Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans

Bombardier beetles have evolved a sophisticated and unique chemical defence mechanism involving controlled explosions within their paired defensive glands, producing a hot, benzoquinone-rich defensive spray. The molecular basis of this response is not well characterized. We therefore combined the tr...

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Main Authors: Heiko Vogel, Nicolai Rügen, Natalie Wielsch, Richard M. Twyman, Miray Tonk-Rügen, Andreas Vilcinskas
Format: Article
Language:English
Published: The Royal Society 2025-05-01
Series:Royal Society Open Science
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Online Access:https://royalsocietypublishing.org/doi/10.1098/rsos.241823
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author Heiko Vogel
Nicolai Rügen
Natalie Wielsch
Richard M. Twyman
Miray Tonk-Rügen
Andreas Vilcinskas
author_facet Heiko Vogel
Nicolai Rügen
Natalie Wielsch
Richard M. Twyman
Miray Tonk-Rügen
Andreas Vilcinskas
author_sort Heiko Vogel
collection DOAJ
description Bombardier beetles have evolved a sophisticated and unique chemical defence mechanism involving controlled explosions within their paired defensive glands, producing a hot, benzoquinone-rich defensive spray. The molecular basis of this response is not well characterized. We therefore combined the transcriptomic and proteomic analysis of different gland compartments in the bombardier beetle Brachinus crepitans (Linnaeus, 1758) (Coleoptera, Carabidae) to identify abundant transcripts and gland-specific proteins with key defensive functions, such as catalases, peroxidases and enzymes involved in hydroquinone synthesis. By combining precise dissections with protein sequence analysis, we built a comprehensive atlas of the relevant proteins and their spatio-temporal organization. We found that glucose is important as a stable precursor of hydrogen peroxide and hydroquinone. These chemicals, together with gland-specific peroxidases and catalases, then initiate the explosive defence reaction. We also present evidence that the evolution of explosive secretions involved the functional adaptation of peroxidase genes involving atypical substitutions in otherwise highly conserved protein domains.
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spelling doaj-art-746c27d88165406da0bb4ce9fbe2e59a2025-08-20T03:08:17ZengThe Royal SocietyRoyal Society Open Science2054-57032025-05-0112510.1098/rsos.241823Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitansHeiko Vogel0Nicolai Rügen1Natalie Wielsch2Richard M. Twyman3Miray Tonk-Rügen4Andreas Vilcinskas5Department of Insect Symbiosis, Max Planck Institute for Chemical Ecology, Jena, GermanyBranch for Bioresources, Fraunhofer Institute for Molecular Biology and Applied Ecology IME, Giessen, Hessen 35392, GermanyResearch Group Mass Spectrometry/Proteomics, Max-Planck-Institute for Chemical Ecology, Jena, Thüringen 07745, GermanyTRM Ltd, Scarborough, UKInstitute for Insect Biotechnology, Justus Liebig Universitat Giessen, Giessen, Hessen 35392, GermanyBranch for Bioresources, Fraunhofer Institute for Molecular Biology and Applied Ecology IME, Giessen, Hessen 35392, GermanyBombardier beetles have evolved a sophisticated and unique chemical defence mechanism involving controlled explosions within their paired defensive glands, producing a hot, benzoquinone-rich defensive spray. The molecular basis of this response is not well characterized. We therefore combined the transcriptomic and proteomic analysis of different gland compartments in the bombardier beetle Brachinus crepitans (Linnaeus, 1758) (Coleoptera, Carabidae) to identify abundant transcripts and gland-specific proteins with key defensive functions, such as catalases, peroxidases and enzymes involved in hydroquinone synthesis. By combining precise dissections with protein sequence analysis, we built a comprehensive atlas of the relevant proteins and their spatio-temporal organization. We found that glucose is important as a stable precursor of hydrogen peroxide and hydroquinone. These chemicals, together with gland-specific peroxidases and catalases, then initiate the explosive defence reaction. We also present evidence that the evolution of explosive secretions involved the functional adaptation of peroxidase genes involving atypical substitutions in otherwise highly conserved protein domains.https://royalsocietypublishing.org/doi/10.1098/rsos.241823chemical defenceomicshydroquinonehydrogen peroxidebombardier beetlesBrachinus crepitans
spellingShingle Heiko Vogel
Nicolai Rügen
Natalie Wielsch
Richard M. Twyman
Miray Tonk-Rügen
Andreas Vilcinskas
Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans
Royal Society Open Science
chemical defence
omics
hydroquinone
hydrogen peroxide
bombardier beetles
Brachinus crepitans
title Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans
title_full Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans
title_fullStr Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans
title_full_unstemmed Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans
title_short Molecular basis of the explosive defence response in the bombardier beetle Brachinus crepitans
title_sort molecular basis of the explosive defence response in the bombardier beetle brachinus crepitans
topic chemical defence
omics
hydroquinone
hydrogen peroxide
bombardier beetles
Brachinus crepitans
url https://royalsocietypublishing.org/doi/10.1098/rsos.241823
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AT nataliewielsch molecularbasisoftheexplosivedefenceresponseinthebombardierbeetlebrachinuscrepitans
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