Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans

Metal-Organic Frameworks (MOFs) gaining increasing interest in heterogeneous catalysis owing to their advantageous properties such as superior porosity, high surface area, ample catalytic sites. Their properties can be tailored by varying the metal ions or metal clusters (nodes) and organic linkers....

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Main Authors: Subrahmanya Ishwar Bhat, Chinmay Bhat
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844024174701
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author Subrahmanya Ishwar Bhat
Chinmay Bhat
author_facet Subrahmanya Ishwar Bhat
Chinmay Bhat
author_sort Subrahmanya Ishwar Bhat
collection DOAJ
description Metal-Organic Frameworks (MOFs) gaining increasing interest in heterogeneous catalysis owing to their advantageous properties such as superior porosity, high surface area, ample catalytic sites. Their properties can be tailored by varying the metal ions or metal clusters (nodes) and organic linkers. Magnetically active nano core-shell MOF composites are also discovered for easy separation and reuse of catalyst. MOF catalysed multicomponent reactions (MCRs) satisfy several green chemistry principles and thus can be considered as a sturdy step towards sustainable chemical synthesis. In this article, synthesis of biologically potent pyran scaffolds through MOF catalysed MCR approaches have been reviewed. Preparation of MOF catalyst, its catalytic performance in pyran synthesis, reusability has been discussed with reaction for each example.
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spelling doaj-art-76d011ea4fb4433fbd595e266896e7802025-01-17T04:51:16ZengElsevierHeliyon2405-84402025-01-01111e41439Metal-organic framework catalysed multicomponent reactions towards the synthesis of PyransSubrahmanya Ishwar Bhat0Chinmay Bhat1Department of Chemistry, NMAM Institute of Technology, Affiliated to NITTE (Deemed to be University), Nitte, 574110, Karnataka, India; Corresponding author.Department of Chemistry, Government First Grade College Chamarajanagar (Affiliated to Chamarajanagar University), Chamarajanagar, Karnataka, IndiaMetal-Organic Frameworks (MOFs) gaining increasing interest in heterogeneous catalysis owing to their advantageous properties such as superior porosity, high surface area, ample catalytic sites. Their properties can be tailored by varying the metal ions or metal clusters (nodes) and organic linkers. Magnetically active nano core-shell MOF composites are also discovered for easy separation and reuse of catalyst. MOF catalysed multicomponent reactions (MCRs) satisfy several green chemistry principles and thus can be considered as a sturdy step towards sustainable chemical synthesis. In this article, synthesis of biologically potent pyran scaffolds through MOF catalysed MCR approaches have been reviewed. Preparation of MOF catalyst, its catalytic performance in pyran synthesis, reusability has been discussed with reaction for each example.http://www.sciencedirect.com/science/article/pii/S2405844024174701PyranMetal organic frameworkMulticomponent reactionsSustainable chemistryHeterogeneous catalysis
spellingShingle Subrahmanya Ishwar Bhat
Chinmay Bhat
Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
Heliyon
Pyran
Metal organic framework
Multicomponent reactions
Sustainable chemistry
Heterogeneous catalysis
title Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
title_full Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
title_fullStr Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
title_full_unstemmed Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
title_short Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
title_sort metal organic framework catalysed multicomponent reactions towards the synthesis of pyrans
topic Pyran
Metal organic framework
Multicomponent reactions
Sustainable chemistry
Heterogeneous catalysis
url http://www.sciencedirect.com/science/article/pii/S2405844024174701
work_keys_str_mv AT subrahmanyaishwarbhat metalorganicframeworkcatalysedmulticomponentreactionstowardsthesynthesisofpyrans
AT chinmaybhat metalorganicframeworkcatalysedmulticomponentreactionstowardsthesynthesisofpyrans