Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry

A solid phase preconcentration procedure using SBA-3 nanosorbent for the fast separation and preconcentration of crystal violet (CV) in water samples by fiber optic-linear array detection spectrophotometry (FO-LADS) is presented. Experimental parameters including pH, sample volume, amount of sorbent...

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Main Authors: Azam Azarkohan, Farzaneh Shemirani, Mahrouz Alvand
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/530843
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author Azam Azarkohan
Farzaneh Shemirani
Mahrouz Alvand
author_facet Azam Azarkohan
Farzaneh Shemirani
Mahrouz Alvand
author_sort Azam Azarkohan
collection DOAJ
description A solid phase preconcentration procedure using SBA-3 nanosorbent for the fast separation and preconcentration of crystal violet (CV) in water samples by fiber optic-linear array detection spectrophotometry (FO-LADS) is presented. Experimental parameters including pH, sample volume, amount of sorbent, type, volume, and concentration of eluent that affect the recovery of crystal violet have been optimized. Under optimized experimental conditions, analytical parameters including limit of detection, linear working range, and relative standard deviation have also been determined. A preconcentration factor of 200 was achieved in this method. In the initial solution, the detection limit for CV was found as 1.3 μg L−1. Under optimal conditions maximum adsorption capacity was obtained as 344.83 mg g−1. Also, the relative standard deviation was less than ±1.3% (n=5). The presented procedure was applied to the determination of crystal violet in water samples (fish, fish farming water, and river water) with good results.
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issn 2090-9063
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publishDate 2013-01-01
publisher Wiley
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spelling doaj-art-7543cfc705f7488fa1b9b0c47ae6b3eb2025-08-20T02:07:13ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/530843530843Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection SpectrophotometryAzam Azarkohan0Farzaneh Shemirani1Mahrouz Alvand2Department of Analytical Chemistry, Faculty of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, IranDepartment of Analytical Chemistry, Faculty of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, IranDepartment of Analytical Chemistry, Faculty of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, IranA solid phase preconcentration procedure using SBA-3 nanosorbent for the fast separation and preconcentration of crystal violet (CV) in water samples by fiber optic-linear array detection spectrophotometry (FO-LADS) is presented. Experimental parameters including pH, sample volume, amount of sorbent, type, volume, and concentration of eluent that affect the recovery of crystal violet have been optimized. Under optimized experimental conditions, analytical parameters including limit of detection, linear working range, and relative standard deviation have also been determined. A preconcentration factor of 200 was achieved in this method. In the initial solution, the detection limit for CV was found as 1.3 μg L−1. Under optimal conditions maximum adsorption capacity was obtained as 344.83 mg g−1. Also, the relative standard deviation was less than ±1.3% (n=5). The presented procedure was applied to the determination of crystal violet in water samples (fish, fish farming water, and river water) with good results.http://dx.doi.org/10.1155/2013/530843
spellingShingle Azam Azarkohan
Farzaneh Shemirani
Mahrouz Alvand
Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry
Journal of Chemistry
title Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry
title_full Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry
title_fullStr Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry
title_full_unstemmed Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry
title_short Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry
title_sort fast analysis of water samples for trace amount of crystal violet dye based on solid phase extraction using nanoporous sba 3 prior to determination by fiber optic linear array detection spectrophotometry
url http://dx.doi.org/10.1155/2013/530843
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AT farzanehshemirani fastanalysisofwatersamplesfortraceamountofcrystalvioletdyebasedonsolidphaseextractionusingnanoporoussba3priortodeterminationbyfiberopticlineararraydetectionspectrophotometry
AT mahrouzalvand fastanalysisofwatersamplesfortraceamountofcrystalvioletdyebasedonsolidphaseextractionusingnanoporoussba3priortodeterminationbyfiberopticlineararraydetectionspectrophotometry