EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes

Scholarly discourse surrounding the thin film composite organic solvent nanofiltration (TFC OSN) membrane field has largely been dominated by focusing on the optimization of the selective layer. However, this often leaves the porous support layer, with its innate solvent resistance, cost-effectivene...

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Main Authors: Guoke Zhao, Tian Zhong, Xinkai Li, Hao Yu, Guoyuan Pan, Yang Zhang, Yiqun Liu
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2025-01-01
Series:Advanced Membranes
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772823425000053
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author Guoke Zhao
Tian Zhong
Xinkai Li
Hao Yu
Guoyuan Pan
Yang Zhang
Yiqun Liu
author_facet Guoke Zhao
Tian Zhong
Xinkai Li
Hao Yu
Guoyuan Pan
Yang Zhang
Yiqun Liu
author_sort Guoke Zhao
collection DOAJ
description Scholarly discourse surrounding the thin film composite organic solvent nanofiltration (TFC OSN) membrane field has largely been dominated by focusing on the optimization of the selective layer. However, this often leaves the porous support layer, with its innate solvent resistance, cost-effectiveness, and superior permeability, in the shadows. This study presents a novel OSN membrane utilizing a polyethylene (PE) battery separator as the porous substrate. The structural affinity between ethylene-vinyl alcohol and PE facilitates efficient hydrophilic modification, which allows for uniform and compact polyamide selective layer formation through interfacial polymerization. The HPE-NF-1.0 membrane exhibits rejections of 99.5 ​%, 96.7 ​%, 100 ​%, and 97.2 ​% for Methyl Orange, Rhodamine B, Congo red, and Rose Bengal, respectively. It also shows a solvent flux of 52.5 LMH in methanol and robust resistance against alcoholic solvents and DMF. Using PE as the porous substrate, we bypass intricate and time-demanding cross-linking processes and complex pore-preservation post-treatments, providing a simplified strategy for TFC OSN membrane fabrication.
format Article
id doaj-art-72eb31f780904b8db17daca889b975f8
institution Kabale University
issn 2772-8234
language English
publishDate 2025-01-01
publisher KeAi Communications Co. Ltd.
record_format Article
series Advanced Membranes
spelling doaj-art-72eb31f780904b8db17daca889b975f82025-02-05T04:32:53ZengKeAi Communications Co. Ltd.Advanced Membranes2772-82342025-01-015100131EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranesGuoke Zhao0Tian Zhong1Xinkai Li2Hao Yu3Guoyuan Pan4Yang Zhang5Yiqun Liu6Corresponding author.; SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaCorresponding author.; SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaCorresponding author.; SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaScholarly discourse surrounding the thin film composite organic solvent nanofiltration (TFC OSN) membrane field has largely been dominated by focusing on the optimization of the selective layer. However, this often leaves the porous support layer, with its innate solvent resistance, cost-effectiveness, and superior permeability, in the shadows. This study presents a novel OSN membrane utilizing a polyethylene (PE) battery separator as the porous substrate. The structural affinity between ethylene-vinyl alcohol and PE facilitates efficient hydrophilic modification, which allows for uniform and compact polyamide selective layer formation through interfacial polymerization. The HPE-NF-1.0 membrane exhibits rejections of 99.5 ​%, 96.7 ​%, 100 ​%, and 97.2 ​% for Methyl Orange, Rhodamine B, Congo red, and Rose Bengal, respectively. It also shows a solvent flux of 52.5 LMH in methanol and robust resistance against alcoholic solvents and DMF. Using PE as the porous substrate, we bypass intricate and time-demanding cross-linking processes and complex pore-preservation post-treatments, providing a simplified strategy for TFC OSN membrane fabrication.http://www.sciencedirect.com/science/article/pii/S2772823425000053Surface functionalizationPolyethylene separatorThin film composite membraneOrganic solvent nanofiltrationInterfacial polymerization
spellingShingle Guoke Zhao
Tian Zhong
Xinkai Li
Hao Yu
Guoyuan Pan
Yang Zhang
Yiqun Liu
EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
Advanced Membranes
Surface functionalization
Polyethylene separator
Thin film composite membrane
Organic solvent nanofiltration
Interfacial polymerization
title EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
title_full EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
title_fullStr EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
title_full_unstemmed EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
title_short EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
title_sort evoh functionalized pe battery separator as the porous substrate for tfc organic solvent nanofiltration membranes
topic Surface functionalization
Polyethylene separator
Thin film composite membrane
Organic solvent nanofiltration
Interfacial polymerization
url http://www.sciencedirect.com/science/article/pii/S2772823425000053
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AT xinkaili evohfunctionalizedpebatteryseparatorastheporoussubstratefortfcorganicsolventnanofiltrationmembranes
AT haoyu evohfunctionalizedpebatteryseparatorastheporoussubstratefortfcorganicsolventnanofiltrationmembranes
AT guoyuanpan evohfunctionalizedpebatteryseparatorastheporoussubstratefortfcorganicsolventnanofiltrationmembranes
AT yangzhang evohfunctionalizedpebatteryseparatorastheporoussubstratefortfcorganicsolventnanofiltrationmembranes
AT yiqunliu evohfunctionalizedpebatteryseparatorastheporoussubstratefortfcorganicsolventnanofiltrationmembranes