Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide

Abstract The primary aim of this study is to examine the rheological attributes of graphene oxide (GO)-reinforced gum ghatti-cl-poly(AA)/GO (GGAAGO) hydrogels, with the intent of improving their mechanical and thermal properties. Thermal gravimetric analysis (TGA) was employed to assess the thermal...

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Main Authors: Pragnesh N. Dave, Pradip M. Macwan, Bhagvan Kamaliya, Arvind Kumar
Format: Article
Language:English
Published: SpringerOpen 2025-02-01
Series:Journal of Materials Science: Materials in Engineering
Subjects:
Online Access:https://doi.org/10.1186/s40712-024-00148-w
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author Pragnesh N. Dave
Pradip M. Macwan
Bhagvan Kamaliya
Arvind Kumar
author_facet Pragnesh N. Dave
Pradip M. Macwan
Bhagvan Kamaliya
Arvind Kumar
author_sort Pragnesh N. Dave
collection DOAJ
description Abstract The primary aim of this study is to examine the rheological attributes of graphene oxide (GO)-reinforced gum ghatti-cl-poly(AA)/GO (GGAAGO) hydrogels, with the intent of improving their mechanical and thermal properties. Thermal gravimetric analysis (TGA) was employed to assess the thermal stability of the synthesized hydrogels, revealing the interaction between GO, gum ghatti, and acrylic acid. This investigation centers on the swelling behavior and rheological assessments of the hydrogels. Various experiments were conducted on nanocomposite particle gels to scrutinize the impact of graphene oxide (GO) microparticle concentration (ranging from 0 to 5 mg) on network topology, swelling, and mechanical characteristics of the gels. The rheological analysis also indicates a reduction in viscosity. Furthermore, the rheological examination of hydrogels indicates that the storage modulus (G′) consistently surpasses the loss modulus (G″) within the linear viscoelastic zone across the entire frequency spectrum. This dominance of the storage modulus over the loss modulus suggests continuous covalent crosslinking, accounting for the solid-like and elastic nature (G′ > G″) of the hydrogels. All rheological parameters highlight commendable mechanical properties, rendering the composite hydrogel suitable for applications such as drug administration and various environmental uses.
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institution Kabale University
issn 3004-8958
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spelling doaj-art-74076a89000449dbbbbf471481b8e9ec2025-02-09T12:15:01ZengSpringerOpenJournal of Materials Science: Materials in Engineering3004-89582025-02-0120111210.1186/s40712-024-00148-wRheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxidePragnesh N. Dave0Pradip M. Macwan1Bhagvan Kamaliya2Arvind Kumar3Department of Chemistry, Sardar Patel UniversityB. N. Patel Institute of Paramedical & Science (Science Division)Department of Chemistry, Sardar Patel UniversitySalt and Marine Chemicals Division, G. B. Marg, CSIR-Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial ResearchAbstract The primary aim of this study is to examine the rheological attributes of graphene oxide (GO)-reinforced gum ghatti-cl-poly(AA)/GO (GGAAGO) hydrogels, with the intent of improving their mechanical and thermal properties. Thermal gravimetric analysis (TGA) was employed to assess the thermal stability of the synthesized hydrogels, revealing the interaction between GO, gum ghatti, and acrylic acid. This investigation centers on the swelling behavior and rheological assessments of the hydrogels. Various experiments were conducted on nanocomposite particle gels to scrutinize the impact of graphene oxide (GO) microparticle concentration (ranging from 0 to 5 mg) on network topology, swelling, and mechanical characteristics of the gels. The rheological analysis also indicates a reduction in viscosity. Furthermore, the rheological examination of hydrogels indicates that the storage modulus (G′) consistently surpasses the loss modulus (G″) within the linear viscoelastic zone across the entire frequency spectrum. This dominance of the storage modulus over the loss modulus suggests continuous covalent crosslinking, accounting for the solid-like and elastic nature (G′ > G″) of the hydrogels. All rheological parameters highlight commendable mechanical properties, rendering the composite hydrogel suitable for applications such as drug administration and various environmental uses.https://doi.org/10.1186/s40712-024-00148-wHydrogelRheologyRheological behaviorGraphene oxideMechanical propertiesFrequency sweep
spellingShingle Pragnesh N. Dave
Pradip M. Macwan
Bhagvan Kamaliya
Arvind Kumar
Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide
Journal of Materials Science: Materials in Engineering
Hydrogel
Rheology
Rheological behavior
Graphene oxide
Mechanical properties
Frequency sweep
title Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide
title_full Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide
title_fullStr Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide
title_full_unstemmed Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide
title_short Rheological investigations and swelling behavior of gum ghatti-cl-poly(acrylic acid) hydrogel reinforced with graphene oxide
title_sort rheological investigations and swelling behavior of gum ghatti cl poly acrylic acid hydrogel reinforced with graphene oxide
topic Hydrogel
Rheology
Rheological behavior
Graphene oxide
Mechanical properties
Frequency sweep
url https://doi.org/10.1186/s40712-024-00148-w
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AT pradipmmacwan rheologicalinvestigationsandswellingbehaviorofgumghatticlpolyacrylicacidhydrogelreinforcedwithgrapheneoxide
AT bhagvankamaliya rheologicalinvestigationsandswellingbehaviorofgumghatticlpolyacrylicacidhydrogelreinforcedwithgrapheneoxide
AT arvindkumar rheologicalinvestigationsandswellingbehaviorofgumghatticlpolyacrylicacidhydrogelreinforcedwithgrapheneoxide