Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
Abundant plastic waste degradation to microplastics may cause pollution hazards for the environment. The circulation of microplastic pollution supports the initiation of research related to detecting microplastics in the environment. One method for detecting microplastics is the utilization of the f...
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Universitas Indonesia
2025-01-01
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Online Access: | https://ijtech.eng.ui.ac.id/article/view/7376 |
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author | Nonni Soraya Sambudi Maissy Graceline Mulia Apriliana Cahya Khayrani Isnaeni Revathi Raviadaran Farhana Aziz Diva Dwira Permana Randy Suwandi Kenny Lischer |
author_facet | Nonni Soraya Sambudi Maissy Graceline Mulia Apriliana Cahya Khayrani Isnaeni Revathi Raviadaran Farhana Aziz Diva Dwira Permana Randy Suwandi Kenny Lischer |
author_sort | Nonni Soraya Sambudi |
collection | DOAJ |
description | Abundant plastic waste degradation to microplastics may cause pollution hazards for the environment. The circulation of microplastic pollution supports the initiation of research related to detecting microplastics in the environment. One method for detecting microplastics is the utilization of the fluorescence properties of carbon quantum dots (CQDs). In this study, CQDs will be produced through the hydrothermal method using oil palm fronds as a carbon source because of their lignin levels of up to 26%. To obtain this carbon, oil palm fronds are crushed and then converted into biochar through a pyrolysis process. Biochar is used as a precursor for the manufacture of CQDs produced through the hydrothermal method at temperature variations of 180°C, 190°C, and 200°C. In this study, CQDs were produced with a peak of 291 nm in the UV wavelength range, which indicates the presence of a ?-?* absorption band in the carbon structure of CQDs. The emergence of dominant C=C, O-H and C=O groups in the FTIR test also proves the success of CQDs production through this hydrothermal method. The CQDs produced at the three temperature variations are less than 10 nm in size and have the highest fluorescence intensity at 200? when excited at 405 nm. Moreover, CQDs exhibit a promising ability for detecting microplastics, as indicated by their decreasing fluorescence intensity trend in response to polyethylene (PE) and polyethylene terephthalate (PET) added solution. |
format | Article |
id | doaj-art-73514f8b45024659ab85b14472259219 |
institution | Kabale University |
issn | 2086-9614 2087-2100 |
language | English |
publishDate | 2025-01-01 |
publisher | Universitas Indonesia |
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series | International Journal of Technology |
spelling | doaj-art-73514f8b45024659ab85b144722592192025-01-31T14:13:03ZengUniversitas IndonesiaInternational Journal of Technology2086-96142087-21002025-01-0116123324210.14716/ijtech.v16i1.73767376Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics DetectionNonni Soraya Sambudi0Maissy Graceline Mulia1Apriliana Cahya Khayrani2Isnaeni3Revathi Raviadaran4Farhana Aziz5Diva Dwira Permana6Randy Suwandi7Kenny Lischer8Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Pertamina, Jakarta 12220, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia1. Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia 2. Research Center of Biomedical Engineering, Universitas Indonesia, Kampus UIResearch Center for Photonics, National Research and Innovation Agency, Building 442 KST BJ Habibie, South Tangerang 15314, IndonesiaDepartment of Energy Engineering, School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Johor 81310, MalaysiaDepartment of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, MalaysiaDepartment of Chemical Engineering, Faculty of Industrial Technology, Universitas Pertamina, Jakarta 12220, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia1. Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia 2. Research Center of Biomedical Engineering, Universitas Indonesia, Kampus UIAbundant plastic waste degradation to microplastics may cause pollution hazards for the environment. The circulation of microplastic pollution supports the initiation of research related to detecting microplastics in the environment. One method for detecting microplastics is the utilization of the fluorescence properties of carbon quantum dots (CQDs). In this study, CQDs will be produced through the hydrothermal method using oil palm fronds as a carbon source because of their lignin levels of up to 26%. To obtain this carbon, oil palm fronds are crushed and then converted into biochar through a pyrolysis process. Biochar is used as a precursor for the manufacture of CQDs produced through the hydrothermal method at temperature variations of 180°C, 190°C, and 200°C. In this study, CQDs were produced with a peak of 291 nm in the UV wavelength range, which indicates the presence of a ?-?* absorption band in the carbon structure of CQDs. The emergence of dominant C=C, O-H and C=O groups in the FTIR test also proves the success of CQDs production through this hydrothermal method. The CQDs produced at the three temperature variations are less than 10 nm in size and have the highest fluorescence intensity at 200? when excited at 405 nm. Moreover, CQDs exhibit a promising ability for detecting microplastics, as indicated by their decreasing fluorescence intensity trend in response to polyethylene (PE) and polyethylene terephthalate (PET) added solution.https://ijtech.eng.ui.ac.id/article/view/7376carbon quantum dotsfluorescencemicroplasticsoil palm frondsquenching |
spellingShingle | Nonni Soraya Sambudi Maissy Graceline Mulia Apriliana Cahya Khayrani Isnaeni Revathi Raviadaran Farhana Aziz Diva Dwira Permana Randy Suwandi Kenny Lischer Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection International Journal of Technology carbon quantum dots fluorescence microplastics oil palm fronds quenching |
title | Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection |
title_full | Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection |
title_fullStr | Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection |
title_full_unstemmed | Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection |
title_short | Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection |
title_sort | production of carbon quantum dots based on oil palm fronds for polyethylene and polyethylene terephthalate microplastics detection |
topic | carbon quantum dots fluorescence microplastics oil palm fronds quenching |
url | https://ijtech.eng.ui.ac.id/article/view/7376 |
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