Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I)
The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is n...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2025-03-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2414314625001932 |
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| Summary: | The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H...O interactions are evident. |
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| ISSN: | 2414-3146 |