Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data

The aim of this paper is to review the actual data on the chemical bond in binary and mixed oxides. The electronegativity (χM) and the acidity pa scales are the most significant semi-empirical concepts for predicting the trend of bonding character in iono-covalent oxides. A satisfactory correlatio...

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Main Author: M. Lenglet
Format: Article
Language:English
Published: Wiley 2004-01-01
Series:Active and Passive Electronic Components
Online Access:http://dx.doi.org/10.1080/0882751031000116142
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author M. Lenglet
author_facet M. Lenglet
author_sort M. Lenglet
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description The aim of this paper is to review the actual data on the chemical bond in binary and mixed oxides. The electronegativity (χM) and the acidity pa scales are the most significant semi-empirical concepts for predicting the trend of bonding character in iono-covalent oxides. A satisfactory correlation between the data issued from the acidity scale and the calculated ionic charges has been established.
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publishDate 2004-01-01
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series Active and Passive Electronic Components
spelling doaj-art-74107bcdd96148a69fb99e625d5238832025-08-20T02:06:48ZengWileyActive and Passive Electronic Components0882-75161563-50312004-01-0127116010.1080/0882751031000116142Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical DataM. Lenglet0Université de Rouen, LASTSM, IUT, Mont Saint Aignan Cedex 76821, FranceThe aim of this paper is to review the actual data on the chemical bond in binary and mixed oxides. The electronegativity (χM) and the acidity pa scales are the most significant semi-empirical concepts for predicting the trend of bonding character in iono-covalent oxides. A satisfactory correlation between the data issued from the acidity scale and the calculated ionic charges has been established.http://dx.doi.org/10.1080/0882751031000116142
spellingShingle M. Lenglet
Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data
Active and Passive Electronic Components
title Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data
title_full Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data
title_fullStr Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data
title_full_unstemmed Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data
title_short Iono-Covalent Character of the Metal–Oxygen Bonds in Oxides: A Comparison of Experimental and Theoretical Data
title_sort iono covalent character of the metal oxygen bonds in oxides a comparison of experimental and theoretical data
url http://dx.doi.org/10.1080/0882751031000116142
work_keys_str_mv AT mlenglet ionocovalentcharacterofthemetaloxygenbondsinoxidesacomparisonofexperimentalandtheoreticaldata