O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application

Porous-activated carbons (PAC) show a lot of applications in various fields due to their large surface area and appropriate pore volume, along with decent thermal, chemical, and mechanical stability. Because of these characteristics, PACs are the best choice as an electrode material in supercapacito...

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Main Authors: Pawan Singh Dhapola, Sushant Kumar, Manoj Karakoti, M.Z.A. Yahya, Vinay Deep Punetha, Sandeep Pandey, Faisal Islam Chowdhury, Serguei V. Savilov, Pramod K. Singh
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Chemical Physics Impact
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Online Access:http://www.sciencedirect.com/science/article/pii/S2667022424002652
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author Pawan Singh Dhapola
Sushant Kumar
Manoj Karakoti
M.Z.A. Yahya
Vinay Deep Punetha
Sandeep Pandey
Faisal Islam Chowdhury
Serguei V. Savilov
Pramod K. Singh
author_facet Pawan Singh Dhapola
Sushant Kumar
Manoj Karakoti
M.Z.A. Yahya
Vinay Deep Punetha
Sandeep Pandey
Faisal Islam Chowdhury
Serguei V. Savilov
Pramod K. Singh
author_sort Pawan Singh Dhapola
collection DOAJ
description Porous-activated carbons (PAC) show a lot of applications in various fields due to their large surface area and appropriate pore volume, along with decent thermal, chemical, and mechanical stability. Because of these characteristics, PACs are the best choice as an electrode material in supercapacitors (SCs). Due to the utility of PACs, this work reports the transformation of polyvinyl chloride (PVC) into PAC with a surface area of 162.40 m2/g. The synthesized PAC exhibits a maximum specific capacitance (CSP) of 40 F/g at five mV/s in 1-ethyl-3- methylimidazolium thiocyanate ionic liquid (EMIM SCN-IL) electrolyte. Also, no degradation was recorded in the initial Csp of the fabricated SC, even after 9000 cycles at room temperature. Additionally, using the same PAC in counter electrode dye-sensitized solar cell (DSSC) was also fabricated, and the cell was tested at 1 sun condition, which shows a fill factor of 59.37 % and an efficiency of 1.42 %.
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issn 2667-0224
language English
publishDate 2024-12-01
publisher Elsevier
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series Chemical Physics Impact
spelling doaj-art-7460a5ddbb2444baa03a49c075caeabf2025-08-20T01:52:44ZengElsevierChemical Physics Impact2667-02242024-12-01910072110.1016/j.chphi.2024.100721O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells applicationPawan Singh Dhapola0Sushant Kumar1Manoj Karakoti2M.Z.A. Yahya3Vinay Deep Punetha4Sandeep Pandey5Faisal Islam Chowdhury6Serguei V. Savilov7Pramod K. Singh8Center for Solar Cells & Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, India; Corresponding author.Center for Solar Cells & Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, IndiaInstitute of Macromolecular Chemistry, Academy of Science of the Czech Republic 16206, Prague 6, Czech RepublicFaculty of Defence Science and Technology, Universiti Pertahanan Nasional Malaysia (UPNM) 57000, Kuala Lumpur, MalaysiaCentre of Excellence for Research, P Savani University, Gujrat, India; Corresponding author.Professor Rajendra Singh Nanosciene and Nanotechnology Centre, Department of Chemistry, DSB Campus, Kumaun University, Nainital, Uttarakhand, IndiaDepartment of Chemistry, University of Chittagong, Chattogram, BangladeshDepartment of Chemistry, Lomonosov Moscow State University, 1–3 Leninskiye Gory, Moscow 119991, RussiaCenter for Solar Cells & Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, India; Corresponding author.Porous-activated carbons (PAC) show a lot of applications in various fields due to their large surface area and appropriate pore volume, along with decent thermal, chemical, and mechanical stability. Because of these characteristics, PACs are the best choice as an electrode material in supercapacitors (SCs). Due to the utility of PACs, this work reports the transformation of polyvinyl chloride (PVC) into PAC with a surface area of 162.40 m2/g. The synthesized PAC exhibits a maximum specific capacitance (CSP) of 40 F/g at five mV/s in 1-ethyl-3- methylimidazolium thiocyanate ionic liquid (EMIM SCN-IL) electrolyte. Also, no degradation was recorded in the initial Csp of the fabricated SC, even after 9000 cycles at room temperature. Additionally, using the same PAC in counter electrode dye-sensitized solar cell (DSSC) was also fabricated, and the cell was tested at 1 sun condition, which shows a fill factor of 59.37 % and an efficiency of 1.42 %.http://www.sciencedirect.com/science/article/pii/S2667022424002652Porous activated carbonSupercapacitorLow-frequency impedance spectroscopyCyclic voltammetryIonic liquidDye-sensitized solar cell
spellingShingle Pawan Singh Dhapola
Sushant Kumar
Manoj Karakoti
M.Z.A. Yahya
Vinay Deep Punetha
Sandeep Pandey
Faisal Islam Chowdhury
Serguei V. Savilov
Pramod K. Singh
O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
Chemical Physics Impact
Porous activated carbon
Supercapacitor
Low-frequency impedance spectroscopy
Cyclic voltammetry
Ionic liquid
Dye-sensitized solar cell
title O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
title_full O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
title_fullStr O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
title_full_unstemmed O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
title_short O, N co-doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
title_sort o n co doped porous activated carbon from polyvinyl chloride for super capacitors and solar cells application
topic Porous activated carbon
Supercapacitor
Low-frequency impedance spectroscopy
Cyclic voltammetry
Ionic liquid
Dye-sensitized solar cell
url http://www.sciencedirect.com/science/article/pii/S2667022424002652
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