Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures

Industrial effluents, especially those containing synthetic dyes which include acid red (AR) and acid black (AB), keep to pose excessive ecological and health dangers due to their balance and resistance to biodegradation. This takes a look at addresses this difficulty by using exploring Mn-doped Sr...

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Main Author: Mohammed Khalaf Zidane
Format: Article
Language:English
Published: Tikrit University 2025-08-01
Series:Tikrit Journal of Pure Science
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Online Access:https://www.tjpsj.org/index.php/tjps/article/view/1979
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author Mohammed Khalaf Zidane
author_facet Mohammed Khalaf Zidane
author_sort Mohammed Khalaf Zidane
collection DOAJ
description Industrial effluents, especially those containing synthetic dyes which include acid red (AR) and acid black (AB), keep to pose excessive ecological and health dangers due to their balance and resistance to biodegradation. This takes a look at addresses this difficulty by using exploring Mn-doped SrTiO₃ perovskite nanostructures as photocatalysts below visible light situations. The substances have been synthesized thru the sol-gel path and comprehensively characterized using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Ultraviolet–Visible Diffuse Reflectance Spectroscopy (UV-Vis/DRS), Brunauer–Emmett–Teller (BET) surface analysis, and Fourier Transform Infrared Spectroscopy (FTIR). surface analysis. Photocatalytic exams were done beneath visible light publicity to assess dye elimination efficiency and determine the role of operational factors such as pH, catalyst dose, and preliminary dye load. The creation of Mn into the SrTiO₃ lattice caused outstanding enhancements in seen-mild absorption and charge separation, allowing degradation efficiencies exceeding (90%) inside a hundred and twenty mins. These outcomes affirm the potential of Mn-doped SrTiO₃ as a viable photocatalyst for dye-contaminated wastewater treatment utilizing solar or artificial light sources The Mn-doped SrTiO₃ achieved degradation efficiencies of (92.5 %) for acid red (1 and 88.3 %) for acid black 1 within (120 min). The optical band gap was reduced from (3.21 eV) to (2.58 eV), and the kinetic rate constants increased up to (0.0146 and 0.0138 min⁻¹) respectively, highlighting significant improvements in photocatalytic performance under visible light.
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spelling doaj-art-7644008d6f1541cd8b2f8a4b2e364dd82025-08-26T02:38:16ZengTikrit UniversityTikrit Journal of Pure Science1813-16622415-17262025-08-0130410.25130/tjps.v30i4.1979Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite NanostructuresMohammed Khalaf Zidane0Islamic Azad University of East of Gilan, Islamic Republic of Iran Industrial effluents, especially those containing synthetic dyes which include acid red (AR) and acid black (AB), keep to pose excessive ecological and health dangers due to their balance and resistance to biodegradation. This takes a look at addresses this difficulty by using exploring Mn-doped SrTiO₃ perovskite nanostructures as photocatalysts below visible light situations. The substances have been synthesized thru the sol-gel path and comprehensively characterized using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Ultraviolet–Visible Diffuse Reflectance Spectroscopy (UV-Vis/DRS), Brunauer–Emmett–Teller (BET) surface analysis, and Fourier Transform Infrared Spectroscopy (FTIR). surface analysis. Photocatalytic exams were done beneath visible light publicity to assess dye elimination efficiency and determine the role of operational factors such as pH, catalyst dose, and preliminary dye load. The creation of Mn into the SrTiO₃ lattice caused outstanding enhancements in seen-mild absorption and charge separation, allowing degradation efficiencies exceeding (90%) inside a hundred and twenty mins. These outcomes affirm the potential of Mn-doped SrTiO₃ as a viable photocatalyst for dye-contaminated wastewater treatment utilizing solar or artificial light sources The Mn-doped SrTiO₃ achieved degradation efficiencies of (92.5 %) for acid red (1 and 88.3 %) for acid black 1 within (120 min). The optical band gap was reduced from (3.21 eV) to (2.58 eV), and the kinetic rate constants increased up to (0.0146 and 0.0138 min⁻¹) respectively, highlighting significant improvements in photocatalytic performance under visible light. https://www.tjpsj.org/index.php/tjps/article/view/1979Photocatalysis; Mn-doped SrTiO₃Acid Red dye; Acid Black dye; Perovskite
spellingShingle Mohammed Khalaf Zidane
Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures
Tikrit Journal of Pure Science
Photocatalysis; Mn-doped SrTiO₃
Acid Red dye; Acid Black dye; Perovskite
title Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures
title_full Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures
title_fullStr Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures
title_full_unstemmed Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures
title_short Photocatalytic Degradation of Acid Red and Acid Black Dyes Using Mn-Doped SrTiO₃ Perovskite Nanostructures
title_sort photocatalytic degradation of acid red and acid black dyes using mn doped srtio₃ perovskite nanostructures
topic Photocatalysis; Mn-doped SrTiO₃
Acid Red dye; Acid Black dye; Perovskite
url https://www.tjpsj.org/index.php/tjps/article/view/1979
work_keys_str_mv AT mohammedkhalafzidane photocatalyticdegradationofacidredandacidblackdyesusingmndopedsrtio3perovskitenanostructures