Green building development utilising modified fired clay bricks and eggshell waste

Abstract The inadequate thermal insulation of the building envelope contributes significantly to the high power consumption of air conditioners in houses. A crucial factor in raising a building’s energy efficiency involves utilizing bricks with high thermal resistance. This issue is accompanied by a...

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Main Authors: Wafaa Soliman, Yasser M. Z. Ahmed, Ahmed Ghitas, Abdel‑Hamid El‑Shater, M. Abdelhamid Shahat
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-87435-4
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author Wafaa Soliman
Yasser M. Z. Ahmed
Ahmed Ghitas
Abdel‑Hamid El‑Shater
M. Abdelhamid Shahat
author_facet Wafaa Soliman
Yasser M. Z. Ahmed
Ahmed Ghitas
Abdel‑Hamid El‑Shater
M. Abdelhamid Shahat
author_sort Wafaa Soliman
collection DOAJ
description Abstract The inadequate thermal insulation of the building envelope contributes significantly to the high power consumption of air conditioners in houses. A crucial factor in raising a building’s energy efficiency involves utilizing bricks with high thermal resistance. This issue is accompanied by another critical challenge: recycling and disposing of waste in a way that is both economically and environmentally beneficial, including using it to fuel industrial growth, in order to reduce the harmful effects of waste on the environment as waste generation in our societies grows. To this end, the current study sought to assess whether integrating a specific amount of eggshell waste as CaCO3 filler within bricks consistently produces fired clay bricks with desirable thermal insulation capabilities. By systematically investigating the physicochemical and thermal characteristics of bricks doped with varying eggshell content, this work demonstrates how waste materials can be repurposed to produce sustainable construction materials with superior performance. The results highlight significant improvements in thermal conductivity, diffusivity, and effusivity, alongside favorable changes in porosity, bulk density, and mechanical strength. The XRD analysis revealed that once the firing temperature rises, a high insulation feature arises due to siliceous melt formation. EDX analysis gave important insights into the impact of eggshell dopants on the physicochemical parameters of burnt clay bricks. Compared to pristine brick, CEs7% brick constructed with clay and 7 wt% eggshell exhibited a 38.7% loss on dry shrinkage, an enhancement on average pore size of 78.8%, an apparent porosity of 52.7%, a bulk density of 8.3%, and a compressive strength of 57.5%. The reduced shrinkage enhances stability, while increased pore size and porosity improve thermal insulation, making the bricks more durable and energy-efficient. In this regard, the brick containing 10% eggshell that was fired at 1100°C possessed the greatest drop in heat conductivity (i.e., 50%), thermal diffusivity (30%), and thermal effusivity (30%) as compared to the pure one. Given the aforementioned findings, these additions hold the potential to reduce the energy required for both heating and cooling buildings. This brings us to the conclusion that combining eggshell waste to create calcium silicate makes it feasible to be utilized as a thermal insulation material, paving the way for improved construction materials’ performance and sustainability.
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spelling doaj-art-730ede6df31640c48a8f2ae10bcfed292025-02-02T12:16:19ZengNature PortfolioScientific Reports2045-23222025-01-0115111710.1038/s41598-025-87435-4Green building development utilising modified fired clay bricks and eggshell wasteWafaa Soliman0Yasser M. Z. Ahmed1Ahmed Ghitas2Abdel‑Hamid El‑Shater3M. Abdelhamid Shahat4Geology Department, Faculty of Science, Sohag UniversityRefractory and Ceramic Materials Department, Advanced Materials Institute, Central Metallurgical Research and Development InstitutePV Unit, Solar and Space Research Department, National Research Institute of Astronomy and Geophysics (NRIAG)Geology Department, Faculty of Science, Sohag UniversityPV Unit, Solar and Space Research Department, National Research Institute of Astronomy and Geophysics (NRIAG)Abstract The inadequate thermal insulation of the building envelope contributes significantly to the high power consumption of air conditioners in houses. A crucial factor in raising a building’s energy efficiency involves utilizing bricks with high thermal resistance. This issue is accompanied by another critical challenge: recycling and disposing of waste in a way that is both economically and environmentally beneficial, including using it to fuel industrial growth, in order to reduce the harmful effects of waste on the environment as waste generation in our societies grows. To this end, the current study sought to assess whether integrating a specific amount of eggshell waste as CaCO3 filler within bricks consistently produces fired clay bricks with desirable thermal insulation capabilities. By systematically investigating the physicochemical and thermal characteristics of bricks doped with varying eggshell content, this work demonstrates how waste materials can be repurposed to produce sustainable construction materials with superior performance. The results highlight significant improvements in thermal conductivity, diffusivity, and effusivity, alongside favorable changes in porosity, bulk density, and mechanical strength. The XRD analysis revealed that once the firing temperature rises, a high insulation feature arises due to siliceous melt formation. EDX analysis gave important insights into the impact of eggshell dopants on the physicochemical parameters of burnt clay bricks. Compared to pristine brick, CEs7% brick constructed with clay and 7 wt% eggshell exhibited a 38.7% loss on dry shrinkage, an enhancement on average pore size of 78.8%, an apparent porosity of 52.7%, a bulk density of 8.3%, and a compressive strength of 57.5%. The reduced shrinkage enhances stability, while increased pore size and porosity improve thermal insulation, making the bricks more durable and energy-efficient. In this regard, the brick containing 10% eggshell that was fired at 1100°C possessed the greatest drop in heat conductivity (i.e., 50%), thermal diffusivity (30%), and thermal effusivity (30%) as compared to the pure one. Given the aforementioned findings, these additions hold the potential to reduce the energy required for both heating and cooling buildings. This brings us to the conclusion that combining eggshell waste to create calcium silicate makes it feasible to be utilized as a thermal insulation material, paving the way for improved construction materials’ performance and sustainability.https://doi.org/10.1038/s41598-025-87435-4Clay–eggshell composite bricksEggshell waste recyclingShrinkage behaviourBulk densitySurface porosityThermophysical compositions
spellingShingle Wafaa Soliman
Yasser M. Z. Ahmed
Ahmed Ghitas
Abdel‑Hamid El‑Shater
M. Abdelhamid Shahat
Green building development utilising modified fired clay bricks and eggshell waste
Scientific Reports
Clay–eggshell composite bricks
Eggshell waste recycling
Shrinkage behaviour
Bulk density
Surface porosity
Thermophysical compositions
title Green building development utilising modified fired clay bricks and eggshell waste
title_full Green building development utilising modified fired clay bricks and eggshell waste
title_fullStr Green building development utilising modified fired clay bricks and eggshell waste
title_full_unstemmed Green building development utilising modified fired clay bricks and eggshell waste
title_short Green building development utilising modified fired clay bricks and eggshell waste
title_sort green building development utilising modified fired clay bricks and eggshell waste
topic Clay–eggshell composite bricks
Eggshell waste recycling
Shrinkage behaviour
Bulk density
Surface porosity
Thermophysical compositions
url https://doi.org/10.1038/s41598-025-87435-4
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