The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
The toxicity of oxytetracycline (OTC) antibiotic remains in the environment and threatens the life of living things. In this research, two series of ZnO nanoparticle catalysts with different particle sizes were prepared.. The structural and optical characteristics of the samples were analyzed and th...
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Iranian Environmental Mutagen Society
2024-05-01
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Series: | Journal of Water and Environmental Nanotechnology |
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Online Access: | https://www.jwent.net/article_713103_10869d53f0a819db492800f6ccb7fd60.pdf |
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author | Reza Torkamani Bagher Aslibeiki Masih Darbandi Hamid Naghshara |
author_facet | Reza Torkamani Bagher Aslibeiki Masih Darbandi Hamid Naghshara |
author_sort | Reza Torkamani |
collection | DOAJ |
description | The toxicity of oxytetracycline (OTC) antibiotic remains in the environment and threatens the life of living things. In this research, two series of ZnO nanoparticle catalysts with different particle sizes were prepared.. The structural and optical characteristics of the samples were analyzed and the photocatalytic degradation of OTC was investigated under a 100 W visible light irradiation. The samples prepared using zinc nitrate and zinc acetate showed different photocatalytic performance. The catalysts prepared at lower calcination temperatures show higher photocatalytic performance due to the active surface of the particles. The intensity of the peaks in the XRD patterns of samples also increases with increasing calcination temperature, which confirms the increase in the size of the nanoparticles. The decrease in particle size with increasing calcination temperature was confirmed by FESEM images. On the other hand, the band gap energy was reduced by decreasing the calcination temperature, which increases the performance of the photocatalytic activity. The 27 nm ZnO nanoparticles prepared using zinc nitrate showed 100 % degradation efficiency. As a result, we reached the maximum performance of pure ZnO by only controlling the size and morphology, without making nanocomposite or doping different elements. |
format | Article |
id | doaj-art-74ba08e757f540a193295402a1750bb7 |
institution | Kabale University |
issn | 2476-7204 2476-6615 |
language | English |
publishDate | 2024-05-01 |
publisher | Iranian Environmental Mutagen Society |
record_format | Article |
series | Journal of Water and Environmental Nanotechnology |
spelling | doaj-art-74ba08e757f540a193295402a1750bb72025-01-12T09:34:26ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152024-05-019218619510.22090/jwent.2024.02.05713103The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticlesReza Torkamani0Bagher Aslibeiki1Masih Darbandi2Hamid Naghshara3Faculty of Physics, University of Tabriz, Tabriz, IranFaculty of Physics, University of Tabriz, Tabriz, IranNanomaterials Research Laboratory, Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, IranFaculty of Physics, University of Tabriz, Tabriz, IranThe toxicity of oxytetracycline (OTC) antibiotic remains in the environment and threatens the life of living things. In this research, two series of ZnO nanoparticle catalysts with different particle sizes were prepared.. The structural and optical characteristics of the samples were analyzed and the photocatalytic degradation of OTC was investigated under a 100 W visible light irradiation. The samples prepared using zinc nitrate and zinc acetate showed different photocatalytic performance. The catalysts prepared at lower calcination temperatures show higher photocatalytic performance due to the active surface of the particles. The intensity of the peaks in the XRD patterns of samples also increases with increasing calcination temperature, which confirms the increase in the size of the nanoparticles. The decrease in particle size with increasing calcination temperature was confirmed by FESEM images. On the other hand, the band gap energy was reduced by decreasing the calcination temperature, which increases the performance of the photocatalytic activity. The 27 nm ZnO nanoparticles prepared using zinc nitrate showed 100 % degradation efficiency. As a result, we reached the maximum performance of pure ZnO by only controlling the size and morphology, without making nanocomposite or doping different elements.https://www.jwent.net/article_713103_10869d53f0a819db492800f6ccb7fd60.pdfzinc oxidecatalystsvisible lightoxytetracycline |
spellingShingle | Reza Torkamani Bagher Aslibeiki Masih Darbandi Hamid Naghshara The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles Journal of Water and Environmental Nanotechnology zinc oxide catalysts visible light oxytetracycline |
title | The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles |
title_full | The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles |
title_fullStr | The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles |
title_full_unstemmed | The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles |
title_short | The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles |
title_sort | effect of particle size on photocatalytic degradation of oxytetracycline by zno nanoparticles |
topic | zinc oxide catalysts visible light oxytetracycline |
url | https://www.jwent.net/article_713103_10869d53f0a819db492800f6ccb7fd60.pdf |
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