Rearrangements of dicarba-<i>nido-</i>undecaborates

The thermal and chemically initiated thermal rearrangements of dicarba-nido-undecaborates was explored by computational chemistry. It was shown that the kinetic stability of dianions of these compounds is reduced in the series 2,9 &gt; 7,8 &gt; 1,7 &gt; 2,4 &gt; 2,8 &gt; 1,2 &...

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Main Authors: S. P. Knyazev, A. Yu. Kostiykovitch
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2011-10-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/800
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author S. P. Knyazev
A. Yu. Kostiykovitch
author_facet S. P. Knyazev
A. Yu. Kostiykovitch
author_sort S. P. Knyazev
collection DOAJ
description The thermal and chemically initiated thermal rearrangements of dicarba-nido-undecaborates was explored by computational chemistry. It was shown that the kinetic stability of dianions of these compounds is reduced in the series 2,9 &gt; 7,8 &gt; 1,7 &gt; 2,4 &gt; 2,8 &gt; 1,2 &gt;2,7 &gt; 2,3.
format Article
id doaj-art-76c6d751dc8a493a933aa39c8b0863da
institution DOAJ
issn 2410-6593
2686-7575
language Russian
publishDate 2011-10-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-76c6d751dc8a493a933aa39c8b0863da2025-08-20T03:23:19ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-10-0165125134794Rearrangements of dicarba-<i>nido-</i>undecaboratesS. P. Knyazev0A. Yu. Kostiykovitch1M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571The thermal and chemically initiated thermal rearrangements of dicarba-nido-undecaborates was explored by computational chemistry. It was shown that the kinetic stability of dianions of these compounds is reduced in the series 2,9 &gt; 7,8 &gt; 1,7 &gt; 2,4 &gt; 2,8 &gt; 1,2 &gt;2,7 &gt; 2,3.https://www.finechem-mirea.ru/jour/article/view/800dicarba-nido-undecaboratecomputational chemistrykinetic stabilityrearrangementstructure
spellingShingle S. P. Knyazev
A. Yu. Kostiykovitch
Rearrangements of dicarba-<i>nido-</i>undecaborates
Тонкие химические технологии
dicarba-nido-undecaborate
computational chemistry
kinetic stability
rearrangement
structure
title Rearrangements of dicarba-<i>nido-</i>undecaborates
title_full Rearrangements of dicarba-<i>nido-</i>undecaborates
title_fullStr Rearrangements of dicarba-<i>nido-</i>undecaborates
title_full_unstemmed Rearrangements of dicarba-<i>nido-</i>undecaborates
title_short Rearrangements of dicarba-<i>nido-</i>undecaborates
title_sort rearrangements of dicarba i nido i undecaborates
topic dicarba-nido-undecaborate
computational chemistry
kinetic stability
rearrangement
structure
url https://www.finechem-mirea.ru/jour/article/view/800
work_keys_str_mv AT spknyazev rearrangementsofdicarbainidoiundecaborates
AT ayukostiykovitch rearrangementsofdicarbainidoiundecaborates