The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles

The toxicity of oxytetracycline (OTC) antibiotic remains in the environment and threatens the life of living things. In this research, two series of ZnO nanoparticle catalysts with different particle sizes were prepared.. The structural and optical characteristics of the samples were analyzed and th...

Full description

Saved in:
Bibliographic Details
Main Authors: Reza Torkamani, Bagher Aslibeiki, Masih Darbandi, Hamid Naghshara
Format: Article
Language:English
Published: Iranian Environmental Mutagen Society 2024-05-01
Series:Journal of Water and Environmental Nanotechnology
Subjects:
Online Access:https://www.jwent.net/article_713103_10869d53f0a819db492800f6ccb7fd60.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841545206003924992
author Reza Torkamani
Bagher Aslibeiki
Masih Darbandi
Hamid Naghshara
author_facet Reza Torkamani
Bagher Aslibeiki
Masih Darbandi
Hamid Naghshara
author_sort Reza Torkamani
collection DOAJ
description The toxicity of oxytetracycline (OTC) antibiotic remains in the environment and threatens the life of living things. In this research, two series of ZnO nanoparticle catalysts with different particle sizes were prepared.. The structural and optical characteristics of the samples were analyzed and the photocatalytic degradation of OTC was investigated under a 100 W visible light irradiation. The samples prepared using zinc nitrate and zinc acetate showed different photocatalytic performance. The catalysts prepared at lower calcination temperatures show higher photocatalytic performance due to the active surface of the particles. The intensity of the peaks in the XRD patterns of samples also increases with increasing calcination temperature, which confirms the increase in the size of the nanoparticles. The decrease in particle size with increasing calcination temperature was confirmed by FESEM images. On the other hand, the band gap energy was reduced by decreasing the calcination temperature, which increases the performance of the photocatalytic activity. The 27 nm ZnO nanoparticles prepared using zinc nitrate showed 100 % degradation efficiency. As a result, we reached the maximum performance of pure ZnO by only controlling the size and morphology, without making nanocomposite or doping different elements.
format Article
id doaj-art-74ba08e757f540a193295402a1750bb7
institution Kabale University
issn 2476-7204
2476-6615
language English
publishDate 2024-05-01
publisher Iranian Environmental Mutagen Society
record_format Article
series Journal of Water and Environmental Nanotechnology
spelling doaj-art-74ba08e757f540a193295402a1750bb72025-01-12T09:34:26ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152024-05-019218619510.22090/jwent.2024.02.05713103The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticlesReza Torkamani0Bagher Aslibeiki1Masih Darbandi2Hamid Naghshara3Faculty of Physics, University of Tabriz, Tabriz, IranFaculty of Physics, University of Tabriz, Tabriz, IranNanomaterials Research Laboratory, Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, IranFaculty of Physics, University of Tabriz, Tabriz, IranThe toxicity of oxytetracycline (OTC) antibiotic remains in the environment and threatens the life of living things. In this research, two series of ZnO nanoparticle catalysts with different particle sizes were prepared.. The structural and optical characteristics of the samples were analyzed and the photocatalytic degradation of OTC was investigated under a 100 W visible light irradiation. The samples prepared using zinc nitrate and zinc acetate showed different photocatalytic performance. The catalysts prepared at lower calcination temperatures show higher photocatalytic performance due to the active surface of the particles. The intensity of the peaks in the XRD patterns of samples also increases with increasing calcination temperature, which confirms the increase in the size of the nanoparticles. The decrease in particle size with increasing calcination temperature was confirmed by FESEM images. On the other hand, the band gap energy was reduced by decreasing the calcination temperature, which increases the performance of the photocatalytic activity. The 27 nm ZnO nanoparticles prepared using zinc nitrate showed 100 % degradation efficiency. As a result, we reached the maximum performance of pure ZnO by only controlling the size and morphology, without making nanocomposite or doping different elements.https://www.jwent.net/article_713103_10869d53f0a819db492800f6ccb7fd60.pdfzinc oxidecatalystsvisible lightoxytetracycline
spellingShingle Reza Torkamani
Bagher Aslibeiki
Masih Darbandi
Hamid Naghshara
The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
Journal of Water and Environmental Nanotechnology
zinc oxide
catalysts
visible light
oxytetracycline
title The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
title_full The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
title_fullStr The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
title_full_unstemmed The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
title_short The effect of particle size on photocatalytic degradation of oxytetracycline by ZnO nanoparticles
title_sort effect of particle size on photocatalytic degradation of oxytetracycline by zno nanoparticles
topic zinc oxide
catalysts
visible light
oxytetracycline
url https://www.jwent.net/article_713103_10869d53f0a819db492800f6ccb7fd60.pdf
work_keys_str_mv AT rezatorkamani theeffectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT bagheraslibeiki theeffectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT masihdarbandi theeffectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT hamidnaghshara theeffectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT rezatorkamani effectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT bagheraslibeiki effectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT masihdarbandi effectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles
AT hamidnaghshara effectofparticlesizeonphotocatalyticdegradationofoxytetracyclinebyznonanoparticles