Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes

Asymmetric induction up to 14% have been obtained in the hydrocarboxylation of olefinic hydrocarbons with carbon monoxide and alcohols in the presence of PdCl2 and (–)-DIOP (= 2,3-O-isopropylidene-2,3-dihydroxy-1,4- bis(diphenylphosphino)butane).  

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Bibliographic Details
Main Authors: Carlo Botteghi, Giambattista Consiglio, Piero Pino
Format: Article
Language:deu
Published: Swiss Chemical Society 1973-09-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9100
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author Carlo Botteghi
Giambattista Consiglio
Piero Pino
author_facet Carlo Botteghi
Giambattista Consiglio
Piero Pino
author_sort Carlo Botteghi
collection DOAJ
description Asymmetric induction up to 14% have been obtained in the hydrocarboxylation of olefinic hydrocarbons with carbon monoxide and alcohols in the presence of PdCl2 and (–)-DIOP (= 2,3-O-isopropylidene-2,3-dihydroxy-1,4- bis(diphenylphosphino)butane).  
format Article
id doaj-art-770983a19c974b2c9cec987ea7e4ee9f
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2673-2424
language deu
publishDate 1973-09-01
publisher Swiss Chemical Society
record_format Article
series CHIMIA
spelling doaj-art-770983a19c974b2c9cec987ea7e4ee9f2025-08-20T02:29:54ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241973-09-0127910.2533/chimia.1973.477Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium ComplexesCarlo Botteghi0Giambattista Consiglio1Piero Pino2Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, ZürichTechnisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, ZürichTechnisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich Asymmetric induction up to 14% have been obtained in the hydrocarboxylation of olefinic hydrocarbons with carbon monoxide and alcohols in the presence of PdCl2 and (–)-DIOP (= 2,3-O-isopropylidene-2,3-dihydroxy-1,4- bis(diphenylphosphino)butane).   https://www.chimia.ch/chimia/article/view/9100
spellingShingle Carlo Botteghi
Giambattista Consiglio
Piero Pino
Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
CHIMIA
title Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
title_full Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
title_fullStr Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
title_full_unstemmed Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
title_short Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
title_sort asymmetric hydrocarboxylation of olefines by chiral palladium complexes
url https://www.chimia.ch/chimia/article/view/9100
work_keys_str_mv AT carlobotteghi asymmetrichydrocarboxylationofolefinesbychiralpalladiumcomplexes
AT giambattistaconsiglio asymmetrichydrocarboxylationofolefinesbychiralpalladiumcomplexes
AT pieropino asymmetrichydrocarboxylationofolefinesbychiralpalladiumcomplexes