Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I)
The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is n...
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| Language: | English |
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International Union of Crystallography
2025-03-01
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| Online Access: | https://journals.iucr.org/paper?S2414314625001932 |
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| author | Frederick P. Malan Kariska Potgieter Reinout Meijboom |
| author_facet | Frederick P. Malan Kariska Potgieter Reinout Meijboom |
| author_sort | Frederick P. Malan |
| collection | DOAJ |
| description | The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H...O interactions are evident. |
| format | Article |
| id | doaj-art-7659f937bcd64eb6886941b511e21812 |
| institution | DOAJ |
| issn | 2414-3146 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-7659f937bcd64eb6886941b511e218122025-08-20T03:07:31ZengInternational Union of CrystallographyIUCrData2414-31462025-03-01103x25019310.1107/S2414314625001932tk4116Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I)Frederick P. Malan0Kariska Potgieter1Reinout Meijboom2Department of Chemistry, University of Pretoria, Lynnwood Road, Hatfield, Pretoria, 0002, South AfricaDepartment of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaDepartment of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaThe molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H...O interactions are evident.https://journals.iucr.org/paper?S2414314625001932silver(i) complexdiphenyl-2-methoxyphenyl phosphinenitritecrystal structure |
| spellingShingle | Frederick P. Malan Kariska Potgieter Reinout Meijboom Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I) IUCrData silver(i) complex diphenyl-2-methoxyphenyl phosphine nitrite crystal structure |
| title | Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I) |
| title_full | Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I) |
| title_fullStr | Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I) |
| title_full_unstemmed | Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I) |
| title_short | Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I) |
| title_sort | bis 2 methoxyphenyl diphenylphosphane κp nitrito κ2o o silver i |
| topic | silver(i) complex diphenyl-2-methoxyphenyl phosphine nitrite crystal structure |
| url | https://journals.iucr.org/paper?S2414314625001932 |
| work_keys_str_mv | AT frederickpmalan bis2methoxyphenyldiphenylphosphanekpnitritok2oosilveri AT kariskapotgieter bis2methoxyphenyldiphenylphosphanekpnitritok2oosilveri AT reinoutmeijboom bis2methoxyphenyldiphenylphosphanekpnitritok2oosilveri |