Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection

Abundant plastic waste degradation to microplastics may cause pollution hazards for the environment. The circulation of microplastic pollution supports the initiation of research related to detecting microplastics in the environment. One method for detecting microplastics is the utilization of the f...

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Main Authors: Nonni Soraya Sambudi, Maissy Graceline Mulia, Apriliana Cahya Khayrani, Isnaeni, Revathi Raviadaran, Farhana Aziz, Diva Dwira Permana, Randy Suwandi, Kenny Lischer
Format: Article
Language:English
Published: Universitas Indonesia 2025-01-01
Series:International Journal of Technology
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Online Access:https://ijtech.eng.ui.ac.id/article/view/7376
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author Nonni Soraya Sambudi
Maissy Graceline Mulia
Apriliana Cahya Khayrani
Isnaeni
Revathi Raviadaran
Farhana Aziz
Diva Dwira Permana
Randy Suwandi
Kenny Lischer
author_facet Nonni Soraya Sambudi
Maissy Graceline Mulia
Apriliana Cahya Khayrani
Isnaeni
Revathi Raviadaran
Farhana Aziz
Diva Dwira Permana
Randy Suwandi
Kenny Lischer
author_sort Nonni Soraya Sambudi
collection DOAJ
description Abundant plastic waste degradation to microplastics may cause pollution hazards for the environment. The circulation of microplastic pollution supports the initiation of research related to detecting microplastics in the environment. One method for detecting microplastics is the utilization of the fluorescence properties of carbon quantum dots (CQDs). In this study, CQDs will be produced through the hydrothermal method using oil palm fronds as a carbon source because of their lignin levels of up to 26%. To obtain this carbon, oil palm fronds are crushed and then converted into biochar through a pyrolysis process. Biochar is used as a precursor for the manufacture of CQDs produced through the hydrothermal method at temperature variations of 180°C, 190°C, and 200°C. In this study, CQDs were produced with a peak of 291 nm in the UV wavelength range, which indicates the presence of a ?-?* absorption band in the carbon structure of CQDs. The emergence of dominant C=C, O-H and C=O groups in the FTIR test also proves the success of CQDs production through this hydrothermal method. The CQDs produced at the three temperature variations are less than 10 nm in size and have the highest fluorescence intensity at 200? when excited at 405 nm. Moreover, CQDs exhibit a promising ability for detecting microplastics, as indicated by their decreasing fluorescence intensity trend in response to polyethylene (PE) and polyethylene terephthalate (PET) added solution.
format Article
id doaj-art-73514f8b45024659ab85b14472259219
institution Kabale University
issn 2086-9614
2087-2100
language English
publishDate 2025-01-01
publisher Universitas Indonesia
record_format Article
series International Journal of Technology
spelling doaj-art-73514f8b45024659ab85b144722592192025-01-31T14:13:03ZengUniversitas IndonesiaInternational Journal of Technology2086-96142087-21002025-01-0116123324210.14716/ijtech.v16i1.73767376Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics DetectionNonni Soraya Sambudi0Maissy Graceline Mulia1Apriliana Cahya Khayrani2Isnaeni3Revathi Raviadaran4Farhana Aziz5Diva Dwira Permana6Randy Suwandi7Kenny Lischer8Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Pertamina, Jakarta 12220, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia1. Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia 2. Research Center of Biomedical Engineering, Universitas Indonesia, Kampus UIResearch Center for Photonics, National Research and Innovation Agency, Building 442 KST BJ Habibie, South Tangerang 15314, IndonesiaDepartment of Energy Engineering, School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Johor 81310, MalaysiaDepartment of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, MalaysiaDepartment of Chemical Engineering, Faculty of Industrial Technology, Universitas Pertamina, Jakarta 12220, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia1. Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, West Java, Indonesia 2. Research Center of Biomedical Engineering, Universitas Indonesia, Kampus UIAbundant plastic waste degradation to microplastics may cause pollution hazards for the environment. The circulation of microplastic pollution supports the initiation of research related to detecting microplastics in the environment. One method for detecting microplastics is the utilization of the fluorescence properties of carbon quantum dots (CQDs). In this study, CQDs will be produced through the hydrothermal method using oil palm fronds as a carbon source because of their lignin levels of up to 26%. To obtain this carbon, oil palm fronds are crushed and then converted into biochar through a pyrolysis process. Biochar is used as a precursor for the manufacture of CQDs produced through the hydrothermal method at temperature variations of 180°C, 190°C, and 200°C. In this study, CQDs were produced with a peak of 291 nm in the UV wavelength range, which indicates the presence of a ?-?* absorption band in the carbon structure of CQDs. The emergence of dominant C=C, O-H and C=O groups in the FTIR test also proves the success of CQDs production through this hydrothermal method. The CQDs produced at the three temperature variations are less than 10 nm in size and have the highest fluorescence intensity at 200? when excited at 405 nm. Moreover, CQDs exhibit a promising ability for detecting microplastics, as indicated by their decreasing fluorescence intensity trend in response to polyethylene (PE) and polyethylene terephthalate (PET) added solution.https://ijtech.eng.ui.ac.id/article/view/7376carbon quantum dotsfluorescencemicroplasticsoil palm frondsquenching
spellingShingle Nonni Soraya Sambudi
Maissy Graceline Mulia
Apriliana Cahya Khayrani
Isnaeni
Revathi Raviadaran
Farhana Aziz
Diva Dwira Permana
Randy Suwandi
Kenny Lischer
Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
International Journal of Technology
carbon quantum dots
fluorescence
microplastics
oil palm fronds
quenching
title Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
title_full Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
title_fullStr Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
title_full_unstemmed Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
title_short Production of Carbon Quantum Dots Based on Oil Palm Fronds for Polyethylene and Polyethylene Terephthalate Microplastics Detection
title_sort production of carbon quantum dots based on oil palm fronds for polyethylene and polyethylene terephthalate microplastics detection
topic carbon quantum dots
fluorescence
microplastics
oil palm fronds
quenching
url https://ijtech.eng.ui.ac.id/article/view/7376
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