Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust

In the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetr...

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Main Authors: N.T. Abdel-Ghani, G.A. El-Chaghaby, F. Helal
Format: Article
Language:English
Published: GJESM Publisher 2016-05-01
Series:Global Journal of Environmental Science and Management
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Online Access:http://www.gjesm.net/article_18506_122e80b95e26a3a2d5d9777194a05f65.pdf
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author N.T. Abdel-Ghani
G.A. El-Chaghaby
F. Helal
author_facet N.T. Abdel-Ghani
G.A. El-Chaghaby
F. Helal
author_sort N.T. Abdel-Ghani
collection DOAJ
description In the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric analyzer. The phenol adsorption capacity of the prepared carbons was evaluated. The different factors affecting phenol’s removal were studied including: contact time, solution pH and initial phenol concentration. The optimum phenol removal was obtained after a contact time of 300 min. and at an initial phenol solution pH 7. The maximum removal percentages were determined at 5mg/l initial phenol concentration as 79, 93, 94 and 98% for AC0, AC1, AC2 and AC3; respectively. The adsorption of phenol on African beech sawdust activated carbons was found to follow the Lagergren first order kinetics and the intraparticle diffusion mechanism gave a good fit to the experimental data. The isothermal models applied fitted the experimental data in the order: Langmuir> Dubinin–Radushkevich> Freundlich and Temkin.
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2383-3866
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publishDate 2016-05-01
publisher GJESM Publisher
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series Global Journal of Environmental Science and Management
spelling doaj-art-73e2393bf5284119bab464fa376b270e2025-02-02T10:54:56ZengGJESM PublisherGlobal Journal of Environmental Science and Management2383-35722383-38662016-05-012320922210.7508/gjesm.2016.03.00118506Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdustN.T. Abdel-Ghani0G.A. El-Chaghaby1F. Helal2Chemistry Department, Faculty of Science, Cairo University, Cairo, EgyptRegional Center for Food and Feed, Agricultural Research Center, Giza, EgyptScience and Technology Centerof Excellence, Ministry of Military Production, Cairo, EgyptIn the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric analyzer. The phenol adsorption capacity of the prepared carbons was evaluated. The different factors affecting phenol’s removal were studied including: contact time, solution pH and initial phenol concentration. The optimum phenol removal was obtained after a contact time of 300 min. and at an initial phenol solution pH 7. The maximum removal percentages were determined at 5mg/l initial phenol concentration as 79, 93, 94 and 98% for AC0, AC1, AC2 and AC3; respectively. The adsorption of phenol on African beech sawdust activated carbons was found to follow the Lagergren first order kinetics and the intraparticle diffusion mechanism gave a good fit to the experimental data. The isothermal models applied fitted the experimental data in the order: Langmuir> Dubinin–Radushkevich> Freundlich and Temkin.http://www.gjesm.net/article_18506_122e80b95e26a3a2d5d9777194a05f65.pdfActivated carbonBrunauer–emmett–teller (BET)Fourier transform infrared spectroscopy (FTIR)Isothermal modelingKinetics surface characteristicsPotassium hydroxide (KOH)Thermogravimetric analyzer (TGA)
spellingShingle N.T. Abdel-Ghani
G.A. El-Chaghaby
F. Helal
Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust
Global Journal of Environmental Science and Management
Activated carbon
Brunauer–emmett–teller (BET)
Fourier transform infrared spectroscopy (FTIR)
Isothermal modeling
Kinetics surface characteristics
Potassium hydroxide (KOH)
Thermogravimetric analyzer (TGA)
title Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust
title_full Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust
title_fullStr Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust
title_full_unstemmed Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust
title_short Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust
title_sort preparation characterization and phenol adsorption capacity of activated carbons from african beech wood sawdust
topic Activated carbon
Brunauer–emmett–teller (BET)
Fourier transform infrared spectroscopy (FTIR)
Isothermal modeling
Kinetics surface characteristics
Potassium hydroxide (KOH)
Thermogravimetric analyzer (TGA)
url http://www.gjesm.net/article_18506_122e80b95e26a3a2d5d9777194a05f65.pdf
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