EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes
Scholarly discourse surrounding the thin film composite organic solvent nanofiltration (TFC OSN) membrane field has largely been dominated by focusing on the optimization of the selective layer. However, this often leaves the porous support layer, with its innate solvent resistance, cost-effectivene...
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Format: | Article |
Language: | English |
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KeAi Communications Co. Ltd.
2025-01-01
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Series: | Advanced Membranes |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2772823425000053 |
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author | Guoke Zhao Tian Zhong Xinkai Li Hao Yu Guoyuan Pan Yang Zhang Yiqun Liu |
author_facet | Guoke Zhao Tian Zhong Xinkai Li Hao Yu Guoyuan Pan Yang Zhang Yiqun Liu |
author_sort | Guoke Zhao |
collection | DOAJ |
description | Scholarly discourse surrounding the thin film composite organic solvent nanofiltration (TFC OSN) membrane field has largely been dominated by focusing on the optimization of the selective layer. However, this often leaves the porous support layer, with its innate solvent resistance, cost-effectiveness, and superior permeability, in the shadows. This study presents a novel OSN membrane utilizing a polyethylene (PE) battery separator as the porous substrate. The structural affinity between ethylene-vinyl alcohol and PE facilitates efficient hydrophilic modification, which allows for uniform and compact polyamide selective layer formation through interfacial polymerization. The HPE-NF-1.0 membrane exhibits rejections of 99.5 %, 96.7 %, 100 %, and 97.2 % for Methyl Orange, Rhodamine B, Congo red, and Rose Bengal, respectively. It also shows a solvent flux of 52.5 LMH in methanol and robust resistance against alcoholic solvents and DMF. Using PE as the porous substrate, we bypass intricate and time-demanding cross-linking processes and complex pore-preservation post-treatments, providing a simplified strategy for TFC OSN membrane fabrication. |
format | Article |
id | doaj-art-72eb31f780904b8db17daca889b975f8 |
institution | Kabale University |
issn | 2772-8234 |
language | English |
publishDate | 2025-01-01 |
publisher | KeAi Communications Co. Ltd. |
record_format | Article |
series | Advanced Membranes |
spelling | doaj-art-72eb31f780904b8db17daca889b975f82025-02-05T04:32:53ZengKeAi Communications Co. Ltd.Advanced Membranes2772-82342025-01-015100131EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranesGuoke Zhao0Tian Zhong1Xinkai Li2Hao Yu3Guoyuan Pan4Yang Zhang5Yiqun Liu6Corresponding author.; SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaSINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaCorresponding author.; SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaCorresponding author.; SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013, ChinaScholarly discourse surrounding the thin film composite organic solvent nanofiltration (TFC OSN) membrane field has largely been dominated by focusing on the optimization of the selective layer. However, this often leaves the porous support layer, with its innate solvent resistance, cost-effectiveness, and superior permeability, in the shadows. This study presents a novel OSN membrane utilizing a polyethylene (PE) battery separator as the porous substrate. The structural affinity between ethylene-vinyl alcohol and PE facilitates efficient hydrophilic modification, which allows for uniform and compact polyamide selective layer formation through interfacial polymerization. The HPE-NF-1.0 membrane exhibits rejections of 99.5 %, 96.7 %, 100 %, and 97.2 % for Methyl Orange, Rhodamine B, Congo red, and Rose Bengal, respectively. It also shows a solvent flux of 52.5 LMH in methanol and robust resistance against alcoholic solvents and DMF. Using PE as the porous substrate, we bypass intricate and time-demanding cross-linking processes and complex pore-preservation post-treatments, providing a simplified strategy for TFC OSN membrane fabrication.http://www.sciencedirect.com/science/article/pii/S2772823425000053Surface functionalizationPolyethylene separatorThin film composite membraneOrganic solvent nanofiltrationInterfacial polymerization |
spellingShingle | Guoke Zhao Tian Zhong Xinkai Li Hao Yu Guoyuan Pan Yang Zhang Yiqun Liu EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes Advanced Membranes Surface functionalization Polyethylene separator Thin film composite membrane Organic solvent nanofiltration Interfacial polymerization |
title | EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes |
title_full | EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes |
title_fullStr | EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes |
title_full_unstemmed | EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes |
title_short | EVOH functionalized PE battery separator as the porous substrate for TFC organic solvent nanofiltration membranes |
title_sort | evoh functionalized pe battery separator as the porous substrate for tfc organic solvent nanofiltration membranes |
topic | Surface functionalization Polyethylene separator Thin film composite membrane Organic solvent nanofiltration Interfacial polymerization |
url | http://www.sciencedirect.com/science/article/pii/S2772823425000053 |
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