathnam
author_sort R. V. Ghorpade
collection DOAJ
description Silica nanoparticles were modified with aromatic amino groups and modified-silica/polyimide composite films were prepared using them. 3,3',4,4'-Benzophenone tetracarboxylic dianhydride (BTDA) and 4,4'-oxydianiline (ODA) were used as precursors for polyimide matrix. The structures of the modified nanoparticles and hybrid nanocomposites were identified using Fourier Transform Infrared (FTIR) spectrometry. The hybrid composite films were evaluated for mechanical, thermal and morphological characteristics. Morphological results describe a uniform dispersion of silica particles in the polymer matrix. The thermal stability and mechanical properties of polyimide composite were improved, and the decomposition temperature was increased when the amount of silica nanoparticles was increased.
format Article
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institution DOAJ
issn 1788-618X
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publishDate 2015-05-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-773fce9c8ea148738dd29117d5e4ae422025-08-20T03:14:54ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2015-05-019546947910.3144/expresspolymlett.2015.44Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigationsR. V. GhorpadeC. R. RajanN. N. ChavanS. PonrathnamSilica nanoparticles were modified with aromatic amino groups and modified-silica/polyimide composite films were prepared using them. 3,3',4,4'-Benzophenone tetracarboxylic dianhydride (BTDA) and 4,4'-oxydianiline (ODA) were used as precursors for polyimide matrix. The structures of the modified nanoparticles and hybrid nanocomposites were identified using Fourier Transform Infrared (FTIR) spectrometry. The hybrid composite films were evaluated for mechanical, thermal and morphological characteristics. Morphological results describe a uniform dispersion of silica particles in the polymer matrix. The thermal stability and mechanical properties of polyimide composite were improved, and the decomposition temperature was increased when the amount of silica nanoparticles was increased.http://www.expresspolymlett.com/letolt.php?file=EPL-0005851&mi=cdNanocompositesNanoparticle modificationHybrid polyimide compositesThermal propertiesMechanical properties
spellingShingle R. V. Ghorpade
C. R. Rajan
N. N. Chavan
S. Ponrathnam
Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations
eXPRESS Polymer Letters
Nanocomposites
Nanoparticle modification
Hybrid polyimide composites
Thermal properties
Mechanical properties
title Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations
title_full Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations
title_fullStr Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations
title_full_unstemmed Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations
title_short Synthesis of novel silica-polyimide nanocomposite films using aromatic-amino modified silica nanoparticles: Mechanical, thermal and morphological investigations
title_sort synthesis of novel silica polyimide nanocomposite films using aromatic amino modified silica nanoparticles mechanical thermal and morphological investigations
topic Nanocomposites
Nanoparticle modification
Hybrid polyimide composites
Thermal properties
Mechanical properties
url http://www.expresspolymlett.com/letolt.php?file=EPL-0005851&mi=cd
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