O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review

A critical review of studies concerning the attribution of the provenance of marble from the Apuan Alps (Italy) (AAM) used for historical–monumental buildings and artefacts is proposed based on its O/C isotopic and EPR signature. First, a summary of the geological origin of AAM and its geo-structura...

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Main Authors: Massimo Coli, Francesco Di Benedetto, Antonella Buccianti
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/15/5/2533
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author Massimo Coli
Francesco Di Benedetto
Antonella Buccianti
author_facet Massimo Coli
Francesco Di Benedetto
Antonella Buccianti
author_sort Massimo Coli
collection DOAJ
description A critical review of studies concerning the attribution of the provenance of marble from the Apuan Alps (Italy) (AAM) used for historical–monumental buildings and artefacts is proposed based on its O/C isotopic and EPR signature. First, a summary of the geological origin of AAM and its geo-structural evolution and setting is presented. A review of the exploitation history of AAM is then discussed. This geological and historical information is used as categorical information to better constrain the literature multimethodic database, containing numerous data, including O/C isotopic and EPR spectroscopic parameters. A robust multivariate statistical analysis of the combination of all these data is performed. The results point to the fact that the O/C isotopic and EPR signature can help in attributing an analysed AAM sample to a marble extraction district, and to a certain extent also to a site, whereas the discrimination of the individual quarry appears to not yet be achievable.
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spelling doaj-art-73da82df6b0b46e9ad0935e4258e90f92025-08-20T02:05:23ZengMDPI AGApplied Sciences2076-34172025-02-01155253310.3390/app15052533O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical ReviewMassimo Coli0Francesco Di Benedetto1Antonella Buccianti2Department of Earth Sciences, Florence University, 50121 Firenze, ItalyDepartment of Earth Sciences, Ferrara University, 44122 Ferrara, ItalyDepartment of Earth Sciences, Florence University, 50121 Firenze, ItalyA critical review of studies concerning the attribution of the provenance of marble from the Apuan Alps (Italy) (AAM) used for historical–monumental buildings and artefacts is proposed based on its O/C isotopic and EPR signature. First, a summary of the geological origin of AAM and its geo-structural evolution and setting is presented. A review of the exploitation history of AAM is then discussed. This geological and historical information is used as categorical information to better constrain the literature multimethodic database, containing numerous data, including O/C isotopic and EPR spectroscopic parameters. A robust multivariate statistical analysis of the combination of all these data is performed. The results point to the fact that the O/C isotopic and EPR signature can help in attributing an analysed AAM sample to a marble extraction district, and to a certain extent also to a site, whereas the discrimination of the individual quarry appears to not yet be achievable.https://www.mdpi.com/2076-3417/15/5/2533Carrara marbleisotopeEPRdatabaseattribution
spellingShingle Massimo Coli
Francesco Di Benedetto
Antonella Buccianti
O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review
Applied Sciences
Carrara marble
isotope
EPR
database
attribution
title O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review
title_full O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review
title_fullStr O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review
title_full_unstemmed O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review
title_short O/C Isotopic and EPR Signature of Marble from the Apuan Alps (Italy): A Critical Review
title_sort o c isotopic and epr signature of marble from the apuan alps italy a critical review
topic Carrara marble
isotope
EPR
database
attribution
url https://www.mdpi.com/2076-3417/15/5/2533
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AT antonellabuccianti ocisotopicandeprsignatureofmarblefromtheapuanalpsitalyacriticalreview