Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices
Abstract All-inorganic lead halide perovskites (LHPs) and their use in optoelectronic devices have been widely explored because they are more thermally stable than their hybrid organic‒inorganic counterparts. However, the active perovskite phases of some inorganic LHPs are metastable at room tempera...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2024-05-01
|
| Series: | NPG Asia Materials |
| Online Access: | https://doi.org/10.1038/s41427-024-00540-0 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832594626140176384 |
|---|---|
| author | Handong Jin Yu-Jia Zeng Julian A. Steele Maarten B. J. Roeffaers Johan Hofkens Elke Debroye |
| author_facet | Handong Jin Yu-Jia Zeng Julian A. Steele Maarten B. J. Roeffaers Johan Hofkens Elke Debroye |
| author_sort | Handong Jin |
| collection | DOAJ |
| description | Abstract All-inorganic lead halide perovskites (LHPs) and their use in optoelectronic devices have been widely explored because they are more thermally stable than their hybrid organic‒inorganic counterparts. However, the active perovskite phases of some inorganic LHPs are metastable at room temperature due to the critical structural tolerance factor. For example, black phase CsPbI3 is easily transformed back to the nonperovskite yellow phase at ambient temperature. Much attention has been paid to improving the phase stabilities of inorganic LHPs, especially those with high solar cell efficiencies. Herein, we discussed the origin of phase stability for CsPbI3 and the strategies used to stabilize the cubic (α) phase. We also assessed the CsPbI3 black β/γ phases that are relatively stable at nearly room temperature. Furthermore, we determined the relationship between phase stabilization and defect passivation and reviewed the growing trend in solar cell efficiency based on black phase CsPbI3. Finally, we provide perspectives for future research related to the quest for optimum device efficiency and green energy. |
| format | Article |
| id | doaj-art-7321313f21e64d5f8759905d9a3591dc |
| institution | Kabale University |
| issn | 1884-4057 |
| language | English |
| publishDate | 2024-05-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | NPG Asia Materials |
| spelling | doaj-art-7321313f21e64d5f8759905d9a3591dc2025-01-19T12:28:41ZengNature PortfolioNPG Asia Materials1884-40572024-05-0116111810.1038/s41427-024-00540-0Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devicesHandong Jin0Yu-Jia Zeng1Julian A. Steele2Maarten B. J. Roeffaers3Johan Hofkens4Elke Debroye5Department of Chemistry, KU LeuvenKey Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen UniversityAustralian Institute for Bioengineering and Nanotechnology and School of Mathematics and Physics, The University of QueenslandcMACS, Department of Microbial and Molecular Systems, KU LeuvenDepartment of Chemistry, KU LeuvenDepartment of Chemistry, KU LeuvenAbstract All-inorganic lead halide perovskites (LHPs) and their use in optoelectronic devices have been widely explored because they are more thermally stable than their hybrid organic‒inorganic counterparts. However, the active perovskite phases of some inorganic LHPs are metastable at room temperature due to the critical structural tolerance factor. For example, black phase CsPbI3 is easily transformed back to the nonperovskite yellow phase at ambient temperature. Much attention has been paid to improving the phase stabilities of inorganic LHPs, especially those with high solar cell efficiencies. Herein, we discussed the origin of phase stability for CsPbI3 and the strategies used to stabilize the cubic (α) phase. We also assessed the CsPbI3 black β/γ phases that are relatively stable at nearly room temperature. Furthermore, we determined the relationship between phase stabilization and defect passivation and reviewed the growing trend in solar cell efficiency based on black phase CsPbI3. Finally, we provide perspectives for future research related to the quest for optimum device efficiency and green energy.https://doi.org/10.1038/s41427-024-00540-0 |
| spellingShingle | Handong Jin Yu-Jia Zeng Julian A. Steele Maarten B. J. Roeffaers Johan Hofkens Elke Debroye Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices NPG Asia Materials |
| title | Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices |
| title_full | Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices |
| title_fullStr | Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices |
| title_full_unstemmed | Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices |
| title_short | Phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices |
| title_sort | phase stabilization of cesium lead iodide perovskites for use in efficient optoelectronic devices |
| url | https://doi.org/10.1038/s41427-024-00540-0 |
| work_keys_str_mv | AT handongjin phasestabilizationofcesiumleadiodideperovskitesforuseinefficientoptoelectronicdevices AT yujiazeng phasestabilizationofcesiumleadiodideperovskitesforuseinefficientoptoelectronicdevices AT julianasteele phasestabilizationofcesiumleadiodideperovskitesforuseinefficientoptoelectronicdevices AT maartenbjroeffaers phasestabilizationofcesiumleadiodideperovskitesforuseinefficientoptoelectronicdevices AT johanhofkens phasestabilizationofcesiumleadiodideperovskitesforuseinefficientoptoelectronicdevices AT elkedebroye phasestabilizationofcesiumleadiodideperovskitesforuseinefficientoptoelectronicdevices |