Characterization of Rice Husk for Graphene Extraction and Metallization

Rice husk, an underutilized agricultural waste product, serves as a potential precursor for graphene synthesis. This study focuses on synthesizing and characterizing graphene through the chemical exfoliation method, employing advanced analytical techniques to explore its potential applications in m...

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Main Authors: Harrison Okechukwu Onovo, Ademola Abiona Agbeleye, Theddeus Tochukwu Akano, Olamilekan Razak Oloyede, Solomon Oaolapo Oyegbami, Emmanuel Oluwatimilehin Amoo
Format: Article
Language:English
Published: College of Engineering of Afe Babalola University, Ado-Ekiti (ABUAD), Ekiti State, Nigeria 2024-12-01
Series:ABUAD Journal of Engineering Research and Development
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Online Access:https://www.journals.abuad.edu.ng/index.php/ajerd/article/view/995
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author Harrison Okechukwu Onovo
Ademola Abiona Agbeleye
Theddeus Tochukwu Akano
Olamilekan Razak Oloyede
Solomon Oaolapo Oyegbami
Emmanuel Oluwatimilehin Amoo
author_facet Harrison Okechukwu Onovo
Ademola Abiona Agbeleye
Theddeus Tochukwu Akano
Olamilekan Razak Oloyede
Solomon Oaolapo Oyegbami
Emmanuel Oluwatimilehin Amoo
author_sort Harrison Okechukwu Onovo
collection DOAJ
description Rice husk, an underutilized agricultural waste product, serves as a potential precursor for graphene synthesis. This study focuses on synthesizing and characterizing graphene through the chemical exfoliation method, employing advanced analytical techniques to explore its potential applications in metallization. Graphene was produced by chemically activating rice husk ash (RHA) with potassium hydroxide (KOH) at 800 ºC. The extracted graphene underwent analysis using various techniques. X-ray Diffraction (XRD) confirmed the material's crystalline nature and graphitic structure. Fourier-Transform Infrared Spectroscopy (FTIR) identified typical functional groups present in the synthesized graphene. Raman Spectroscopy revealed significant defects and confirmed that the graphene consists of single or few-layer thin sheets. Transmission Electron Microscopy (TEM) showed the presence of thin graphene sheets and nanoparticles with sizes ranging from 1.47 nm to 5.80 nm. Ultraviolet-Visible Spectroscopy (UV-Vis) confirmed electronic structure and optical properties, essential for metallization. X-ray Fluorescence (XRF) confirmed the purity of the graphene, while Brunauer-Emmett-Teller (BET) analysis revealed a high specific surface area, making the material suitable for surface-based applications. Electrical conductivity tests demonstrated good conductivity in the lower to moderate current range. The study underscores the potential of rice husk-derived graphene for metallization, offering a cost-effective and eco-friendly synthesis method for industrial and commercial applications.
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publishDate 2024-12-01
publisher College of Engineering of Afe Babalola University, Ado-Ekiti (ABUAD), Ekiti State, Nigeria
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spelling doaj-art-751f6ec4815b493c80465f751c7520992025-08-20T02:50:47ZengCollege of Engineering of Afe Babalola University, Ado-Ekiti (ABUAD), Ekiti State, NigeriaABUAD Journal of Engineering Research and Development2756-68112645-26852024-12-017210.53982/ajerd.2024.0702.50-jCharacterization of Rice Husk for Graphene Extraction and MetallizationHarrison Okechukwu Onovo0Ademola Abiona Agbeleye1Theddeus Tochukwu Akano2Olamilekan Razak Oloyede3Solomon Oaolapo Oyegbami4Emmanuel Oluwatimilehin Amoo5Department of Metallurgical and Materials Engineering, Faculty of Engineering, University of Lagos 101017, NigeriaDepartment of Metallurgical and Materials Engineering, Faculty of Engineering, University of Lagos 101017, NigeriaDepartment of Mechanical Engineering, University of Botswana Gaborone, BotswanaDepartment of Mechanical and Mechatronics Engineering, Afe Babalola University, Ado Ekiti, NigeriaDepartment of Metallurgical and Materials Engineering, College of Engineering, Yaba College of Technology, Lagos NigeriaDepartment of Metallurgical and Materials Engineering, Faculty of Engineering, University of Lagos 101017, Nigeria Rice husk, an underutilized agricultural waste product, serves as a potential precursor for graphene synthesis. This study focuses on synthesizing and characterizing graphene through the chemical exfoliation method, employing advanced analytical techniques to explore its potential applications in metallization. Graphene was produced by chemically activating rice husk ash (RHA) with potassium hydroxide (KOH) at 800 ºC. The extracted graphene underwent analysis using various techniques. X-ray Diffraction (XRD) confirmed the material's crystalline nature and graphitic structure. Fourier-Transform Infrared Spectroscopy (FTIR) identified typical functional groups present in the synthesized graphene. Raman Spectroscopy revealed significant defects and confirmed that the graphene consists of single or few-layer thin sheets. Transmission Electron Microscopy (TEM) showed the presence of thin graphene sheets and nanoparticles with sizes ranging from 1.47 nm to 5.80 nm. Ultraviolet-Visible Spectroscopy (UV-Vis) confirmed electronic structure and optical properties, essential for metallization. X-ray Fluorescence (XRF) confirmed the purity of the graphene, while Brunauer-Emmett-Teller (BET) analysis revealed a high specific surface area, making the material suitable for surface-based applications. Electrical conductivity tests demonstrated good conductivity in the lower to moderate current range. The study underscores the potential of rice husk-derived graphene for metallization, offering a cost-effective and eco-friendly synthesis method for industrial and commercial applications. https://www.journals.abuad.edu.ng/index.php/ajerd/article/view/995Agricultural wasteChemical exfoliationGrapheneMetallizationPotassium HydroxideRice Husk
spellingShingle Harrison Okechukwu Onovo
Ademola Abiona Agbeleye
Theddeus Tochukwu Akano
Olamilekan Razak Oloyede
Solomon Oaolapo Oyegbami
Emmanuel Oluwatimilehin Amoo
Characterization of Rice Husk for Graphene Extraction and Metallization
ABUAD Journal of Engineering Research and Development
Agricultural waste
Chemical exfoliation
Graphene
Metallization
Potassium Hydroxide
Rice Husk
title Characterization of Rice Husk for Graphene Extraction and Metallization
title_full Characterization of Rice Husk for Graphene Extraction and Metallization
title_fullStr Characterization of Rice Husk for Graphene Extraction and Metallization
title_full_unstemmed Characterization of Rice Husk for Graphene Extraction and Metallization
title_short Characterization of Rice Husk for Graphene Extraction and Metallization
title_sort characterization of rice husk for graphene extraction and metallization
topic Agricultural waste
Chemical exfoliation
Graphene
Metallization
Potassium Hydroxide
Rice Husk
url https://www.journals.abuad.edu.ng/index.php/ajerd/article/view/995
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AT olamilekanrazakoloyede characterizationofricehuskforgrapheneextractionandmetallization
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